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931.
Miroslav Stredanský Lubomir Kremnický Ernest Sturdik Anna Fecková 《Applied biochemistry and biotechnology》1993,38(3):269-276
Production of α-amylase withB. subtilis CCM 2722 in an aqueous two-phase polyethylene glycol/dextran system integrated with product purification by affinity chromatography on crosslinked starch during cultivation was studied. The medium was drawn from the bioreactor to the external settler during fermentation. After phase separation in the settler the dextran-rich bottom phase with cells was returned to the bioreactor. The PEG-rich top phase was pumped to the column with crosslinked starch and returned to the bioreactor after α-amylase adsorption. The same volumetric productivities, 0.53 U/mL/h, were reached in both batch and described process, but total productivity of the latter method was much higher owing to shortening upstream and downstream processing time. The enzyme of 98% homogenity in 95% yield was obtained after its elution from the column. 相似文献
932.
933.
Anna Varvak 《Journal of Combinatorial Theory, Series A》2005,112(2):1-307
For an element w in the Weyl algebra generated by D and U with relation DU=UD+1, the normally ordered form is w=∑ci,jUiDj. We demonstrate that the normal order coefficients ci,j of a word w are rook numbers on a Ferrers board. We use this interpretation to give a new proof of the rook factorization theorem, which we use to provide an explicit formula for the coefficients ci,j. We calculate the Weyl binomial coefficients: normal order coefficients of the element (D+U)n in the Weyl algebra. We extend these results to the q-analogue of the Weyl algebra. We discuss further generalizations using i-rook numbers. 相似文献
934.
JPC – Journal of Planar Chromatography – Modern TLC - Long-chain fatty acids and hydroxy fatty acids and their esters have been separated by reversed-phase thin-layer chromatography... 相似文献
935.
Anna Finne Ann‐Christine Albertsson 《Journal of polymer science. Part A, Polymer chemistry》2003,41(9):1296-1305
Hydrogels of poly(1,5‐dioxepan‐2‐one) and hydrogels of block copolymers of poly(1,5‐dioxepan‐2‐one) and poly(L ‐lactide) were synthesized. Both star‐shaped polymers and linear polymers were polymerized with ring‐opening polymerization and crosslinked in situ with a tetrafunctional acid chloride (1,2,3,4‐cyclopentane tetracarboxylic acid chloride) or a difunctional acid chloride (succinyl chloride). Different network architectures were synthesized in this way. The initial monomer concentrations and the molecular weights of the macromonomers were also altered. The networks were characterized with 1H NMR and differential scanning calorimetry, and the swelling abilities of the different hydrogels were investigated in water and dichloromethane. The ratio of the monomer to the crosslinking agent was assessed by the quantification of the signal intensities in the 1H NMR spectra of the swelled network and agreed with the theoretical crosslinking density. Both the homopolymers of 1,5‐dioxepan‐2‐one and the copolymers of 1,5‐dioxepan‐2‐one and L ‐lactide swelled to a high degree in water. The swelling properties of the materials could be varied over a broad range by changes in the architecture, molecular weight, and content of the precursor in the network. Star‐shaped poly(1,5‐dioxepan‐2‐one) crosslinked with a difunctional acid chloride had the highest degree of swelling among the different homopolymer hydrogels. This network also had the lowest glass‐transition temperature because of the flexible units in the structure. The same trends found for the homopolymer hydrogels were also seen in the hydrogels with block copolymers. The hydrogels swelled enormously in dichloromethane, and as in water, the star‐shaped copolymer crosslinked with a difunctional acid chloride had the highest degree of swelling. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1296–1305, 2003 相似文献
936.
An axiomatics for the indistinguishability of elementary particles in terms of hidden variables is presented in a manner which
depart from the standard approaches usually given to hidden variables. Quantum distribution functions are also discussed and
some possible related lines of work are suggested. 相似文献
937.
Marek Bożejko Anna Dorota Krystek Łukasz Jan Wojakowski 《Mathematische Zeitschrift》2006,253(1):177-196
In this paper we study the properties of the r–deformation introduced in [B1]. We observe that the associated convolution coming from the conditionally free convolution
is associative only for r = 1 and r = 0. We give the realization of some r–Gaussian random variables and obtain Haagerup–Pisier–Buchholz type inequalities. We also study another convolution defined
with the use of the r–deformation through a moment–cumulant formula [KY1] and show that it is associative and in general not positive.
Partially sponsored with KBN grant no 2P03A00723 and RTN HPRN-CT-2002-00279. 相似文献
938.
Anna Krebs Barbara Starczewska Helena Puzanowska-Tarasiewicz Joanna Sledz 《Analytical sciences》2006,22(6):829-833
Three simple spectrophotometric methods have been described for the assay of olanzapine in its pure and pharmaceutical formulations. The direct method (A) is based on the drug oxidation with excess of N-bromosuccinimide in acidic medium and the two indirect methods (B and C) are based on the oxidation of the drug with excess of N-bromosuccinimide and cerium(IV)sulfate, followed by the reaction of the unconsumed oxidants with celestine blue. The calibration graphs were linear over the range 10 - 120 microg mL(-1) (method A), 0.5 - 6.0 microg mL(-1) (method B) and 0.6 - 3.0 microg mL(-1) (method C). After validation, the proposed methods were successfully applied to assay of olanzapine in its commercial tablets with mean percentage recoveries of 101.23 +/- 0.10, 96 +/- 0.10 and 94 +/- 0.04%. The mechanism of olanzapine oxidation with N-bromosuccinimide was also proposed. 相似文献
939.
940.
Stanislav Dubniĉka Anna Zuzana Dubniĉkova Jerzy Kraskiewicz Ryszard Raczka 《Zeitschrift fur Physik C Particles and Fields》1995,68(1):153-162
The Körner-Kuroda model of the electromagnetic structure of octet 1/2+ baryons is restored on a more topical physical basis. Electromagnetic radii of baryons under consideration are calculated and compared with other model predictions. By an incorporation of a two-cut approximation of correct form factor analytic properties and nonzero vector-meson widths, the Körner-Kuroda model is unitarized, providing in this manner imaginary parts of the octet 1/2+ baryon form factors to be nonzero just starting from a branch point corresponding to the lowest threshold. 相似文献