Kinetic spectrophotometric determination of sulfide, using in-cuvette mixing and titration techniques with computerized data acquisition

In-cuvette mixing and titration techniques have been used for the kinetic determination of sulfide based on its inhibition effect on the oxidation of indigo carmine with hexacyanoferrate(III) in the presence of silver. The reaction was monitored spectrophotometrically by measuring the decrease in absorbance of indigo carmine at 612 nm. Both initial rate and fixed-time methods were applied to the in-cuvette technique. Using in-cuvette mixing, sulfide up to 1800 ng was determined and detection limit and relative standard deviation for the determination of 120 ng of sulfide were calculated as 23.0 ng and 1.59%, respectively. On the basis of the titration technique, the upper limit of determination was 25 μg of sulfide and detection limit and average relative standard deviation for the determination of 1 μg of sulfide were 0.025 μg and 4.95%, respectively. The effect of foreign ions on the sulfide determination was studied. The proposed methods were applied to the determination of sulfide in water. Received: 10 March 1999 / Revised: 9 June 1999 / Accepted: 12 June 1999     

Essential spectra of operator matrices and applications

The main goal of this paper is to give a characterization of Wolf, Schechter, and Browder essential spectra of (2 × 2) matrix operator on a Banach space. Furthermore, we apply the obtained results to transport equations. Copyright © 2013 John Wiley & Sons, Ltd.     

Anisotropic solution of the holographic model of light quarks with an external magnetic field

Theoretical and Mathematical Physics - We find a black hole solution in a five-dimensional fully anisotropic holographic model of light quarks. The model is described by the Einstein action with a...     

Electrochemical characterization of naproxen and the adsorbed naproxen oxidation products at glassy carbon electrode modified with carboxyl functionalized multi-walled carbon nanotubes and introducing a new route for naproxen determination

Journal of Solid State Electrochemistry - In the present work, a glassy carbon electrode was modified with carboxyl functionalized multi-walled carbon nanotubes (f-MWCNTs) to investigate the...     

Buckling analysis of functionally graded arbitrary straight-sided quadrilateral plates on elastic foundations

As a first endeavor, the buckling analysis of functionally graded (FG) arbitrary straight-sided quadrilateral plates rested on two-parameter elastic foundation under in-plane loads is presented. The formulation is based on the first order shear deformation theory (FSDT). The material properties are assumed to be graded in the thickness direction. The solution procedure is composed of transforming the governing equations from physical domain to computational domain and then discretization of the spatial derivatives by employing the differential quadrature method (DQM) as an efficient and accurate numerical tool. After studying the convergence of the method, its accuracy is demonstrated by comparing the obtained solutions with the existing results in literature for isotropic skew and FG rectangular plates. Then, the effects of thickness-to-length ratio, elastic foundation parameters, volume fraction index, geometrical shape and the boundary conditions on the critical buckling load parameter of the FG plates are studied.     

Photophysical Properties and Kinetic Studies of 2-Vinylpyridine-Based Cycloplatinated(II) Complexes Containing Various Phosphine Ligands

A series of cycloplatinated(II) complexes with general formula of [PtMe(Vpy)(PR₃)], Vpy = 2-vinylpyridine and PR₃ = PPh₃ (1a); PPh₂Me (1b); PPhMe₂ (1c), were synthesized and characterized by means of spectroscopic methods. These cycloplatinated(II) complexes were luminescent at room temperature in the yellow–orange region’s structured bands. The PPhMe₂ derivative was the strongest emissive among the complexes, and the complex with PPh₃ was the weakest one. Similar to many luminescent cycloplatinated(II) complexes, the emission was mainly localized on the Vpy cyclometalated ligand as the main chromophoric moiety. The present cycloplatinated(II) complexes were oxidatively reacted with MeI to yield the corresponding cycloplatinated(IV) complexes. The kinetic studies of the reaction point out to an S_N2 mechanism. The complex with PPhMe₂ ligand exhibited the fastest oxidative addition reaction due to the most electron-rich Pt(II) center in its structure, whereas the PPh₃ derivative showed the slowest one. Interestingly, for the PPhMe₂ analog, the trans isomer was stable and could be isolated as both kinetic and thermodynamic product, while the other two underwent trans to cis isomerization.     

Performance analysis of an integrated cooling system consisted of earth-to-air heat exchanger (EAHE) and water spray channel

This study evaluates the cooling performance of a new hybrid system composing of an earth-to-air heat exchanger (EAHE) and a water spray channel to provide thermal comfort in Tehran, Iran. The inlet air temperature passing through the EAHE dissipates its heat to the surrounding soil and become slightly colder. To reach thermal comfort, the pre-cooled air flows upward through a channel spraying water downward and enters the living space. Considering the evaporative thermal comfort zone, the results showed that this system can meet comfort conditions for summer season Tehran. Moreover, according to the results, the cooling effectiveness of the proposed hybrid system is more than 100%, which means that the integrated system is capable of decreasing the air dry-bulb temperature below the inlet ambient wet-bulb temperature. Employing ground as a reliable source of alternative energy, the proposed cooling system can be considered an eco-friendly and energy-efficient system. Therefore, the introduced cooling system can be utilized as an alternative to conventional evaporative coolers or mechanical vapor compression systems while it can be considered an eco-friendly and energy-efficient system.

     

Applying different types of artificial neural network for modeling thermal conductivity of nanofluids containing silica particles

Journal of Thermal Analysis and Calorimetry - Nanofluids are widely applicable in thermal devices with porous structures. Silica nanoparticles have been dispersed in different heat transfer fluids...