首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3812篇
  免费   62篇
  国内免费   35篇
化学   2326篇
晶体学   82篇
力学   71篇
数学   703篇
物理学   727篇
  2022年   43篇
  2021年   73篇
  2020年   41篇
  2019年   41篇
  2018年   44篇
  2017年   62篇
  2016年   98篇
  2015年   81篇
  2014年   111篇
  2013年   250篇
  2012年   170篇
  2011年   240篇
  2010年   137篇
  2009年   156篇
  2008年   204篇
  2007年   193篇
  2006年   183篇
  2005年   161篇
  2004年   176篇
  2003年   116篇
  2002年   138篇
  2001年   69篇
  2000年   66篇
  1999年   58篇
  1998年   56篇
  1997年   59篇
  1996年   59篇
  1995年   33篇
  1994年   39篇
  1993年   46篇
  1992年   30篇
  1991年   36篇
  1990年   35篇
  1989年   33篇
  1988年   27篇
  1987年   32篇
  1986年   23篇
  1985年   37篇
  1984年   52篇
  1983年   27篇
  1982年   33篇
  1981年   40篇
  1980年   29篇
  1979年   37篇
  1978年   31篇
  1977年   43篇
  1976年   32篇
  1975年   23篇
  1974年   18篇
  1973年   20篇
排序方式: 共有3909条查询结果,搜索用时 15 毫秒
991.
In the paper, we introduce a wide class of domestic finite dimensional algebras over an algebraically closed field which are obtained from the hereditary algebras of Euclidean type , n≥1, by iterated one-point extensions by two-ray modules. We prove that these algebras are domestic and their Auslander-Reiten quivers admit infinitely many nonperiodic connected components with infinitely many orbits with respect to the action of the Auslander-Reiten translation. Moreover, we exhibit a wide class of almost sincere domestic simply connected algebras of large global dimensions.  相似文献   
992.
Let A be an artin algebra over a commutative artin ring R and ind A the category of indecomposable finitely generated right A-modules. Denote to be the full subcategory of ind A formed by the modules X whose all predecessors in ind A have projective dimension at most one, and by the full subcategory of ind A formed by the modules X whose all successors in ind A have injective dimension at most one. Recently, two classes of artin algebras A with co-finite in ind A, quasi-tilted algebras and generalized double tilted algebras, have been extensively investigated. The aim of the paper is to show that these two classes of algebras exhaust the class of all artin algebras A for which is co-finite in ind A, and derive some consequences. Dedicated to Stanislaw Balcerzyk on the occation of his 70th birthday  相似文献   
993.
Carbon paste electrodes bulk-modified with Bi(2)O(3)were used for the determination of Cd(II) and Pb(II). The best composition was 1% (wt%) Bi(2)O(3) in the paste. The measurements were made by differential pulse voltammetry in the potential range from -1.2 V to -0.3 V. The peak potential of the reoxidation of Cd is -0.85 V, and of Pb -0.60 V vs. SCE. The lowest concentration that could be determined was 5 microg L(-1) of both metals (preconcentration time 240 s), the relative standard deviation was 3.5%-5.0% (four determinations). The correlation coefficient ( r(2)) of the calibration curves was 0.9966 (for Cd) and 0.9971 (for Pb). The Bi(2)O(3)-modified electrode could be used for the analysis of drinking water, mineral water and urine.  相似文献   
994.
995.
996.
997.
In this paper, we introduce axiomatically a new value for cooperative TU games satisfying the efficiency, additivity, and symmetry axioms of Shapley (1953) and some new postulate connected with the average marginal contributions of the members of coalitions which can form. Our solution is referred to as the solidarity value. The reason is that its interpretation can be based on the assumption that if a coalition, sayS, forms, then the players who contribute toS more than the average marginal contribution of a member ofS support in some sense their weaker partners inS. Sometimes, it happens that the solidarity value belongs to the core of a game while the Shapley value does not.This research was supported by the KBN Grant 664/2/91 No. 211589101.  相似文献   
998.
The Burgers field responsible for dislocations in a continuized crystal is represented by the torsion tensor of a teleparallel connection, metric with respect to the internal length measurement metric tensor. Lattice lines in a continuized dislocated monocrystal are represented by geodesics of the teleparallel connection, and the internal length measurement along these geodesics is analyzed. The closed teleparallelism responsible for uniformly dense distributions of dislocations is discussed, and equations describing slip surfaces for such distributions of dislocations are formulated. The Galilei-like character of the geometry describing uniformly dense distributions of dislocations is pointed out.  相似文献   
999.
Excess molar volumes V E measured at 15 and 35°C for the (1-propanol + 1-octene), (1-butanol + 1-octene), (1-octanol + 1-octene), and (1-decanol + 1-decene) systems are reported. These data and the measurements reported before at 25°C for this series of mixtures were used to calculate the excess molar isobaric thermal expansion A p E = ( V E/ T)p at 25°C. In the above series of mixtures the A p E values change from positive over the whole concentration range in the systems formed by 1-propanol and 1-butanol, to positive-negative for longer chain alkanols, the positive values occurring in the alkene-rich region. For systems characterized by the sigmoid shape, the positive region of A p E values decreases with increasing length of the 1-alkanol molecule. The modified model of associated mixtures proposed by Treszczanowicz and Benson predicts qualitatively the changes in the shape of the A p E curves. The model allows interpretation of the above results as a balance between the contributions due to self-association of alkanol, nonspecific interactions, and free volume.  相似文献   
1000.
The surface acidity of different mesoporous titanium-silicates, such as well-organized hexagonally packed Ti-MMM, Ti-MMM-2, Ti-SBA-15, and amorphous TiO(2)-SiO(2) mixed oxides (aerogels and xerogels), was studied by means of FTIR spectroscopy of CO adsorbed at 80 K and CD(3)CN adsorbed at 293 K. The surface hydroxyl groups of mesoporous titanium-silicates with 2-7 wt % Ti revealed a Br?nsted acidity slightly higher to that of pure silicate. TiO(2)-SiO(2) xerogels revealed the highest Br?nsted acidity among the titanium-silicates studied. CO adsorption revealed two additional sites on the surface in comparison to pure silicate, characterized by nu(CO) from 2185 (high pressure) to 2178 (low pressure) cm(-1) and from 2174 (high pressure) to 2170 (low pressure) cm(-1). These bands are due to CO adsorbed on isolated titanium cations in the silica surrounding or having one Ti(4+) cation in their second coordination sphere and due to CO interactions with Ti-OH groups, respectively. CD(3)CN adsorption similarly revealed the existence of two additional sites, which were not detected for pure silicate: at 2289 cm(-1) due to CD(3)CN interaction with titanol groups and from 2306 (low pressure) to 2300 (high pressure) cm(-1) due to acetonitrile interaction with isolated framework titanium cations with probably one Ti(4+) cation in their second coordination shell. The spectroscopic results are compared with computational data obtained on cluster models of titanium-silicate with different titanium content. According to the IR data, the Ti accessibility on the surfaces for mesoporous titanium-silicates with similar Ti loading (2 wt %) was found to fall in the order TiO(2)-SiO(2) aerogel approximately TiO(2)-SiO(2) xerogel > Ti-MMM approximately Ti-MMM-2 > Ti-SBA-15. This order (except TiO(2)-SiO(2) xerogel) correlates with the catalytic activity found previously for titanium-silicates in 2,3,6-trimethylphenol oxidation with H(2)O(2).  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号