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151.
This paper presents the convergence proof and complexity analysis of an interior-point framework that solves linear programming problems by dynamically selecting and adding relevant inequalities. First, we formulate a new primal–dual interior-point algorithm for solving linear programmes in non-standard form with equality and inequality constraints. The algorithm uses a primal–dual path-following predictor–corrector short-step interior-point method that starts with a reduced problem without any inequalities and selectively adds a given inequality only if it becomes active on the way to optimality. Second, we prove convergence of this algorithm to an optimal solution at which all inequalities are satisfied regardless of whether they have been added by the algorithm or not. We thus provide a theoretical foundation for similar schemes already used in practice. We also establish conditions under which the complexity of such algorithm is polynomial in the problem dimension and address remaining limitations without these conditions for possible further research. 相似文献
152.
Improved Rayleigh to Compton scattering ratio curves for mass attenuation coefficients determination for X‐ray fluorescence analysis
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Nondestructive assays are essentials for certain types of sample materials, and, among those, the X‐ray fluorescence technique enables the determinations of stable elements, and there is an increasing effort on the development of equipment to suit the various needs. Nevertheless, a great difficulty on the analysis of unknown materials' composition is to account for self‐absorption of the fluorescence photons that must be considered in the elemental concentration calculation. The correlation between the Rayleigh to Compton scattering ratio to the mass attenuation coefficient has proved to follow a single polynomial function for the first 20 elements of the periodical table with a correlation factor higher than of 0.998 for the sixth order function. The Rayleigh to Compton scattering ratios for pure elements and the 22.16 keV photons, the main energy from an X‐ray tube with silver anode, were determined with the MCNP6 Monte Carlo computer code. Two scattering angles were considered. Reference samples were measured, and the calculated results were compared to the literature values of the mass attenuation coefficient for some known samples and showed to be within 20% for de 90° scattering angle. Only Lucite was slightly above 20%. Curve fit coefficients are also presented for the 7.11‐ and 17.40‐keV photon energies. 相似文献
153.
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155.
Thiago O. Mendes Georgia M. A. Junqueira Brenda L. S. Porto Charles D. Brito Fernando Sato Marcone A. L. de Oliveira Virgilio Anjos Maria J. V. Bell 《Journal of Raman spectroscopy : JRS》2016,47(6):692-698
This paper presents a systematic analysis of the infrared absorption spectra and Raman scattering of the triacylglycerol molecule predominant in raw bovine milk. Gas chromatography measurements were also performed and revealed the palmitic, stearic, and oleic acids as the most predominant fatty acids in the composition of milk. Based on the gas chromatography results, infrared, and Raman spectra of the triacylglycerol with this combination of fatty acids were simulated. The theoretical spectra were compared with the experimental ones of milk fat and fluid raw milk. Assignment of bands of milk fat was proposed, which can be used for a quality monitoring of the product. We also performed a multivariate model of partial least squares from samples of fluid milk with different concentrations of fat. As a result, the most important variables in the projection were selected as vibrational markers for quality monitoring and quantifying of this important constituent of milk. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
156.
Fluxes of cosmic rays: a delicately balanced stationary state 总被引:1,自引:0,他引:1
The analysis of cosmic rays fluxes as a function of energy reveals a knee slightly below 1016 eV and an ankle close to 1019 eV. Their physical origins remain up to now quite enigmatic; in particular, no elementary process is known which occurs at energies close to 1016 eV. We propose a phenomenological approach along the lines of nonextensive statistical mechanics, a formalism which contains Boltzmann–Gibbs statistical mechanics as a particular case. The knee then appears as a crossover between two fractal-like thermal regimes, the crossover being caused by process occurring at energies ten million times lower than that of the knee, in the region of the quark hadron transition (109 eV). This opens the door to an unexpected standpoint for further clarifying the phenomenon. 相似文献
157.
Shashwati Sen DK Aswal Ajay Singh TV Chandrasekhar Rao KP Muthe JC Vyas LC Gupta SK Gupta VC Sahni 《Pramana》2002,58(5-6):867-870
The MgB2 superconductor, synthesized using solid-state and liquid-phase sintering methods, have been characterized for various properties.
The upper critical field, irreversibility line and critical current density have been determined using magnetization data.
