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81.
A strong electric susceptibility is measured as a function of temperature in a molecular dimer which is weakly bound by a pair of hydrogen bonds. This system is a remarkable example where the dominant term in the susceptibility is due to a vibration induced electric dipole. As a consequence, the averaged square of the dipole moment varies linearly with the temperature and the susceptibility does not follow the usual 1/T Curie law. this spectacular effect demonstrates the importance of dynamics to interpret the properties of weakly bound complexes. 相似文献
82.
83.
84.
85.
We examine the robustness of ultrashort optical vortices propagating freely in the atmosphere. We first approximate the stability regions of femtosecond spinning pulses as a function of their topological charge. Next, we numerically demonstrate that atmospheric optical vortices are capable of conveying high power levels in air over hundreds of meters before they break up into filaments. 相似文献
86.
Stable polar oxide surfaces must be simultaneously electrostatically compensated and in thermodynamic equilibrium with the environment. As a paradigm, the MgO(111)-p(2x2) reconstructed surface is shown to involve combinations of Mg-covered terminations with peculiar insulating electronic structure, favored in O-poor conditions, and the O-terminated octopole, stabler in more O-rich environments. Such a picture, which could not have been foreseen by either experiments or simulations separately, goes beyond the Wolf model and reconciles the theory with the experimental data taken in variable thermodynamic conditions. 相似文献
87.
Luis A.?CaffarelliEmail author Ki-Ahm?Lee Antoine?Mellet 《Archive for Rational Mechanics and Analysis》2004,172(2):153-190
This paper is concerned with a class of singular equations modelling the combustion of premixed gases in periodic media. The model involves two parameters: the period of the medium |L| and a singular parameter related to the activation energy. The existence of pulsating travelling fronts for fixed and |L| was proved by Berestycki & Hamel in [BH]. In the present paper, we investigate the behaviour of such solutions when
More precisely, we establish that pulsating travelling fronts behave like travelling waves, when the period |L| is small and . We also study the convergence of the solution, as goes to zero (and |L| is fixed), toward a solution of a free boundary problem. 相似文献
88.
Antoine?AyacheEmail author Murad S.?Taqqu 《Journal of Fourier Analysis and Applications》2003,9(5):451-471
Consider the fractional Brownian motion process $B_H(t), t\in [0,T]$,
with parameter $H\in (0,1)$.
Meyer, Sellan and Taqqu have developed
several random wavelet representations for
$B_H(t)$, of the form $\sum_{k=0}^\infty
U_k(t)\epsilon_k$ where $\epsilon_k$ are Gaussian random
variables and where the functions $U_k$ are not random. Based on the
results of Kühn and Linde, we say that the
approximation $\sum_{k=0}^n U_k(t)\epsilon_k$ of $B_H(t)$
is optimal if
$$
\displaystyle
\left( E \sup_{t\in [0,T]} \left| \sum_{k=n}^\infty U_k(t)
\epsilon_k\right|^2 \right)^{1/2} =O
\left( n^{-H} (1+\log n)^{1/2} \right),
$$
as $n\rightarrow\infty$. We show that the random wavelet
representations given in Meyer, Sellan and
Taqqu are optimal. 相似文献
89.
A time-domain formulation for the flexural vibrations in damped rectangular isotropic and orthotropic plates is developed, in order to investigate transient excitation of plates by means of sound synthesis. The model includes three basic mechanisms of damping (thermoelasticity, viscoelasticity and radiation) using a general differential operator. The four rigidity factors of the plate are modified by perturbation terms, each term corresponding to one specific damping mechanism. The first damping term is derived from the coupling between the thermoelastic stress-strain relations and the heat diffusion equation. The second term is obtained from the general differential formulation of viscoelasticity. The third term is obtained through a Pade approximation of the damping factor which governs the coupling of the plate with the surrounding air. The decay factors predicted by the model reproduce adequately the dependence on both dimensions and frequency of the decay factors measured on rectangular plates of various sizes and thicknesses made of four different materials (aluminum, glass, carbon fiber, and wood). The numerical resolution of the complete problem, including initial and boundary conditions, and the comparison between real and simulated sounds are presented in a companion paper. 相似文献
90.
Lambourg C Chaigne A Matignon D 《The Journal of the Acoustical Society of America》2001,109(4):1433-1447
A time-domain model for the flexural vibrations of damped plates was presented in a companion paper [Part I, J. Acoust. Soc. Am. 109, 1422-1432 (2001)]. In this paper (Part II), the damped-plate model is extended to impact excitation, using Hertz's law of contact, and is solved numerically in order to synthesize sounds. The numerical method is based on the use of a finite-difference scheme of second order in time and fourth order in space. As a consequence of the damping terms, the stability and dispersion properties of this scheme are modified, compared to the undamped case. The numerical model is used for the time-domain simulation of vibrations and sounds produced by impact on isotropic and orthotropic plates made of various materials (aluminum, glass, carbon fiber and wood). The efficiency of the method is validated by comparisons with analytical and experimental data. The sounds produced show a high degree of similarity with real sounds and allow a clear recognition of each constitutive material of the plate without ambiguity. 相似文献