Collinear to spiral spin transformation without changing the modulation wavelength upon ferroelectric transition in Tb1-xDyxMnO3

Lattice modulation and magnetic structures in magnetoelectric compounds Tb1-xDyxMnO3 have been studied around the ferroelectric (FE) Curie temperature TC by x-ray and neutron diffraction. Temperature-independent modulation vectors through TC are observed for the compounds with 0.50 相似文献   

Inclusion Complexation of a Seleno-Organic Antioxidant, Ebselen, with Cyclodextrins in Aqueous Solution

The interaction of ebselen, 2-phenyl-1,2-benzisoselenazol-3(2H)-one, a novel neuroprotective agent, with cyclodextrins (CyDs) in aqueous solution was studied by the solubility method and spectroscopic methods. The ability of sulfobutyl ether -CyD (SBE7--CyD, average degree of substitution= 6.2) to solubilize ebselen was greater, and its stability constant (> 2000 M^-1) was significantly higher than those (< 1000 M^-1) of other CyD complexes employed. The stability constant of the complexes rose as hydrophobicity of the substituents of CyDs increased, whereas it was negligibly affected by change in ionic strength of the medium, indicating a significant contribution of hydrophobic interaction in the complexation. SBE7--CyD gave positive and negative CD bands at around 320 and 350 nm, respectively, indicating that the guest is embedded in the asymmetric locus of the CyD cavity. ¹H-NMR spectroscopic studies suggested that the mono-substituted benzene ring of ebselen is preferably included in the cavity of SBE7--CyD. The results indicate that SBE7--CyD is useful as a solubilizing agent for ebselen.     

A PL homotopy for finding all the roots of a polynomial

This paper presents a constructive method which gives, for any polynomialF(Z) of the degreen, approximate values of all the roots ofF(Z).. The point of the method is on the use of a piecewise linear function (Z, t) which approximates a homotopyH(Z, t) betweenF(Z) and a polynomialG(Z) of the degreen withn known simple roots. It is shown that the set of solutions to (Z, t) = 0 includesn distinct paths,m of which converges to a root ofF(Z) if and only if the root has the multiplicitym. Starting from givenn roots ofG(Z), a complementary pivot algorithm generates thosen paths.This work was supported by grants from Management Science Development Foundation and Takeda Science Foundation.     

Photo-modulation of supramolecular polymorphism in the self-assembly of a scissor-shaped azobenzene dyad into nanotoroids and fibers

Recent advances in the research field of supramolecularly engineered dye aggregates have enabled the design of simple one-dimensional stacks such as fibers and of closed structures such as nanotoroids (nanorings). More complex and advanced supramolecular systems could potentially be designed using a molecule that is able to provide either of these distinct nanostructures under different conditions. In this study, we introduced bulky but strongly aggregating cholesterol units to a scissor-shaped azobenzene dyad framework, which affords either nanotoroids, nanotubes, or 1D fibers, depending on the substituents. This new dyad with two trans-azobenzene arms shows supramolecular polymorphism in its temperature-controlled self-assembly, leading to not only oligomeric nanotoroids as kinetic products, but also to one-dimensional fibers as thermodynamic products. This supramolecular polymorphism can also be achieved via photo-triggered self-assembly, i.e., irradiation of a monomeric solution of the dyad with two cis-azobenzene arms using strong visible light leads to the preferential formation of nanotoroids, whereas irradiation with weak visible light leads to the predominant formation of 1D fibers. This is the first example of a successful light-induced modulation of supramolecular polymorphism to produce distinctly nanostructured aggregates under isothermal conditions.

Introduction of the bulky yet strongly aggregating cholesterol units to an azobenzene dyad lead to a supramolecular polymorphism not only in its temperature-controlled but also in photo-triggered self-assembly, leading to toroids and helical fibers.     

Electromagnetic cross sections of double giant dipole resonances in 136Xe and 208Pb within the phonon damping model

The electromagnetic cross sections of the double giant dipole resonances (DGDR) in 136Xe and 208Pb are calculated using the strength functions obtained within the phonon damping model. The parameters of the model have been selected to describe reasonably well the single giant dipole resonance in these nuclei. The results are found in an overall agreement with the recent experimental data for the DGDR cross sections in exclusive measurements at near-relativistic energies.     

Magnetic hyperfine structure of muonic and electronic atoms

The magnetic hyperfine structure of atoms is studied. A new compact expression is introduced for the magnetic hyperfine anomaly. A theoretical foundation is given for an empirical formula discovered by Moskowitz and Lombardi. The effects of core polarization and mesonic exchange currents are discussed. There are two kinds of core polarization, Δl = 0 and Δl = 2. The latter is shown to be important to explain certain isotope shifts, though it is smaller than the former Δl = 0 effect.     

Pressure-induced sharp coordination change in liquid germanate

Local structures around germanium in liquid germanate have been investigated by means of in situ x-ray absorption measurements up to 9 GPa at 1273 K. Liquid germanate consisting of tetrahedrally coordinated germanium contracts with increasing pressure without significant changes in the local structure up to 2.5 GPa and then shows an abrupt fourfold-to-sixfold coordination change around 3 GPa. The coordination change is completed below 4 GPa where upon a high-density liquid consisting of octahedrally coordinated germanium becomes stable. The GeO6 octahedron in the high-density liquid is more compressible than that in solids.