Ni2 在炭包覆氧化铝表面存在状态及加氢性能

采用等体积浸渍法制备了以炭包覆氧化铝(CCA)为载体的Ni基催化剂.利用低温N2物理吸附、XRD、UV-Vis DRS、H2-TPR、H2-TPD等手段对催化剂进行表征,并考察了催化剂粗1,4-丁二醇加氢反应性能.结果表明,均匀分散在表面的炭可以有效阻止Ni2+进入氧化铝表面四面体及八面体空位,Ni2+以与载体具有中等强度相互作用的物种形式存在.随Ni含量的增加,镍物种晶粒尺寸发生明显变化,当Ni含量低于10%时,NiO以高分散状态存在于载体表面,Ni含量达到14%时催化剂中出现了NiO微晶,进一步提高Ni含量,NiO晶粒尺寸有所长大,但仍保持了较高的分散度.由于Ni的聚集程度较小,随着Ni含量增加,Ni的总活性比表面积增加,催化剂加氢活性提高,至Ni含量达17%时,催化剂表现出最佳的催化加氢活性.     

Fenton-type treatment: state of the art

The different currently used Fenton-type treatments, either chemically or electrochemically generated, are reviewed. A particular attention is devoted to the traditional Fe++/H2O2 chemical process and to the indirect electrochemical oxidation which uses in situ generated hydrogen peroxide. Mechanisms and experimental conditions employed for the optimisation of each technology are reported; moreover advantages and main limitations are discussed.     

Heat Trace and Spectral Action on the Standard Podleś Sphere

We give a new definition of dimension spectrum for non-regular spectral triples and compute the exact (i.e., not only the asymptotics) heat-trace of standard Podle? spheres \({S^2_q}\) for 0 < q < 1, study its behaviour when \({q\to 1}\) , and fully compute its exact spectral action for an explicit class of cut-off functions.     

On three-electron bonds and hydrogen bonds in the open-shell complexes [H2X2]+ for X = F, Cl, and Br

The [H2X2]+ (X = Cl, Br) formula could refer to two possible stable structures, namely, the hydrogen-bonded complex and the three-electron-bonded one. In contrary to the results published by other authors, we claim that for the F-type structures the hydrogen-bonded form is the only possible one and the [HFFH]+ complex is an artifact as its wave function is unstable. For all analyzed molecules, the IR anharmonic spectra have been simulated, which enabled a deeper analysis of other authors' published results of IR low-temperature matrix experiments. Topological atoms in molecules and electron localization function investigations have revealed that the nature of the bond in three-electron-bonded structures is similar to the covalent-depleted one in F2 or HOO molecules, but the effect of removing electrons from the bond area is stronger.     

Field Theory on a q = −1 Quantum Plane

We build a q = –1 deformation of a plane on a product of two copies of algebras of functions on the plane. This algebra contains a subalgebra of functions on the plane. We present a general scheme (which could be also used to construct a quaternion from pairs of complex numbers) and we use it to derive differential structures and metrics, and discuss sample field-theoretical models.Mathematics Subject Classifications (1991):46L87, 81T13, 17B37.     

对外贸易对中国经济结构影响机制的实证分析

为充分说明对外贸易对中国经济结构的影响机制,在着重使用CGE模型的基础上,结合P ro jectL ink模型中劳动力供求与价格影响决定模块,综合考察传导因素—价格作用下比较优势的差异导致经济结构的形成,以及开放条件下对外贸易对经济结构的影响,充分体现价格因素在整个宏观体系中的传导作用.     

Perturbation theorems for linear hyperbolic mixed problems and applications to the compressible euler equations

The main result of this paper (which is completely new, apart from our previous and less general result proved in reference [9]) states that the nonlinear system of equations (1.11) (or, equivalently, (1.10)) that describes the motion of an inviscid, compressible (barotropic) fluid in a bounded domain Ω, gives rise to a strongly well-posed problem (in the Hadamard classical sense) in spaces H^k(Ω), k ≧ 3; see Theorem 1.4 below. Roughly speaking, if (a_n, ?_n) → (a, ?) in H^k × H^k and if f_n → f in ??²(0, T;H^k), then (v_n, g_n) → (v, g) in ?? (0, T; H^k × H^k). The method followed here (see also [8]) also applies to the non-barotropic case p = p(ρ, s) (see [10]) and to other nonlinear problems. These results are based upon an improvement of the structural-stability theorem for linear hyperbolic equations. See Theorem 1.2 below. Added in proof: The reader is referred to [29], Part I, for a concise explanation of some fundamental points in the method followed here. © 1993 John Wiley & Sons, Inc.     

Microwave-assisted Allylic Oxidation at C-13 Position of 14-Deoxysinenxan A

Microwave-assisted allylic oxidation at C-13 position of 14-deoxysinenxan A was described. This new method (150℃/10 min/5 bar on microwave synthesizer) led to a better yield of compound 1 and shorter reaction time.     

Experimental and modeling study of the oxidation of toluene

This paper describes an experimental and modeling study of the oxidation of toluene. The low‐temperature oxidation was studied in a continuous flow stirred tank reactor with carbon‐containing products analyzed by gas chromatography under the following experimental conditions: temperature from 873 to 923 K, 1 bar, fuel equivalence ratios from 0.45 to 0.91, concentrations of toluene from 1.4 to 1.7%, and residence times ranging from 2 to 13 s corresponding to toluene conversion from 5 to 85%. The ignition delays of toluene–oxygen–argon mixtures with fuel equivalence ratios from 0.5 to 3 were measured behind reflected shock waves for temperatures from 1305 to 1795 K and at a pressure of 8.7 ± 0.7 bar. A detailed kinetic mechanism has been proposed to reproduce our experimental results, as well as some literature data obtained in other shock tubes and in a plug flow reactor. The main reaction paths have been determined by sensitivity and flux analyses. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 37: 25–49, 2005