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51.
Franco FernándezXerardo Garc?&#x;a-Mera José Enrique Rodr?&#x;guez-BorgesMar?&#x;a Luisa C. Vale 《Tetrahedron letters》2003,44(3):431-433
The recently reported compound (+)-(1R,endo)-2-benzonorbornenol (2) proved to be an efficient chiral auxiliary in the asymmetric aza-Diels-Alder reaction between cyclopentadiene and the N-benzyl imine of its glyoxylate, which afforded a virtually all-exo mixture of cycloaducts with a 1S:1R diastereomeric ratio of 63:37. 相似文献
52.
Andrade Eiroa A Vázquez Blanco E López Mahía P Muniategui Lorenzo S Prada Rodríguez D 《The Analyst》2000,125(7):1321-1326
Two spectrofluorimetric methods, second-derivative constant-energy synchronous luminescence (SDCESL) and constant-wavelength synchronous luminescence (CWSL) in combination with multiple linear regression (MLR), for the quantification of benzo[a]pyrene (BaP) at sub-ng mL-1 levels, in the presence of benzo[b]fluoranthene (BbFt), benzo[k]fluoranthene (BkFt), benzo[ghi]perylene (BghiP) and indeno[1,2,3-cd]pyrene (IP), were developed and compared in detail. SDCESL presents lower limits of detection and quantification than CWSL/MLR and also gives more exact and precise results for levels close to the quantification limit. For BaP, SDCESL achieved quantification limits of 0.019 ng mL-1 in river waters and 0.007 ng mL-1 in drinking waters. This work offers a sensitive, precise, accurate, rapid, simple and economic methodology for monitoring BaP in waters for public consumption, meeting all the requirements of the EC Directive 98/83/CE that fixes the maximum admissible limit for this polycyclic aromatic hydrocarbon in drinking waters at of 0.010 ng mL-1. 相似文献
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Miguel A. Bañares Amador Angoso Juan L. Manzano Emilio Rodríguez 《Transition Metal Chemistry》1987,12(2):149-152
Summary Cobalt(II) chlorocomplexes with empirical formulae (bnH2)2CoCl6·2H2O (1) and (bnH2)2CoCl6 (2), where bnH
2
2+
represents the diprotonated species of putrescine (1,4-butanediamine), were prepared.The visible spectra in the solid state and measurement of the magnetic moments permit the assignation of an octahedral geometry for cobalt in (1) and a tetrahedral geometry for (2). 相似文献
55.
Rodríguez A Muñoz M del Mar Graciani M Fernández Chacón S Moyá ML 《Langmuir : the ACS journal of surfaces and colloids》2004,20(23):9945-9952
The spontaneous hydrolysis of phenyl chloroformate was studied in water-ethylene glycol, EG, cationic, zwitterionic, nonionic, and anionic micellar solutions, the surfactants being tetradecyltrimethylammonium bromide, tetradecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate, tricosaoxyethylene glycol ether, and sodium dodecyl sulfate. The dependence of the observed rate constant on surfactant concentration as well as on the percentage by weight of EG, varying from 0 to 50 wt %, was investigated. Information about changes in the critical micelle concentrations, in the micellar ionization degrees (for ionic surfactants), in the aggregation numbers, and in the polarity of the interfacial region of the micelles upon changing the weight percent of EG was obtained through conductivity, surface tension, spectroscopic, and fluorescence measurements. A simple pseudophase model was adequate to rationalize the kinetic data. Micellar medium effects were explained by considering charge-charge interactions and polarity, ionic strength, and water content in the micellar interfacial region. The acceleration of the reaction produced by an increase in the amount of EG present in the mixture was explained on the basis of the substantial decrease in the equilibrium binding constant of phenyl chloroformate molecules to the micelles, resulting in the contribution of the reaction taking place in the bulk water-EG phase being more important. The weight percent of EG did not substantially influence the rate constant in the micellar pseudophase. 相似文献
56.
Regás D Afonso MM Rodríguez ML Palenzuela JA 《The Journal of organic chemistry》2003,68(20):7845-7852
The reaction of vinyl allenes with imines under Lewis acid catalysis has been explored. Vinyl allenes in which the allenic portion of the molecule is tri- or tetrasubstituted gave octahydroquinoline derivatives as single isomers together with a minor compound formed by an ene reaction of the imine with the allene. Compounds in which the allene is 1,3-disubstituted do not react under the conditions assayed. 相似文献
57.
Constantino E Rodríguez-Santiago L Sodupe M Tortajada J 《The journal of physical chemistry. A》2005,109(1):224-230
Cobalt cations are open shell systems with several possible electronic states arising from the different occupations of the 3d and 4s orbitals. The influence of these occupations on the relative stability of the coordination modes of the metal cation to glycine has been studied by means of theoretical methods. The structure and vibrational frequencies have been determined using the B3LYP method. Single-point calculations have also been carried out at the CCSD(T) level. The most stable structure of Co(+)-glycine is bidentate, with the Co(+) cation interacting with the amino group and the carbonyl oxygen of neutral glycine, and the ground electronic state being (3)A. For Co(2+)-glycine, the lowest energy structure corresponds to the interaction of the metal cation with the carboxylate group of the zwitterionic glycine, the ground electronic state being (4)A'. 相似文献
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