Antisymmetric exchange interaction,magnetoelectric and magnetodielectric response in structurally distorted G-type antiferromagnetic perovskite: La0.9Gd0.1FeO3

Detailed structural analysis of the X-Ray diffraction pattern of La_0.9Gd_0.1FeO₃ (LGFO) synthesized via the solid state reaction reveals distorted perovskite structure. Magnetization studies show a characteristic of weak ferromagnetism which is believed to be induced by canted anti-ferromagnetically coupled spins. When explored in a wide temperature and frequency range, AC electrical properties reveal interesting relaxation mechanisms. LGFO exhibits relatively high dielectric permittivity (ε′~4×10³) close to room temperature. Temperature dependent magneto-dielectric response appears (magnetodielectric ~−5.5%) even at low magnetic field ~5 kOe. Attractive electrical, magnetic and magnetoelectric properties of the present LGFO at relatively higher temperature makes it a very promising material for application in devices.     

One dimensional flow of a plasma with an external magnetic field

Zusammenfassung Eine Lösung der Gleichungen der eindimensionalen Plasmaströmung in Anwesenheit eines externen magnetischen Feldes senkrecht zur Strömungsrischtung wird entwickelt im speziellen Fall: (i)P _r =3/4, (ii)c _p -constant und (iii)T=T(u).     

Photodetachment of the Positronium Negative Ion with Exponential Cosine-Screened Coulomb Potentials

We have made an investigation to study the photodetachment of positronium negative ion (Ps ⁻) interacting with exponential cosine-screened Coulomb potentials (ECSCP) within the framework of dipole approximation. The dipole transition matrix elements are calculated using the asymptotic form of highly accurate initial wave function of the bound ionic state and plane wave for final electron–positronium state. Results for photodetachment cross section in ECSCP are reported for the screening parameter in the range [0.0,0.35] (in a₀^-1{a_0^{-1}}). Our results for the unscreened case agree nicely with some of the most accurate results available in the literature. Furthermore we make a comparative study of the photodetachment of Ps ⁻ in ECSCP with the photodetachment of Ps ⁻ in screened Coulomb potential. To the best of our knowledge, such a study on the photodetachment of Ps ⁻ in ECSCP is carried out for the first time in the literature.     

Asymptotic behaviour of high Gaussian minima

We investigate what happens when an entire sample path of a smooth Gaussian process on a compact interval lies above a high level. Specifically, we determine the precise asymptotic probability of such an event, the extent to which the high level is exceeded, the conditional shape of the process above the high level, and the location of the minimum of the process given that the sample path is above a high level.     

Synergistically advancing Li storage property of hydrothermally grown 1D pristine MnO2 over a mesh-like interconnected framework of 2D graphene oxide

Journal of Solid State Electrochemistry - Here, we present a unique morphology comprising a blend of ultrafine 1D MnO2 and graphene oxide as an efficient anode material to overcome the issue of...     

Surfactant solubilization and the direct encapsulation of interfacially active phenols in mesoporous silicas

The solubilization of phenols in micelles of cetyltrimethyl ammonium bromide leads to microstructural changes from spherical micelles to wormlike micelles and then to vesicles. These microstructures are then used to template silicas. There is a transition from highly ordered hexagonal mesoporous silicas of the M41S family to lamellar structures, as the phenolic dopant concentration is increased. The results have implication to the removal of phenols from aqueous waste streams through the micellar enhanced ultrafiltration process. The entrapment of phenols in mesoporous silicas provides a way to sequester such contaminants in concentrated form.     

Separating Vibrational Coherences in Ground/Excited Electronic States of Solvent/Solute Following Non-Resonant/Resonant Impulsive Excitation

In a quest to track down the origin of coherent vibrational motions observed in femtosecond pump-probe transients, whether they arise from ground/excited electronic state of solute or are contributed by the solvent, we demonstrate a method for extricating vibrations under resonant and non-resonant impulsive excitations using a diatomic solute in condensed phase (iodine in carbon tetrachloride) with aid of spectral dispersion of the chirped broadband probe. Most importantly, we show how a sum over intensities for a select region of detection wavelengths and Fourier transform of data over select temporal window untwine contributions from vibrational modes of different origins. Thus, in a single pump-probe experiment, vibrational features specific to solute as well as solvent are disentangled that are otherwise spectrally overlapping and are non-separable in conventional (spontaneous/stimulated) Raman spectroscopy employing narrowband excitation. We envision wide-ranging applications of this method to unveil vibrational features in complex molecular systems.     

Segmented conjugated macromolecules containing silicon and boron: ADMET synthesis and luminescent properties

Boron‐ and silicon‐containing conjugated homo‐ and copolymers could be synthesized using acyclic diene metathesis (ADMET) condensation of bis‐styryl monomers. Both, tri‐and tetra‐coordinated boron monomers were successfully polymerized forming homopolymers, or random copolymers (if polymerized together with a silicon containing co‐monomer). Polymer molecular weights M_n were measured at ～6000 to 15,000 g/mol (NMR end group analysis) with molecular weight distributions M_w/M_n ～1.8 to 2.2. The polymers absorbed at λ_max ～317 to 406 nm and emitted at λ_max ～370 to 494 nm with fluorescent quantum efficiencies ～24 to 48%. The copolymer with tri‐coordinate boron showed highly efficient fluorescence quenching in the presence of fluoride ions at ratios boron/fluoride ～5/1, demonstrating its potential as anion sensor. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1707–1718     

Gold(I)/Chiral Brønsted Acid Catalyzed Enantioselective Hydroamination–Hydroarylation of Alkynes: The Effect of a Remote Hydroxyl Group on the Reactivity and Enantioselectivity

The catalytic enantioselective hydroamination–hydroarylation of alkynes under the catalysis of (R₃P)AuMe/(S)‐3,3′‐bis(2,4,6‐triisopropylphenyl)‐1,1′‐binaphthyl‐2,2′‐diyl hydrogenphosphate ((S)‐TRIP) is reported. The alkyne was reacted with a range of pyrrole‐based aromatic amines to give pyrrole‐embedded aza‐heterocyclic scaffolds bearing a quaternary carbon center. The presence of a hydroxyl group in the alkyne tether turned out to be very crucial for obtaining products in high yields and enantioselectivities. The mechanism of enantioinduction was established by carefully performing experimental and computational studies.