Cis‐trans Isomerism in Copper(II) Complexes with N‐acyl Thiourea Ligands

The N‐acyl thiourea complexes bis[N,N‐diethyl‐N′‐(p‐nitrobenzoyl)‐thioureato]copper(II) ( 1a,1b ) and bis(N,N‐diphenyl‐N′‐benzoylthioureato)copper(II) ( 2a,2b ) crystallize in each case in two modifications. X‐ray structural analysis shows that 1a and 1b are cis‐trans isomers. This is very unusual for N‐acyl thioureato complexes because with exception of one platinum(II) complex up to now only cis complexes have been found. In contrast X‐ray structural analysis of both forms 2a and 2b of the other complex shows no cis‐trans pair. Both modifications are cis complexes. In solution both isomers of the copper(II) complexes are observable by EPR spectroscopy.     

Another calculation of the Higgs mass and the top mass from the principles of H. B. Nielsen: m H ≅ 163GeV for M t ≅ 190GeV

We calculate the Higgs mass and the top mass starting from the principle that there are two, essentially degenerate minima in the Higgs effective potential; the second is at about the Planck energy scale M _P = 1.2 × 10¹⁹ GeV. Thus the parameter of the quartic self-coupling λ _h vanishes, as does β _λH at M _P. The new element is the addition of a quantum interaction term which couples the square of the Higgs field to the square of a pseudoscalar field, in the domain of the energy scale between about 10¹⁴ GeV and M _P. We modify β _λH at one loop. The pseudoscalar field which is introduced may be the field which is responsible for a spontaneous breakdown of discrete symmetry — for CP noninvariance at an energy scale of (10¹⁵–10¹⁶) GeV. The result is then a closer value for m _H ? 163 GeV for the top pole-mass M _t ? 190 GeV; both values are now close to the electroweak scale parameter $\langle {\phi _H}\rangle /\sqrt 2 = 175{\text{ GeV}}$ . In terms of dimensionless running coupling parameters, which determine the masses near to the electroweak scale, we get $\sqrt {{\lambda _H}} \cong 0.06$ and $gt/\sqrt 2 \cong 0.72$ , values that are close to each other and close to unity.     

On the First Critical Field in Ginzburg–Landau Theory for Thin Shells and Manifolds

In this article, we investigate the response of a thin superconducting shell to an arbitrary external magnetic field. We identify the intensity of the applied field that forces the emergence of vortices in minimizers, the so-called first critical field H _c1 in Ginzburg–Landau theory, for closed simply connected manifolds and arbitrary fields. In the case of a simply connected surface of revolution and vertical and constant field, we further determine the exact number of vortices in the sample as the intensity of the applied field is raised just above H _c1. Finally, we derive via Γ-convergence similar statements for three-dimensional domains of small thickness, where in this setting point vortices are replaced by vortex lines.     

Nontrivial application of Nielsen theory to differential systems

In reply to a problem of Jean Leray concerning application of the Nielsen theory to differential systems for obtaining multiplicity results, we present a nontrivial example of such an application. The emphasis is on the parameter space in order to ensure that no subdomain becomes subinvariant under the related Hammerstein solution operator. To achieve this goal, we develop a general method applicable also for ordinary differential equations with or without uniqueness as well as for upper-Carathéodory differential inclusions. We are not aware that any alternative approach can be employed, even in the single-valued case.     

A package for symbolic solution of real functional equations of real variables

Summary This paper discusses the problems associated with the symbolic treatment of functional equations and presents a Mathematica package for the solution of real functional equations of real variables. The package includes a minimal basic database which contains a reduced set of functional equations with its four components: equation, domain, class and the corresponding solution. The word minimal is used in the sense that any equation that is solvable by the system using non-searching methods is excluded from the database. The package incorporates a searching algorithm which can solve functional equations independently of their notation and their algebraic representation. Not only general solutions but particular and candidate solutions are dealt with. This implies a careful analysis of domains and classes. The package includes some methods for solving functional equations, which are used when the input functional equations are not found in the database. Some methods have been implemented internally and some are in an external package. Finally, some examples illustrate the use of the package.