Concentration-dependent luminescence of Tb ions in high calcium aluminosilicate glasses

This study deals with the results on the concentration-dependent fluorescence properties of Tb³⁺-doped calcium aluminosilicate (CAS) glasses of composition (100−x)(58SiO₂–23CaO–5Al₂O₃–4MgO–10NaF in mol%)-x Tb₂O₃ (x=0, 0.25, 0.5, 1, 2, 4, 8, 16, 24, 32, 40 in wt%). The FTIR reflectance spectra suggested the role of dopant ions as network modifiers in the glass network. The fluorescence spectra of low Tb³⁺-doped glasses have revealed prominent blue and green emissions from ⁵D₃ and ⁵D₄ excited levels to ⁷F_j ground state multiplet, respectively. The glass with 2 wt% of Tb₂O₃ has exhibited maximum intensity of blue emission from ⁵D₃ level, while green emission from ⁵D₄ level has increased linearly up to 24 wt% and showed reduction in the rate of increase for higher Tb₂O₃ concentrations. The concentration quenching of blue emission (⁵D₃→⁷F_j) is attributed mainly to the resonant energy transfer (RET) assisted cross-relaxation (CR) among the excited and nearest neighbour unexcited Tb³⁺ ions in the glass matrix. The decline in rate of increase of green emission (⁵D₄→⁷F_j) at higher concentrations has been explained due to a possible occurrence of cooperative energy transfers leading to 4f⁸→4f⁷5d transition interactions. The blue and green emission decay kinetics have been recorded to compute the excited level (⁵D₃ and ⁵D₄) lifetimes, which confirmed the Tb³⁺ concentration quenching of the blue emission in these glasses.     

Multiple Responses Optimization and Modeling of Lipase Production by <Emphasis Type="Italic">Rhodotorula mucilaginosa</Emphasis> MTCC-8737 Using Response Surface Methodology

Response surface methodology was employed to optimize culture medium for production of lipase with Rhodotorula sp. MTCC 8737. In the first step, a Plackett–Burman design was used to evaluate the effects of different inducers qualitatively. Of all the seven inducers tested, soybean oil showed significant influence on the lipase production. Further, response surface studies were conducted to quantitatively optimize by considering linear, interactive, and quadratic effects of test variables. A novel approach was proposed to optimize the lipase production system by optimizing the responses in terms of yield kinetics rather than optimizing the direct responses like lipase titer and biomass growth. The coefficient of determination (R ²) calculated for Y _P/S (0.769), Y _P/X (0.799), and Y _X/S (0.847) indicated that the statistical model could explain 76.9%, 79.99%, and 84.7% of variability in the response.     

Dielectric and phase transition of BaTi<Subscript>0.6</Subscript>Zr<Subscript>0.4</Subscript>O<Subscript>3</Subscript> ceramics prepared by a soft chemical route

BaTi_0.6Zr_0.4O₃ (BTZ) ceramic was synthesized by a soft chemical route. X-ray diffraction at room temperature shows that the sample has cubic perovskite structure with space group Pm-3m. Temperature dependent dielectric study of the sample has been investigated in the frequency range from 50 Hz to 1 MHz. The density of the sample was determined using Archimedes’ principle and found to be ∼ 97% of the X-ray density. The average grain size in the pallet was found to be ∼ 1 μm. The dielectric constant peaks at temperature T_m which is dependent on the frequency. The dielectric relaxation rate follows the Vogel–Fulcher relation with activation energy = 0.0185 eV, and freezing temperature = 186 K. All these measurements confirm that BTZ is a relaxor ferroelectric. PACS 77.22.Jp; 77.84.-s; 77.80.Bh; 77.22.Gm     

Optimal placement and sizing of capacitor using Limaçon inspired spider monkey optimization algorithm

The power system is a complex interconnected network which can be subdivided into three components: generation, distribution, and transmission. Capacitors of specific sizes are placed in the distribution network so that losses in transmission and distribution is minimum. But the decision of size and position of capacitors in this network is a complex optimization problem. In this paper, Limaçon curve inspired local search strategy (LLS) is proposed and incorporated into spider monkey optimization (SMO) algorithm to deal optimal placement and the sizing problem of capacitors. The proposed strategy is named as Limaçon inspired SMO (LSMO) algorithm. In the proposed local search strategy, the Limaçon curve equation is modified by incorporating the persistence and social learning components of SMO algorithm. The performance of LSMO is tested over 25 benchmark functions. Further, it is applied to solve optimal capacitor placement and sizing problem in IEEE-14, 30 and 33 test bus systems with the proper allocation of 3 and 5-capacitors. The reported results are compared with a network without a capacitor (un-capacitor) and other existing methods.     

