Synthesis and crystal structure of [Re2Cl2(CO)6(S e)]

The dinuclear complex [Re₂Cl₂(CO)₆S e] has been prepared and characterized in the solid state by X-ray crystallography. Proton NMR spectroscopy has shown the structure to be stereochemically rigid in solution.     

Flow past a cylinder: shear layer instability and drag crisis

Flow past a circular cylinder for Re=100 to 10⁷ is studied numerically by solving the unsteady incompressible two‐dimensional Navier–Stokes equations via a stabilized finite element formulation. It is well known that beyond Re ～ 200 the flow develops significant three‐dimensional features. Therefore, two‐dimensional computations are expected to fall well short of predicting the flow accurately at high Re. It is fairly well accepted that the shear layer instability is primarily a two‐dimensional phenomenon. The frequency of the shear layer vortices, from the present computations, agree quite well with the Re^0.67 variation observed by other researchers from experimental measurements. The main objective of this paper is to investigate a possible relationship between the drag crisis (sudden loss of drag at Re ～ 2 × 10⁵) and the instability of the separated shear layer. As Re is increased the transition point of shear layer, beyond which it is unstable, moves upstream. At the critical Reynolds number the transition point is located very close to the point of flow separation. As a result, the shear layer eddies cause mixing of the flow in the boundary layer. This energizes the boundary layer and leads to its reattachment. The delay in flow separation is associated with narrowing of wake, increase in Reynolds shear stress near the shoulder of the cylinder and a significant reduction in the drag and base suction coefficients. The spatial and temporal power spectra for the kinetic energy of the Re=10⁶ flow are computed. As in two‐dimensional isotropic turbulence, E(k) varies as k^?5/3 for wavenumbers higher than energy injection scale and as k^?3 for lower wavenumbers. The present computations suggest that the shear layer vortices play a major role in the transition of boundary layer from laminar to turbulent state. Copyright © 2004 John Wiley & Sons, Ltd.     

A simple and efficient method for solvent-free iodination of hydroxylated aromatic aldehydes and ketones using iodine and iodic acid by grinding method

<正>Green,mild and efficient iodination of hydroxylated aromatic aldehydes and ketones using iodine and iodic acid in the solidstate by grinding under solvent-free conditions at room temperature.This method provides several advantages such as environmentally friendly,short reaction times,high yields,non-hazardous and simple work-up procedure.     

Sedimentation analysis of organic–inorganic hybrid colloids

Hybrid organic–inorganic latex particles are synthesized to combine the beneficial properties of the constituents which thus lead to synergistic improvement in the properties. The properties of hybrid particles are dependent on the successful hybridization process, thus controlling or tuning of such processes by effective characterization is immensely important. Analytical ultracentrifugation provides these characterization possibilities owing to its high statistical capability and ability to characterize multiple parameters. The use of different detection methodologies can help in generating valuable information on the overall size and density distributions of the particles. Apart from that, it is also possible to quantify the presence of any free polymer and inorganic particles in the hybrid latex which would affect the properties of hybrid latexes. By following the densities of the pure and hybrid particles, it is also possible to quantify the amounts of the constituent phases in the hybrid particles. The density gradients generated in preparative ultracentrifugation also provide additional possibilities for the characterization of the hybrid particles which have densities higher than the measurable range in the analytical ultracentrifuge. Evolution of hybrid particles can also be studied as a function of time. It also provides advantage of separation of the various fractions for further characterization.     

Determination of amoxapine and nortriptyline in blood plasma and serum by salt-assisted liquid-liquid microextraction and high-performance liquid chromatography

A new, selective and sensitive method has been developed for the determination of tricyclic antidepressant drugs, amoxapine and nortriptyline, in human blood plasma and serum, involving their reaction with allyl isothiocyanate and extraction of thiourea derivatives with water-miscible organic solvent acetonitrile. The phase separation was effected by addition of ammonium sulphate, a process called salt-assisted liquid-liquid microextraction. The extract was analyzed by HPLC with UV detection at 254?nm. The method has been optimized for derivatization reaction time and temperature, solvent for extraction, and salt for solvent phase separation. Under the optimal conditions, a linear calibration graph was obtained between the amount of drug and the peak area of thiourea derivatives in the range of 0.002-20?mg/L drugs. The correlation coefficient and limit of detection values for amoxapine and nortriptyline in serum/plasma samples were in the range of 0.9953-0.9999 and 0.46-0.58?μg/L, respectively. The recovery in spiking experiments ranged, respectively, 75-88% (RSD 3.4-7.2%) and 79-97% (RSD 3.7-7.9%) for the two drugs.     

A High-Order Immersed Boundary Method for Acoustic Wave Scattering and Low-Mach Number Flow-Induced Sound in Complex Geometries

A new sharp-interface immersed boundary method based approach for the computation of low-Mach number flow-induced sound around complex geometries is described. The underlying approach is based on a hydrodynamic/acoustic splitting technique where the incompressible flow is first computed using a second-order accurate immersed boundary solver. This is followed by the computation of sound using the linearized perturbed compressible equations (LPCE). The primary contribution of the current work is the development of a versatile, high-order accurate immersed boundary method for solving the LPCE in complex domains. This new method applies the boundary condition on the immersed boundary to a high-order by combining the ghost-cell approach with a weighted least-squares error method based on a high-order approximating polynomial. The method is validated for canonical acoustic wave scattering and flow-induced noise problems. Applications of this technique to relatively complex cases of practical interest are also presented.     

On simplifying ‘incremental remap’–based transport schemes

The flux-form incremental remapping transport scheme introduced by Dukowicz and Baumgardner [1] converts the transport problem into a remapping problem. This involves identifying overlap areas between quadrilateral flux-areas and regular square grid cells which is non-trivial and leads to some algorithm complexity. In the simpler swept area approach (originally introduced by Hirt et al. [2]) the search for overlap areas is eliminated even if the flux-areas overlap several regular grid cells. The resulting simplified scheme leads to a much simpler and robust algorithm.