全文获取类型
收费全文 | 988篇 |
免费 | 28篇 |
国内免费 | 5篇 |
专业分类
化学 | 532篇 |
晶体学 | 7篇 |
力学 | 23篇 |
数学 | 128篇 |
物理学 | 331篇 |
出版年
2023年 | 7篇 |
2022年 | 13篇 |
2021年 | 8篇 |
2020年 | 13篇 |
2019年 | 19篇 |
2018年 | 20篇 |
2017年 | 22篇 |
2016年 | 31篇 |
2015年 | 27篇 |
2014年 | 36篇 |
2013年 | 58篇 |
2012年 | 64篇 |
2011年 | 56篇 |
2010年 | 43篇 |
2009年 | 42篇 |
2008年 | 60篇 |
2007年 | 37篇 |
2006年 | 46篇 |
2005年 | 36篇 |
2004年 | 30篇 |
2003年 | 22篇 |
2002年 | 18篇 |
2001年 | 12篇 |
2000年 | 16篇 |
1999年 | 15篇 |
1998年 | 18篇 |
1997年 | 5篇 |
1996年 | 9篇 |
1995年 | 13篇 |
1994年 | 12篇 |
1993年 | 11篇 |
1992年 | 19篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 8篇 |
1987年 | 7篇 |
1986年 | 5篇 |
1985年 | 10篇 |
1984年 | 17篇 |
1983年 | 10篇 |
1982年 | 10篇 |
1981年 | 12篇 |
1980年 | 6篇 |
1979年 | 8篇 |
1978年 | 15篇 |
1977年 | 5篇 |
1976年 | 5篇 |
1957年 | 4篇 |
1936年 | 4篇 |
排序方式: 共有1021条查询结果,搜索用时 31 毫秒
91.
D. P. Bhattacharyya R. Rakshit B. Basu P. Pal S. Biswas N. Durgaprasad 《Il Nuovo Cimento C》1992,15(3):341-347
Summary A search has been made on the charge-changing partial cross-sections by using 0.927 GeV/n238U ion from LBL BEVALAC projected at an angle 30° on27Al target and CR-39 (DOP) was used as analyser. The irradiated plastic sheets were duly etched for one hour in 6.25N NaOH
solution and about 1680 cone lengths at both the surfaces of the CR-39 (DOP) sheets were optically measured. The cone length
distribution exhibits the existence of U fragments in the charge range 84≤Z≤91 and the estimated partial cross-sections range from 60 to 400 mb. The present data are in accord with the fit to the extrapolated
data of Binnset al. 相似文献
92.
The use of Amberlite-LA-2, a high molecular weight secondary amine, for the radiochemical solvent extraction of Ag(I) present as anionic thiosulfato complex at pH 3 is described. The effects of different parameters on the extraction and preconcentration have been studied in detail. The method was successfully applied in the determination of silver in several synthetic mixutres and also in a few medicinal samples. 相似文献
93.
Sudeshna Basu 《Indagationes Mathematicae》2002,13(2):169-175
The Ball Generated Property (BGP) was introduced by Corson and Lindenstrauss and subsequently analysed in detail by Godefroy and Kalton. In this work, the (BGP) is studied in spaces of operators. It is shown that (BGP) is stable under c0 and lp-sums for 1 < p < ∞ and a characterization is provided for C(K, X)-spaces with (BGP). A similar characterization is obtained for L(X, C(K))-spaces. (BGP) is shown to be stable under injective tensor products. 相似文献
94.
Anchoring Mechanism of ZnO Nanoparticles on Graphitic Carbon Nanofiber Surfaces through a Modified Co‐Precipitation Method to Improve Interfacial Contact and Photocatalytic Performance
下载免费PDF全文
![点击此处可从《Chemphyschem》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Gowra Raghupathy Dillip Dr. Arghya Narayan Banerjee Dr. Veettikunnu Chandran Anitha Dr. Sang Woo Joo Dr. Bong Ki Min Dr. Sandesh Y. Sawant Dr. Moo Hwan Cho 《Chemphyschem》2015,16(15):3214-3232
A facile three‐step co‐precipitation method is developed to synthesize graphitic carbon nanofibers (CNFs) decorated with ZnO nanoparticles (NPs). By interchanging intermediate steps of the reaction processes, two kinds of nanohybrids are fabricated with stark morphological and physicochemical differences. The morphologies differ because of the different chemical environments of the NP/nanocluster formation. The hybrid with larger and non‐uniform ZnO nanocluster size is formed in liquid phase and resulted in considerable interfacial defects that deteriorate the charge‐transfer properties. The hybrid with smaller and uniform ZnO NPs was formed in a dry solid phase and produced near‐defect‐free interfaces, leading to efficient charge transfer for superior photocatalytic performance. The results broaden the understanding of the anchoring/bonding mechanism in ZnO/CNF hybrid formation and may facilitate further development of more effective exfoliation strategies for the preparation of high‐performance composites/hybrids. 相似文献
95.
