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141.
Possible formation of stable Au atomic wire on the hydrogen terminated Si(0 0 1): 3×1 surface is investigated under the density functional formalism. The hydrogen terminated Si(0 0 1): 3×1 surface is patterned in two different ways by removing selective hydrogen atoms from the surface. The adsorption of Au on such surfaces is studied at different sub-monolayer coverages. At 4/9 monolayer (ML) coverage, zigzag continuous Au chains are found to be stable on the patterned hydrogen terminated Si(0 0 1): 3×1 surface. The reason for the stability of the wire structures at 4/9 ML coverage is explained. It is to be noted that beyond 4/9 ML coverage, the additional Au atoms may introduce clusters on the surface. The continuous atomic gold chains on the substrate may be useful for the fabrication of atomic scale devices. 相似文献
142.
Magnetic field effect in conjunction with laser flash photolysis have been used for studying interactions of 9,10-anthraquinone and 2-methyl 1,4-naphthoquinone (menadione) with a DNA base, thymine (Thy) and its nucleoside, thymidine (dThd). Irrespective of medium Thy has been found to support both electron transfer (ET) and hydrogen abstraction with the quinones while dThd has exhibited a complete reluctance towards ET. This unique behavior of dThd has been attributed to a failure in attaining aromaticity by virtue of keto-enol tautomerism upon addition of a sugar moiety. Electron withdrawing effect of sugar unit is also considered responsible for reduction of ET from dThd. Again both Thy and dThd have exhibited hydrogen abstraction in homogeneous medium, which is normally unexpected. The above behaviors of the bases have been explained on the basis of their chemical structures. 相似文献
143.
Vamsi Krishna Balla Susmita Bose Amit Bandyopadhyay 《Optics and Lasers in Engineering》2009,47(6):651-655
The feasibility of enhancing thermal conductivity of Al–4Cu–1Mg alloy by depositing 80Cu–20Mo coating using high-power lasers has been examined. Coatings of 667±2.5 μm thickness were formed with metallurgically sound interface. Results showed an 86% increase in the thermal conductivity of Al–4Cu–1Mg alloy due to laser-deposited 80Cu–20Mo alloy coating. This coating approach can potentially be used on low coefficient of thermal expansion metal matrix composites to enhance their thermal conductivity in electronic devices. 相似文献
144.
Bushra Asad Taimoor Khan Faiza Zareen Gul Muhammad Asad Ullah Samantha Drouet Sara Mikac Laurine Garros Manon Ferrier Shankhamala Bose Thibaut Munsch Duangjai Tungmunnithum Arnaud Lanoue Nathalie Giglioli-Guivarch Christophe Hano Bilal Haider Abbasi 《Molecules (Basel, Switzerland)》2021,26(15)
In vitro cultures of scarlet flax (Linum grandiflorum L.), an important ornamental flax, have been established as a new possible valuable resource of lignans and neolignans for antioxidant and anti-inflammatory applications. The callogenic potential at different concentrations of α-naphthalene acetic acid (NAA) and thidiazuron (TDZ), alone or in combinations, was evaluated using both L. grandiflorum hypocotyl and cotyledon explants. A higher callus induction frequency was observed on NAA than TDZ, especially for hypocotyl explants, with a maximum frequency (i.e., 95.2%) on 1.0 mg/L of NAA. The presence of NAA (1.0 mg/L) in conjunction with TDZ tended to increase the frequency of callogenesis relative to TDZ alone, but never reached the values observed with NAA alone, thereby indicating the lack of synergy between these two plant growth regulators (PGRs). Similarly, in terms of biomass, NAA was more effective than TDZ, with a maximum accumulation of biomass registered for medium supplemented with 1.0 mg/L of NAA using hypocotyls as initial explants (DW: 13.1 g). However, for biomass, a synergy between the two PGRs was observed, particularly for cotyledon-derived explants and for the lowest concentrations of TDZ. The influence of these two PGRs on callogenesis and biomass is discussed. The HPLC analysis confirmed the presence of lignans (secoisolariciresinol (SECO) and lariciresinol (LARI) and neolignan (dehydrodiconiferyl alcohol [DCA]) naturally accumulated in their glycoside forms. Furthermore, the antioxidant activities performed for both hypocotyl- and cotyledon-derived cultures were also found maximal (DPPH: 89.5%, FRAP 866: µM TEAC, ABTS: 456 µM TEAC) in hypocotyl-derived callus cultures as compared with callus obtained from cotyledon explants. Moreover, the anti-inflammatory activities revealed high inhibition (COX-1: 47.4% and COX-2: 51.1%) for extract of hypocotyl-derived callus cultures at 2.5 mg/L TDZ. The anti-inflammatory action against COX-1 and COX-2 was supported by the IC50 values. This report provides a viable approach for enhanced biomass accumulation and efficient production of (neo)lignans in L. grandiflorum callus cultures. 相似文献
145.