The current-voltage characteristics recorded under an applied magnetic field revealed the existence of vortex glass transition.
The surface analysis using X-ray photoelectron spectroscopy shows that MgB2 is sensitive to atmospheric degradation. 相似文献
158.
da Silva MJ dos Anjos EV Honorato RS Pimentel MF Paim AP 《Analytica chimica acta》2008,629(1-2):98-103
Quantifying cocaine in apprehended samples is important to the Brazilian Federal Police because the concentration can indicate the origin of the drug and consequently the traffic route. In addition to the other risks of using this drug is the variability in cocaine concentration, which makes large doses lethal. Gas Chromatography with a Flame Ionization Detector (GC-FID) and a Mass Selective Detector (GC-MS) are the techniques usually employed, but these systems are not available in all police laboratories, due to the relatively high cost. In the present work, a flow-system procedure for the spectrophotometric determination of cocaine using cobalt thiocyanate as a complexing reagent was developed. In this reaction, two phases are formed: the superior (pink) contains an excess of cobalt thiocyanate solution and the lower layer (blue) contains the complex cocaine-cobalt thiocyanate. Samples and reagent are inserted through a sequential-injection valve between two air bubbles inside a reaction chamber. An optic fiber sensor connected to the chamber recorded the absorbance at 630 nm signal. The detection and quantification limits were 29.4 mg L(-1) and 98 mg L(-1), respectively. Relative standard deviation was 4.9% for solutions containing 400 mg L(-1) (n=10), with stable baselines. The analytical throughput was 12 determinations per hour. 相似文献
159.
Temtem M Casimiro T Santos AG Macedo AL Cabrita EJ Aguiar-Ricardo A 《The journal of physical chemistry. B》2007,111(6):1318-1326
The carbon and fluorine chemical shifts of mixtures of carbon dioxide and Krytox, a carboxylic acid end-capped perfluorinated polyether used as stabilizer for the dispersion polymerization of methyl methacrylate, have been studied using high-pressure, high-resolution nuclear magnetic resonance. 13C and 19F spectra were measured in the density region between 0.54 and 0.73 g.cm(-3) at 334 K for different solutions of Krytox in scCO2 (0.22, 1.13 and 1.72 w/w %). An in-house developed high-pressure apparatus with the capability to change in situ the sample composition was used for this purpose using a 10 mm polyether ketone NMR tube. The nature of CO2-Krytox interaction was assessed both by comparing the CO2 deltaC variation of neat CO2 with that of mixtures with increasing surfactant composition and by the analysis of Krytox 19F corrected chemical shifts in terms of medium magnetic susceptibility. Ab initio calculations, at the second-order M?ller-Plesset level of theory to include the effects of electron correlation, were performed to access and compare the nature of the interactions between CO2 and perfluorinated and nonfluorinated analogue model molecules. Both experimental 13C and 19F HP-NMR results and molecular modeling studies support a F...CO2 site-specific Lewis acid-Lewis base interaction model. A positive entropic variation for the formation of CO2-fluorinated solute complex is advanced as an explanation for the higher solubility of perfluorinated molecules when compared to the nonfluorinated analogues. 相似文献
160.
Bitencourt VL de Paula TA da Matta SL Fonseca CC dos Anjos Benjamin L Costa DS 《Micron (Oxford, England : 1993)》2007,38(6):584-589
The duration of the seminiferous epithelium cycle was estimated in adult maned wolves (Chrysocyon brachyurus, Illiger, 1811), by applying intratesticular injections with tritiated thymidine. The total duration of the seminiferous epithelium cycle in this species was calculated in 8.99 days. So, taking into account that approximately 4.5 cycles of the seminiferous epithelium are necessary for the whole spermatogenesis process to complete, the production of spermatozoa from one spermatogonia will take about 40.45 days. The duration of the spermiogenesis was calculated to be 12.3 days. The eight stages of the seminiferous epithelium cycle were described by the tubular morphology method, which is based either on the form and position of the spermatid nuclei and the occurrence of meiotic divisions. The values of the relative frequency for the pre-meiotic, meiotic and post-meiotic phases in this species were 3.5, 0.78 and 4.8 days, respectively. The maned wolf produces about 29 million spermatozoa a day for each testis gram, therefore being classified among the species provided with a high spermatogenetic efficiency. 相似文献