96.
Dr. Igor V. Pimkov Dr. Barbara Serli‐Mitasev Antoinette A. Peterson Stephen C. Ratvasky Dr. Bernd Hammann Prof. Partha Basu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(47):17057-17072
Molybdopterin is an essential cofactor for all forms of life. The cofactor is composed of a pterin moiety appended to a dithiolene‐functionalized pyran ring, and through the dithiolene moiety it binds metal ions. Different synthetic strategies for dithiolene‐functionalized pyran precursors that have been designed and synthesized are discussed. These precursors also harbor 1,2‐diketone or osone functionality that has been condensed with 1,2‐diaminobenzene or other heterocycles resulting in several quinoxaline or pterin derivatives. Use of additives improves the regioselectivity of the complexes. The molecules have been characterized by 1H and 13C NMR and IR spectroscopies, as well as by mass spectrometry. In addition, several compounds have been crystallographically characterized. The geometries of the synthesized molecules are more planar than the geometry of the cofactor found in proteins. 相似文献
97.
Quasi-Monte Carlo (QMC) sampling has been developed for integration over \([0,1]^s\) where it has superior accuracy to Monte Carlo (MC) for integrands of bounded variation. Scrambled net quadrature allows replication-based error estimation for QMC with at least the same accuracy and for smooth enough integrands even better accuracy than plain QMC. Integration over triangles, spheres, disks and Cartesian products of such spaces is more difficult for QMC because the induced integrand on a unit cube may fail to have the desired regularity. In this paper, we present a construction of point sets for numerical integration over Cartesian products of s spaces of dimension d, with triangles (\(d=2\)) being of special interest. The point sets are transformations of randomized (t, m, s)-nets using recursive geometric partitions. The resulting integral estimates are unbiased, and their variance is o(1 / n) for any integrand in \(L^2\) of the product space. Under smoothness assumptions on the integrand, our randomized QMC algorithm has variance \(O(n^{-1 - 2/d} (\log n)^{s-1})\), for integration over s-fold Cartesian products of d-dimensional domains, compared to \(O(n^{-1})\) for ordinary MC. 相似文献
98.
Dheer Singh Anju Chopra Ravindra Kumar M. I. S. Sastry M. B. Patel B. Basu 《Chromatographia》2014,77(1-2):165-169
EN 14103 is generally used for quantification of ester content in biodiesel free of heptadecanoate ester (C17:0) or methyl nonadecanoate (C19:0), which are employed as internal standards. It was observed that ester content obtained by EN 14103 method did not match with theoretical value of biodiesel, as the method did not take care of response factors of each component to compensate for changes in detector sensitivities. In this study, the whole range of fatty acid (C6–C24:1) methyl esters have been taken into consideration for the calculation of the ester content. Methyl nonadecanoate (C19:0) was used as an internal standard. The response factors of both the saturated and unsaturated methyl esters in the range C6–C24:1 were estimated and found in the range 0.97–1.16. The ester content was calculated after applying the response factors of each methyl ester. The results obtained by this method agreed well with the theoretical value as compared to estimated value using EN14103 method. The results obtained from this method also show good correlation (R 2 = 0.98) with 1H-NMR method. Further, this method does not depend on nature of biodiesel feed stock and is applicable to all methyl biodiesel samples obtained from different raw materials. 相似文献
99.
100.
R. K. Singhal P. K. Sharma M. K. T. Bassan H. Basu A. V. R. Reddy 《Journal of Radioanalytical and Nuclear Chemistry》2011,288(1):149-156
During this work selective separation of uranium from rock phosphate and columbite mineral was done before its quantitative
estimation by using Inductively Coupled Plasma Optical Emission Spectrometery (ICP-OES). Uranium from the rock phosphate and
columubite was extracted by sodium peroxide fusion followed by leaching in 2 M HNO3. To avoid spectral interference in the estimation of uranium by ICP-OES, the selective separation of uranium from the leachate
was carried out by using two different extractants, 30% Tributyl Phophates (TBP) in CCl4 and a equi-volume mixture of Di(2-ethylhexyl) phosphoric acid (D2EHPA) & TBP in petrofin. Uranium was stripped from the organic
phase by using 1 M ammonium carbonate solution. Determination of uranium by ICP-OES was done after dissolving the residue
left after evaporation of ammonium carbonate solution in 4% HNO3. The concentration of the uranium observed in the rock phosphates samples was 40–200 μg g−1 whereas in columbite samples the concentration range was 100–600 μg g−1. Uranium concentration evaluated by ICP-OES was complimented by gamma & alpha spectrometry. Concentration of uranium evaluated
by gamma spectrometry in case of rock phosphate and coulmbite was in close agreement with the uranium content obtained by
ICP-OES. Uranium determination by alpha spectrometry showed only minor deviation (1–2%) from the results obtained by ICP-OES
in case of rock phosphates whereas in case of coulmbites results are off by 20–30%. 相似文献