The Mordell-Weil bases for the elliptic curve y2 = x3 − m2x + m2

Czechoslovak Mathematical Journal - Let Dm be an elliptic curve over ? of the form y2 = x3 ? m2x + m2, where m is an integer. In this paper we prove that the two points P?1 =...     

Application of medium energy plasma focus device in study of radioisotopes

Pulsed neutrons generated in a plasma focus device are used for the thermal neutron activation analysis (TNAA) of selected three elements having widely different half-lives varying from a few seconds to a few days [Dysprosium (Dy), Manganese (Mn) and Gold (Au)]. Neutron pulse having strength of $(1.2\pm 0.3)\times {10}^9$ neutrons/pulse with a pulse width of $46\pm 5\text{ns}$ is produced by “MEPF-12” device operated at a filling gas (deuterium + 0.5% krypton) pressure of 3 mbar. The fast 2.45 MeV D–D neutrons are thermalized before irradiating the sample. The decay gammas from the radioisotopes ^165mDy ($T_{1/2}=1.26\text{min.}$), ⁵⁶Mn ($T_{1/2}=2.58\text{hrs.}$), and ¹⁹⁸Au ($T_{1/2}=2.69\text{days}$) produced via reactions, ¹⁶⁴Dy($n,\gamma$)^165mDy, ⁵⁵Mn($n,\gamma$) ⁵⁶Mn, and ¹⁹⁷Au($n,\gamma$) ¹⁹⁸Au respectively are counted off-line in a lead shielded well type $76\times 76{\text{mm}}^2$ NaI(Tl) detector coupled to a calibrated 2048 channel analyzer. The values of half-lives evaluated from the measured decay gammas, $1.43\pm 0.3\text{min.}$, $2.56\pm 0.5\text{hrs.}$ and $2.84\pm 0.6\text{days}$ respectively for the radioisotopes of Dy, Mn and Au, are seen to be close to the values reported in literature.     

Facile synthesis of additive-assisted nano goethite powder and its application for fluoride remediation

The present article describes a novel synthesis route for nano-sized goethite (α-FeOOH) using hydrazine sulphate as an additive. The X-ray diffraction (XRD) peaks of synthesized powder matched well with those of α-FeOOH. Transmission electron microscopy (TEM) showed the particles of irregular shape in the range of 1–10 nm. Batch adsorption experiments for fluoride uptake were performed to study the influence of various experimental parameters such as contact time (10 min to 7 h), initial fluoride concentration (10–150 mg L⁻¹), pH (2–11.6) and the presence of competing anions. The time data fitted well to pseudo-second-order kinetic model. The fluoride removal passed through broad maxima in pH ranges of 6–8. High adsorption capacity of 59 mg g⁻¹ goethite was obtained. The isothermic data fitted well to Freundlich model. The presence of other ions namely chloride and sulphate adversely affected fluoride removal. Fluoride from contaminated water sample could be successfully brought down from 10.25 to 0.5 mg L⁻¹.     

Line broadening studies in low energy plasma focus

Optical emission spectroscopic studies were carried out to characterise the plasma leading to the estimation of two plasma parameters, electron density and temperature. These experiments were conducted on a 2 kJ plasma device which is equipped with squirrel cage electrode configuration enclosed in a glass vacuum chamber filled with hydrogen at a pressure of 5 mbar. Spectral emissions obtained from each flash were photographed in the region of 4000–6000 Å using one metre Czerny-Turner spectrograph cum monochromator. Detailed examination of the observed features showed that theH _β andH _λ lines of hydrogen showed significant broadening of the order of 35 Å FWHM which is due to Stark effect expected in high density plasmas. Further several atomic lines of Cu and Zn from the electrode material (brass) showed broadening which was due to quadratic Stark effect. A comparative study of the broadening of lines obtained in DC arc, hollow cathode and plasma focus was made. Electron density from Stark broadened hydrogen lines and quadratic Stark Coefficient C₄ for the CuI and ZnI lines were evaluated. The excitation temperature was determined from the line intensity ratio method using CuI lines.     

The kinetics of retardation by phenol of the polymerization of acrylonitrile

The present communication discusses the kinetics of the retarding effect of phenol on the polymerization of acrylonitrile initiated by azobisisobutyronitrile (AIBN). The results are treated on the basis of the scheme proposed by Tüdös et al.