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191.
An attempt is made to synthesize Nd2Co14C compound by mechanical alloying Nd16Co76B8−xCx (0x8) alloys and subsequent annealing. Phase formation and magnetic properties of Nd2Fe14B-type Nd16Co76B8−xCx alloys and their hydrides are investigated. The Nd2Co14(B,C) phase with Nd2Fe14B-type structure is formed for Nd16Co76B8−xCx (0x7) alloys, while NdCo7Cδ phase with TbCu7-type structure is observed in Nd16Co76C8 alloy. The lattice parameter c of the Nd2Co14(B,C) phase decreases with increasing the carbon content. A limit volume of the unit cell to form the Nd2Fe14B-type structure is estimated to be 0.870 nm3. The spin-reorientation temperature TSR increases with increasing the carbon content, due to an enhancement of magnetocrystalline anisotropy caused by carbon substitution for boron. After hydrogenation, the lattice expansion is observed for Nd16Co76B8−xCx (0x7) alloys. The spin-reorientation temperature of Nd16Co76B8−xCxHy (0x7) is much lower than that of the host alloys. Some structural and magnetic properties of hypothetic Nd2Co14C and Nd2Co14CHy compounds are estimated by extrapolation. 相似文献
192.
The EPR parameters (g factors and hyperfine structure constants A) for the tetragonal Ti3+ center in cubic phase and the rhombic Ti3+ center in tetragonal phase in the neutron-irradiated SrTiO3 crystals are calculated from the third-order perturbation formulas of EPR parameters for d1 ions. These low-symmetry Ti3+ centers in both phases of SrTiO3 are due to the Ti3+ ion at “off center” on the Sr2+ site. From the calculation, the defect models (including the direction and magnitude of the Ti3+ off-center displacement) of the two Ti3+ centers in SrTiO3 are estimated and the EPR parameters of both Ti3+ centers are reasonably explained on the basis of the defect models. The results are discussed. 相似文献
193.
A novel dicalix[4]pyrrolyl-substituted 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dye I with an absorption peak at approximately 670 nm and an emission peak at about 690 nm was prepared. As an anion receptor,
I displayed a red shift in absorption spectra and fluorescence quenching in varying degrees in the presence of F−, AcO−, H2PO4−, or Cl−. Compared with the parent calix[4]pyrrole, a representative anion receptor, I exhibited a stronger affinity to these anions due to the formation of a sandwich complex through multiple hydrogen-bonding
interactions. 相似文献
194.
195.
Enhanced targeted energy transfer for adaptive vibration suppression of pipes conveying fluid 总被引:1,自引:0,他引:1
Nonlinear Dynamics - In this paper, a nonlinear energy sink and a negative stiffness element are integrated for achieving enhanced, passive, and adaptive vibration suppression for a pipe conveying... 相似文献
196.
Xiangyu Xu Dianqing Li Jiaqing Song Yanjun Lin Zhi Lv Min Wei Xue Duan 《Particuology》2010,8(3):198-201
A clean method for preparing layered double hydroxides (LDHs) has been developed, featured by using the hydroxides of two different metals as starting materials by atom-economic reaction. The reactions were carried out under hydrothermal conditions in either a high pressure autoclave or a microwave digester. The compositions, structural parameters and thermal behavior of the resulting LDHs are very similar to those of materials produced by using the separate nucleation and aging steps (SNAS) method. The major advantage of the new method is that no by-product is produced, so that filtration and washing processes are unnecessary. The consequent reduction in water consumption is beneficial to the environment. 相似文献
197.
In this paper, a three-species food chain model is analytically investigated on theories of ecology and using numerical simulation. Bifurcation diagrams are obtained for biologically feasible parameters. The results show that the system exhibits rich complexity features such as stable, periodic and chaotic dynamics. 相似文献
198.
Xia Li Min Lu Qi Wu De‐shui Lv Xian‐Fu Lin 《Journal of polymer science. Part A, Polymer chemistry》2008,46(1):117-126
To develop designed polymer–drug conjugates, where the rate of drug liberation and hepatoma cell targeting function could be rationally and widely controlled, we facilely synthesized a series of novel, galactose‐functionalized polymer–acyclovir conjugates with different linkers and first reported the effect of the linker structure including the type of acyclovir‐linked bond (an ester bond or an amide bond) and relative length of the linker between acyclovir and the polymer main chain on release rate and targeting ability of conjugates. In vitro release studies showed that the cumulative released acyclovir from these polymer–acyclovir conjugates was between 24 and 65% in pH 1.2 glycine solution after 7 days. The ester bond more easily underwent hydrolysis than the amide bond. The longer the relative linker length was, the faster the acyclovir was released. The cell recognition experiments visualized using confocal laser scanning microscopy exhibited that the resultant galactose‐functionalized polymer–acyclovir conjugates had evident targeting to hepG2 cells, and targeting ability was also in connection with the relative length of linker. By choosing appropriate linker, cellular internalization of acyclovir could be well achieved. We consider these results to be helpful for the design of multifunctional polymeric prodrugs, in which the required release rate and targeting ability could be rationally controlled by predetermined molecular architecture. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 117–126, 2008 相似文献
199.
Chong Jia Yong Su Qingtao Zhou Minjun Xin Yousheng Lv Weihai Kong 《Applied Surface Science》2008,254(8):2331-2335
Large scale flower-like ZnO nanosheets have been synthesized on Zinc foil by a simple hydrothermal method. Their morphology and microstructures were characterized and analyzed by X-ray spectroscopy (XRD), field emission scanning electron microscopy (FE-SEM) and high-resolution transmission electron microscopy (HRTEM). The as-synthesized flower-like nanosheets are hexagonal phase single crystal with 200-300 nm in width, 50 nm in thickness. The growth process follows the liquid phase epitaxial growth mechanism. In this approach, the ZnO buffer is used as substrate for the growth of flower-like ZnO nanosheets. The growth direction of the nanosheets is the preferential [0 0 0 1] growth direction of ZnO. The photoluminescence spectrum of the sample exhibits only a sharp and strong UV emission centered at 386 nm, which indicates that the flower-like ZnO nanosheets on Zn foil are of good optical property. 相似文献
200.
This paper is concerned with eigenvalues of perturbed second-order vector discrete Sturm–Liouville problems. By some variational properties of eigenvalues of discrete Sturm–Liouville problems, error estimates of eigenvalues of perturbed problems, sufficiently close to a given Sturm–Liouville problem, are given under a certain non-singularity condition. Perturbations of the coefficient functions of the difference equation, the weight function, and the coefficients of the boundary condition are all considered. This, together with higher-dimension involved, results in a certain complexity of the problem and difficulty of study. As a direct consequence, continuous dependence of eigenvalues on problems is obtained under the non-singularity condition. In addition, an example is presented to illustrate the necessity of the non-singularity condition. 相似文献