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71.
Gabrijela Brađan Božidar Čobeljić Andrej Pevec Iztok Turel Marina Milenković Dušanka Radanović 《Journal of Coordination Chemistry》2016,69(5):801-811
Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard’s T reagent) were synthesized and characterized by elemental analyses, IR and UV–vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined. 相似文献
72.
73.
Quantitative characterization of nucleic acids is becoming a frequently used method in routine analysis of biological samples, one use being the detection of genetically modified organisms (GMOs). Measurement uncertainty is an important factor to be considered in these analyses, especially where precise thresholds are set in regulations. Intermediate precision, defined as a measure between repeatability and reproducibility, is a parameter describing the real situation in laboratories dealing with quantitative aspects of molecular biology methods. In this paper, we describe the top-down approach to calculating measurement uncertainty, using intermediate precision, in routine GMO testing of food and feed samples. We illustrate its practicability in defining compliance of results with regulations. The method described is also applicable to other molecular methods for a variety of laboratory diagnostics where quantitative characterization of nucleic acids is needed. 相似文献
74.
75.
Daniel Ha??ko Jaroslav Bruncko Andrej Vincze Franti??ek Uherek 《Central European Journal of Physics》2009,7(2):345-349
Two series of polycrystalline zinc oxide (ZnO) layers, from Zn or ZnO targets, were grown on silicon (1 1 1) substrates by
pulsed laser deposition (PLD) at ambient oxygen pressure levels, stepwise increased from 1 to 35 Pa. For ablation of targets,
a pulsed Nd:YAG laser was used. The structural and morphological properties of the layers were investigated by scanning electron
microscopy (SEM), atomic force microscopy (AFM), and secondary ion mass spectrometry (SIMS). The SEM images of ZnO layers
in SE mode show a uniform granular structure and modified surface morphology, depending on oxygen pressure. The mean grain
size in height and lateral directions decreases with an increase of oxygen pressure from 1 to 5 Pa, while a subsequent rise
of oxygen pressure from 5 to 35 Pa will cause an increase in the grain size. The AFM measurement revealed that the surface
structures of zinc oxide layers grown from different targets were similar, and the layers formed at an ambient oxygen pressure
of 5 Pa exhibited the smallest values of calculated roughness and granularity. SIMS depth profiling analyses confirmed that
the ZnO composition was homogenous across the layer, up to the abrupt change of chemical composition at the interface between
the ZnO layer and the Si substrate.
相似文献
76.
Andrej Vincze Ján Jakabovi? Rudolf Srnánek Alexander ?atka Jaroslav Kovac Jr. 《Central European Journal of Physics》2009,7(2):270-278
To improve Organic Thin Film Transistor (OTFT) properties we study OTFT semiconductor/dielectric interfacial properties via
examination of the gate dielectric using thin Parylene C layer. Structural and morphology properties of pentacene layers deposited
on parylene layer and SiO2/Si substrate structure were compared. The surface morphology was investigated using atomic force microscopy (AFM) and scanning
electron microscopy (SEM). AFM topography of pentacene layer in non-contact mode confirmed the preferable pentacene grain
formation on parylene surface in dependence on layer thickness. The distribution of chemical species on the surfaces and composition
depth profiles were measured by secondary ion mass spectroscopy (SIMS) and surface imaging. The depth profiles of the analyzed
structures show a homogenous pentacene layer, characterized with C or C2 ions. Relatively sharp interface between pentacene and parylene layers was estimated by characteristic increased intensity
of CCl ions peak. For revealing the pentacene phases in the structures the Micro-Raman spectroscopy was utilized. Conformal
coatings of parylene and pentacene layers without pinholes resulted from the deposition process as was confirmed by SIMS surface
imaging. For the pentacene layers thicker than 20 nm, both thin and bulk pentacene phases were detected by Micro-Raman spectroscopy,
while for the pentacene layer thickness of 5 and 10 nm the preferable thin phase was detected. The complete characterisation
of pentacene layers deposited on SiO2 and parylene surface revealed that the formation of large grains suggests 3D pentacene growth at parylene layer with small
voids between grains and more than one monolayer step growth. The results will be utilized for optimization of the deposition
process.
相似文献
77.
R. I. Batalov R. M. Bayazitov D. I. Kryzhkov P. I. Gajduk E. I. Gatskevich G. D. Ivlev C. P. Marques E. Alves 《Journal of Applied Spectroscopy》2009,76(2):209-214
The dynamics of phase transitions induced by nanopulsed ruby laser radiation (80 nsec, 2 J/cm2) both in silicon layers doped with erbium ions and in those containing doped erbium and oxygen have been studied by an optical
probing method. It is shown that the reflectivity behavior of structures under pulsed irradiation is governed by phase transitions
(melting and crystallization) of implanted silicon and also by interference effects at the interfaces of the resulting phases.