Conductivities of some tetraalkylammonium halides, viz. tetrabutylammonium bromide (Bu4NBr), tetrapentylammonium bromide (Pen4NBr), tetrahexylammonium bromide (Hex4NBr) and tetraheptylammonium bromide (Hep4NBr) were measured at 298.15 K in THF + C6H6 mixtures with 10, 20, 30 and 40 mass% of C6H6. A minimum in the conductance values was observed as concentration increases, which dependent both on the salt and the solvent. The observed molar conductivities were explained by the formation of ion-pairs (M+ + X− ↔ MX, KP) and triple-ions (2 M+ + X− ↔ M2X+; M+ + 2X− ↔ MX2−, KT). A linear relationship between the triple-ion formation constants [log(KT/KP)] and the salt concentrations at the minimum conductivity (log Cmin) was given for all salts in C6H6 + THF mixtures. The formation of triple-ions might be attributed to the ion sizes in solutions in which coulombic interactions and covalent bonding forces act as the main forces between the ions (R4N+ X−). 相似文献
146.
147.
Anirbandeep Bose Uttam Bhaumik Animesh Ghosh Bappaditya Chatterjee Uday Sankar Chakrabarty Amlan Kanti Sarkar Tapan Kumar Pal 《Chromatographia》2009,69(11-12):1233-1241
A rapid, simple, sensitive and specific liquid chromatography–tandem mass spectrometry method was developed and validated for simultaneous quantification of itopride hydrochloride and domperidone in human plasma. Both drugs were extracted by liquid–liquid extraction with ethyl acetate and saturated borax solution. The chromatographic separation was performed on a reversed-phase C18 column with a mobile phase of water–methanol (2:98, v/v) containing 0.5% formic acid. The protonated analyte was quantitated in positive ionization by multiple reaction monitoring with a mass spectrometer. The assay exhibited linearity over the concentration range of 3.33–500 ng mL?1 for itopride hydrochloride and 3.33–100 ng mL?1 for domperidone in human plasma. The precursor to product ion transitions of m/z 359.1–72.3 and 426.0–147.2 were used to measure itopride hydrochloride and domperidone respectively. The method was found suitable for the analysis of plasma samples collected during phase 1 pharmacokinetics study of itopride HCl 50 mg and domperidone 20 mg in 12 healthy volunteers after single oral doses of the combination drug. 相似文献
148.
Prosenjit Bose Vida Dujmović Ferran Hurtado Stefan Langerman Pat Morin David R. Wood 《Discrete and Computational Geometry》2009,42(4):570-585
To untangle a geometric graph means to move some of the vertices so that the resulting geometric graph has no crossings. Pach and Tardos (Discrete Comput. Geom. 28(4): 585–592, 2002) asked if every n-vertex geometric planar graph can be untangled while keeping at least n ε vertices fixed. We answer this question in the affirmative with ε=1/4. The previous best known bound was \(\Omega(\sqrt{\log n/\log\log n})\). We also consider untangling geometric trees. It is known that every n-vertex geometric tree can be untangled while keeping at least \(\Omega(\sqrt{n})\) vertices fixed, while the best upper bound was \(\mathcal{O}((n\log n)^{2/3})\). We answer a question of Spillner and Wolff (http://arxiv.org/abs/0709.0170) by closing this gap for untangling trees. In particular, we show that for infinitely many values of n, there is an n-vertex geometric tree that cannot be untangled while keeping more than \(3(\sqrt{n}-1)\) vertices fixed. 相似文献
149.
The bandwidth packing problem is defined as the selection and routing of messages from a given list of messages with prespecified requirements on demand for bandwidth. The messages have to be routed over a network with given topology so that the generated revenue is maximized. Messages to be routed are classified into two priority classes. An integer programming based formulation of this problem is proposed and a Lagrangean relaxation based methodology is described for solving this problem. A general purpose heuristic is then developed for generating feasible solutions of good quality. Several numerical experiments are conducted using a number of problem parameters such as number of messages, ratio of messages for lower and higher priority classes, capacity of links, and demand distribution of messages belonging to different classes and high quality solutions to the priority bandwidth packing problem are generated under the different situations. 相似文献
150.