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101.
102.
103.
Gomila A Le Poul N Cosquer N Kerbaol JM Noël JM Reddy MT Jabin I Reinaud O Conan F Le Mest Y 《Dalton transactions (Cambridge, England : 2003)》2010,39(48):11516-11518
We report the self-induced "electroclick" immobilization of the [Cu(II)(6-ethynyl-TMPA)(H(2)O)](2+) complex, by its simple electro-reduction, onto a mixed azidoundodecane-/decane-thiol modified gold electrode. The redox response of the grafted [Cu(II/I)(TMPA)] at the modified electrode is fully reversible indicating no Cu coordination change and a fast electron transfer. 相似文献
104.
Vincent Larraillet Aleksey Vorobyev Claire Brunet Jér?me Lemoine Yury O. Tsybin Rodolphe Antoine Philippe Dugourd 《Journal of the American Society for Mass Spectrometry》2010,21(4):670-680
We compare product-ion mass spectra produced by electron detachment dissociation (EDD) and electron photodetachment dissociation
(EPD) of multi-deprotonated peptides on a Fourier transform and a linear ion trap mass spectrometer, respectively. Both methods,
EDD and EPD, involve the electron emission-induced formation of a radical oxidized species from a multi-deprotonated precursor
peptide. Product-ion mass spectra display mainly fragment ions resulting from backbone cleavages of Cα-C bond ruptures yielding a and x ions. Fragment ions originating from N-Cα backbone bond cleavages are also observed, in particular by EPD. Although EDD and EPD methods involve the generation of a
charge-reduced radical anion intermediate by electron emission, the product ion abundance distributions are drastically different.
Both processes seem to be triggered by the location and the recombination of radicals (both neutral and cation radicals).
Therefore, EPD product ions are predominantly formed near tryptophan and histidine residues, whereas in EDD the negative charge
solvation sites on the backbone seem to be the most favorable for the nearby bond dissociation. 相似文献
105.
Pearson and Bellissard recently built a spectral triple – the data of Riemannian noncommutative geometry – for ultrametric Cantor sets. They derived a family of Laplace–Beltrami
like operators on those sets. Motivated by the applications to specific examples, we revisit their work for the transversals
of tiling spaces, which are particular self-similar Cantor sets. We use Bratteli diagrams to encode the self-similarity, and Cuntz–Krieger algebras to implement it. We show that the abscissa of convergence of the ζ-function of the spectral triple gives indications on the exponent of complexity of the tiling. We determine completely the
spectrum of the Laplace–Beltrami operators, give an explicit method of calculation for their eigenvalues, compute their Weyl
asymptotics, and a Seeley equivalent for their heat kernels. 相似文献
106.
Antoni T Kuhn AG Briant T Cohadon PF Heidmann A Braive R Beveratos A Abram I Le Gratiet L Sagnes I Robert-Philip I 《Optics letters》2011,36(17):3434-3436
We have designed photonic crystal suspended membranes with optimized optical and mechanical properties for cavity optomechanics. Such resonators sustain vibration modes in the megahertz range with quality factors of a few thousand. Thanks to a two-dimensional square lattice of holes, their reflectivity at normal incidence at 1064?nm reaches values as high as 95%. These two features, combined with the very low mass of the membrane, open the way to the use of such periodic structures as deformable end mirrors in Fabry-Perot cavities for the investigation of cavity optomechanical effects. 相似文献
107.
In algorithmic randomness, when one wants to define a randomness notion with respect to some non-computable measure λ, a choice needs to be made. One approach is to allow randomness tests to access the measure λ as an oracle (which we call the “classical approach”). The other approach is the opposite one, where the randomness tests are completely effective and do not have access to the information contained in λ (we call this approach “Hippocratic”). While the Hippocratic approach is in general much more restrictive, there are cases where the two coincide. The first author showed in 2010 that in the particular case where the notion of randomness considered is Martin-Löf randomness and the measure λ is a Bernoulli measure, classical randomness and Hippocratic randomness coincide. In this paper, we prove that this result no longer holds for other notions of randomness, namely computable randomness and stochasticity. 相似文献
108.
We prove that every closed subgroup of a locally compact group is locally p -Ditkin for 1<p<∞. 相似文献
109.
Pierre Antoine Grillet 《Semigroup Forum》1995,50(1):317-326
An explicit upper bound is given for the number of commutative semigroups withn elements. 相似文献
110.
The condensation reaction between polymerised formaldehyde and a ketone possessing a methylene group α to the carbonyl function, in the presence of a polystyrene (1) or fluorinated (2) ion-exchange catalyst, leads to the corresponding 1,3-dioxane and is characterized by excellent yield and selectivity. 相似文献