It is established that the profiles of erbium distribution change under nanosecond laser irradiation and that the dopant is
forced out to the surface due to a segregation effect at small implantation doses. As the implanatation dose increases, diffusion
deep into the sample tends to prevail over segregation. A considerable increase in the photoluminescence peak intensity at
0.81 eV is found after both the pulsed laser processing and thermal post-annealing of doped samples as opposed to spectra
of samples subjected either to thermal annealing or to pulsed laser irradiation.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 76, No. 2, pp. 225–231, March–April, 2009. 相似文献
78.
Bogdan Kralj Andrej Šmidovnik Jože Kobe 《Rapid communications in mass spectrometry : RCM》2009,23(1):171-180
The mass spectrometric characterization of aqueous solutions of α‐ and β‐cyclodextrins (CDs) and o‐, m‐ and p‐coumaric acids (CAs) by negative ion electrospray ionization (ESI) indicates that the [CD+CA]? ions were sourced from the inclusion complex present in solution and from the anion attached to CD molecules formed in the spray processes. The anion adducts formed in the spray process contribute significantly to the signal intensity of an ionized inclusion complex thus overestimating the calculated stability constant (K) of solution‐phase complexes by one to two orders of magnitude. The relative intensities of anion adducts in mass spectra depend on the concentration ratio of the anion and the CD in spray droplets, while the relative intensity of the ionized inclusion complex depends on CD and CA concentrations in solutions and the value of K. Ion Mobility Spectrometry Mass Spectrometry [IMS‐MS] measurements show that the collision cross‐section (Ω) values of the [CD+CA]? or [(CD)2+CA]2? and [CD+CA] complex ions are 5–6% larger than or equal to CD? or [CD], respectively. Therefore, in the gas phase the anion adducts [CD+CA?] on cyclodextrin molecules possess the same conformations as the ionized inclusion complexes [CD+CA]?. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
79.
Ion Gutiérrez-Aguirre Marko Banjac Andrej Steyer Mateja Poljšak-Prijatelj Matjaž Peterka Aleš Štrancar Maja Ravnikar 《Journal of chromatography. A》2009,1216(13):2700-2704
Rotaviruses are the leading cause of diarrhoea in infants around the globe and, under certain conditions they can be present in drinking water sources and systems. Ingestion of 10–100 viral particles is enough to cause disease, emphasizing the need for sensitive diagnostic methods. In this study we have optimized the concentration of rotavirus particles using methacrylate monolithic chromatographic supports. Different surface chemistries and mobile phases were tested. A strong anion exchanger and phosphate buffer (pH 7) resulted in the highest recoveries after elution of the bound virus with 1 M NaCl. Using this approach, rotavirus particles spiked in 1 l volumes of tap or river water were efficiently concentrated. The developed concentration method in combination with a real time quantitative polymerase chain reaction assay detected rotavirus concentrations as low as 100 rotavirus particles/ml. 相似文献
80.
Perdih F Pevec A Petricek S Petric A Lah N Kogej K Demsar A 《Inorganic chemistry》2006,45(19):7915-7921
Organotitanium fluorides (C5Me4R)TiF3 (R = H, Me, Et) sublimate with formation of crystalline dimers. From solution, we obtained crystals of dimers and tetramers. The tetramer [{(C5Me5)TiF3}4] irreversibly dissociates in the solid state to dimers (DeltaH = 8.33 kcal mol(-1)). The variable-temperature (1)H and (19)F NMR spectroscopy measurements of the toluene-d(8) solution of [{(C5Me5)TiF3}2] revealed at 202 K one monomeric, two dimeric (with C2h and Cs symmetry), two tetrameric (with D2 and C2v symmetry), and two trimeric (both C2 symmetry) molecules. With the increase in temperature and dilution of the solution, the composition of the solution shifts to the smaller molecules. The thermodynamic and activation parameters for the reversible dissociation of dimers to monomers in the solution are DeltaH = 9.2 kcal mol(-1), DeltaS = 24.2 cal mol(-1) K(-1), DeltaH(double dagger) = 12.2 kcal mol(-1), DeltaS(double dagger) = 9.7 cal mol(-1) K(-1). The dissociation path with a weakly double-bridged transition-state dimer was proposed. The thermodynamic parameters for the reversible dissociation of the C2v tetramer to the dimers in solution are DeltaH = 7.9 kcal mol(-1) and DeltaS = 26.8 cal mol(-1) K(-1). From both tetramers, the D2 molecule is 0.34(5) kcal mol(-1) lower in enthalpy and 6.5(5) cal mol(-1) K(-1) lower in entropy than the C2v molecule. The structures of both trimers were proposed. The low-temperature 19F NMR spectra of the CDCl3 solution of [{(C5Me5)TiF3}2] are consistent with equilibria of a monomer, two dimers (with C2h and Cs symmetry), and a trimer. The vapor pressure osmometric molecular mass determination of CDCl3 solution of [{(C5Me5)TiF3}2] at 302 K is consistent with the equilibrium of the dimer and the monomer. 相似文献