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101.
Polyaniline nanotube (PANI-NT) based films have been fabricated onto indium-tin-oxide (ITO) coated glass plates via electrophoretic technique. These PANI-NT/ITO electrodes have been utilized for covalent immobilization of cholesterol oxidase (ChOx) using glutaraldehyde (Glu) as cross-linker. Structural, morphological and electrochemical characterization of PANI-NT/ITO electrode and ChOx/Glu/PANI-NT/ITO bioelectrode have been done using FT-IR spectroscopy, SEM, electrochemical impedance spectroscopy and cyclic voltammetry techniques. Response studies of the ChOx/Glu/PANI-NT/ITO bioelectrode have been carried out using both linear sweep voltammetry and UV-Visible spectrophotometry. The results of the biosensing studies reveal that this bioelectrode can be used to detect cholesterol in wide detection range of 25-500 mg/dL with high sensitivity of 3.36 mA mg(-1) dL and fast response time of 30 s at pH 7.4. This bioelectrode exhibits very low value of Michaelis-Menten constant of 1.18 mM indicating enhanced interactions between cholesterol and ChOx immobilized onto this nanostructured PANI matrix.  相似文献   
102.
Aqueous dispersions of highly stable, redispersible silver nanoparticles (Ag NPs) were synthesized using gamma radiolysis with gum acacia as a protecting agent. The formation of nanosized silver was confirmed by its characteristic surface plasmon absorption peak at around 405 nm in UV–vis spectra. The size of the silver nanoparticles can be tuned by controlling the radiation dose, ratio of gum acacia to silver ions and also the ionic strength of the medium. Dynamic light scattering (DLS) measurement of the as-synthesized nanoparticles indicated the size less than 3 nm at higher dose of radiation and this also corroborated the size measurement from the width of the corresponding X-ray diffraction (XRD) peak. The face centered cubic (fcc) crystallinity of the nanoparticles was evident from XRD and high resolution transmission electron microscopic (HRTEM) measurements. Fourier transform infra-red (FTIR) spectroscopic data indicate a bonding of Ag NPs with COO? group of acacia through bridging bidentate linkage.  相似文献   
103.
We quantify the one-shot entanglement cost of an arbitrary bipartite state, that is, the minimum number of singlets needed by two distant parties to create a single copy of the state up to a finite accuracy, by using local operations and classical communication only. This analysis, in contrast to the traditional one, pertains to scenarios of practical relevance, in which resources are finite and transformations can be achieved only approximately. Moreover, it unveils a fundamental relation between two well-known entanglement measures, namely, the Schmidt number and the entanglement of formation. Using this relation, we are able to recover the usual expression of the entanglement cost as a special case.  相似文献   
104.
An efficient and direct procedure for the synthesis of amidoalkyl-2-naphthol derivatives has been described. The process employs a three-component cyclocondensation reaction in one-pot using β-naphthol, aromatic aldehyde and acetamide or benzamide in the presence of silica chloride accelerated by ultrasound giving the product in excellent yield in very short duration.  相似文献   
105.
The thermodynamic parameters like Moelwyn-Hughes parameter (C1), reduced molar volume (V~), isochoric temperature coefficient of internal pressure (X), Huggin's parameter (F), Gruneisen parameter (Γp), isothermal microscopic Gruneisen parameter, Sharma parameter (So), fraction free volume (f) and (A?) a dimensionless thermal parameter, etc and the Beyer's nonlinearity parameter (B/A) were deduced employing the thermal expansion coefficient derived from density data for the homologues series of compounds terephthalyidene-bis-p-n-alkyl anilines, TBnA with n = 5 to 10,12,14,16 and 18. Further, it is found that the variation of molecular radius, Mr increases with the increase of alkyl chain number, with a core radius of 4.78 Å and the increment for methylene unit is 0.086 Å . The results were discussed with the body of the data available.  相似文献   
106.
Different thermodynamic parameters are estimated from volume expansion coefficient, α for a number of N-(p-n-alkoxybenzylidene)-p-n-butyloxyanilines, nO.O4 compounds in isotropic phase (at TIN + 5 °C) and in liquid crystalline phases. The variation of different thermodynamic parameters with the alkoxy chain length in nO.O4 series and their variation with the temperature in individual liquid crystal compounds are discussed. The parameters like available volume (Va), inter molecular free length (Lf) and molecular radius (Mr) are also computed from density, and refractive index for these nO.O4 compounds and the nature of molecular free length and molecular radius are analyzed and discussed.  相似文献   
107.
108.
Amitava Datta 《Pramana》1993,40(6):L503-L509
It is argued with the help of an illustrative model, that the inter species hierarchy among the fermion masses and the quark mixing angles can be accommodated naturally in the standard model with (approximate) flavor democracy provided there are three exactly massless neutrinos and four families of sequential quark-leptons with all members of the fourth family having roughly equal masses. The special problem of light neutrino masses (if any) and possible solutions are also discussed.  相似文献   
109.
A temperature-dependent integrated kinetics for the overall process of photosynthesis in green plants is discussed. The C4 plants are chosen and in these plants, the rate of photosynthesis does not depend on the partial pressure of O2. Using some basic concepts like chemical equilibrium or steady state approximation, a simplified scheme is developed for both light and dark reactions. The light reaction rate per reaction center (R′ 1) in thylakoid membrane is related to the rate of exciton transfer between chlorophyll neighbours and an expression is formulated for the light reaction rate R′ 1. A relation between R′ 1 and the NADPH formation rate is established. The relation takes care of the survival probability of the membrane. The CO2 saturation probability in bundle sheath is also taken into consideration. The photochemical efficiency (ϕ) is expressed in terms of these probabilities. The rate of glucose production is given by R glucose = (8/3)(R′ 1 v L )ϕ(T) g (T) ([G3P]/[P i]2 leaf)SS Q G3P→glucose where g is the activity quotient of the involved enzymes, and G3P represent glycealdehyde-3-phosphate in steady state. A Gaussian distribution for temperature-dependence and a sigmoid function for de-activation are incorporated through the quotient g. In general, the probabilities are given by sigmoid curves. The corresponding parameters can be easily determined. The theoretically determined temperature-dependence of photochemical efficiency and glucose production rate agree well with the experimental ones, thereby validating the formalism.  相似文献   
110.
We demonstrate the method of averaging for conservative oscillators which may be strongly nonlinear, under small perturbations including delayed and/or fractional derivative terms. The unperturbed systems studied here include a harmonic oscillator, a strongly nonlinear oscillator with a cubic nonlinearity, as well as one with a nonanalytic nonlinearity. For the latter two cases, we use an approximate realization of the asymptotic method of averaging, based on harmonic balance. The averaged dynamics closely match the full numerical solutions in all cases, verifying the validity of the averaging procedure as well as the harmonic balance approximations therein. Moreover, interesting dynamics is uncovered in the strongly nonlinear case with small delayed terms, where arbitrarily many stable and unstable limit cycles can coexist, and infinitely many simultaneous saddle-node bifurcations can occur.  相似文献   
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