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101.
Le Derf F Mazari M Mercier N Levillain E Trippé G Riou A Richomme P Becher J Garín J Orduna J Gallego-Planas N Gorgues A Sallé M 《Chemistry (Weinheim an der Bergstrasse, Germany)》2001,7(2):447-455
A series of redox-responsive ligands that associate the electroactive tetrathiafulvalene core with polyether subunits of various lengths has been synthesized. X-ray structures are provided for each of the free ligands. The requisite structural criteria for reaching switchable ligands are satisfied for the largest macrocycles, that is, planarity of the 1,1',3,3'-tetrathiafulvalene (TTF) pi system and correctly oriented coordinating atoms. The ability of these ligands to recognize various metal cations as a function of the cavity size has been investigated by various techniques (LSIMS, 1H NMR, and UV/Vis spectroscopy, cyclic voltammetry). These systems exhibit an unprecedented high coordination ability among TTF crown ethers. Their switchable ligating properties have been confirmed by cyclic voltammetry, and metal-cation complexation has been illustrated by X-ray structures of three of the corresponding metal complexes (Pb2+, Sr2+, and Ba2+). Solid-state structures of these complexes display original packing modes with channel-like arrangements. 相似文献
102.
André Begouen-Demeaux Gérard Villers Pierre Gibart 《Journal of solid state chemistry》1975,15(2):178-180
The system FeCrTe was investigated around the composition FeCr2Te4. FeCr2Te4 is a metastable compound. Single crystals with Fe0·93Cr1·76Te4 composition were grown by vapor transport or the Bridgman method. These crystals are metallic and anisotropic ferromagnets. 相似文献
103.
Seymour (1981) proved that the cut criterion is necessary and sufficient for the solvability of the edge-disjoint paths problem when the union of the supply graph and the demand graph is planar and Eulerian. When only planarity is required, Middendorf and Pfeiffer (1993) proved the problem to be NP-complete. For this case, Korach and Penn (1992) proved that the cut criterion is sufficient for the existence of a near-complete packing of paths. Here we generalize this result by showing how a natural strengthening of the cut criterion yields better packings of paths.Analogously to Seymour's approach, we actually prove a theorem on packing cuts in an arbitrary graph and then the planar edge-disjoint paths case is obtained by planar dualization. The main result is derived from a theorem of Seb (1990) on the structure of ±1 weightings of a bipartite graph with no negative circuits.Research partially supported by the Hungarian National Foundation for Scientific Research Grants OTKA 2118 and 4271. 相似文献
104.
We show that the Ashtekar-Isham extension
of the configuration space of Yang-Mills theories
is (topologically and measure-theoretically) the projective limit of a family of finite dimensional spaces associated with arbitrary finite lattices.These results are then used to prove that
is contained in a zero measure subset of
with respect to the diffeomorphism invariant Ashtekar-Lewandowski measure on
. Much as in scalar field theory, this implies that states in the quantum theory associated with this measure can be realized as functions on the extended configuration space
. 相似文献
105.
András Telcs 《Journal of Theoretical Probability》1995,8(1):77-96
This paper continues the study of exponentsd(x), d
(x), d
R
(x) andd
(x) for graphG; and the nearest neighbor random walk {X
n
}
nN
onG, if the starting pointX
0=x is fixed. These exponents are responsible for the geometric, resistance, diffusion and spectral properties of the graph. The main concern of this paper is the relation of these exponents to the spectral density of the transition matrix. A series of new exponentse, e
,e
R
,e
are introduced by allowingx to vary along the vertices. The results suggest that the geometric and resistance properties of the graph are responsible for the diffusion speed on the graph. 相似文献
106.
107.
108.
Pochodzalla J Möhlenkamp T Rubehn T Schüttauf A Wörner A Zude E Begemann-Blaich M Blaich T Emling H Ferrero A Gross C Immé G Iori I Kunde GJ Kunze WD Lindenstruth V Lynen U Moroni A Müller WF Ocker B Raciti G Sann H Schwarz C Seidel W Serfling V Stroth J Trautmann W Trzcinski A Tucholski A Verde G Zwieglinski B 《Physical review letters》1995,75(6):1040-1043
109.
André LeClair 《Theoretical and Mathematical Physics》1994,98(3):297-305
We present a new application of affine Lie algebras to massive quantum field theory in 2 dimensions by investigating theq1 limit of theq-deformed affine
symmetry of the sine-Gordon theory, this limit occurring at the free fermion point. Working in radial quantization leads to a quasi-chiral factorization of the space of fields. The conserved charges which generate the affine Lie algebrasplit into two independent affine algebras on this factorized space, each with level 1 in the anti-periodic sector, and level 0 in the periodic sector. The space of fields in the anti-periodic sector can be organized using level-1 highest weight representations if one supplements the
algebra with the usual local integrals of motion. Introducing a particle-field duality leads to a new way of computing form-factors in radial quantization. Using the integrals of motion, a momentum space bosonization involving vertex operators is formulated. Form-factors are computed as vacuum expectation values of vertex operators in momentum space.Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 98. No. 3, pp. 430–441, March, 1994. 相似文献
110.
András Kroó 《Constructive Approximation》1994,10(2):197-206
In this paper we prove that given certain convex domains Δ on the plane, ε>0, andf∈C(Δ) such thatf=0 on θ2Δ={(θ2 x,θ2 y):(x,y)?Δ} (0<θ<1), a polynomialp(x, y) of the form $$p(x,y) = \sum\limits_{\theta n \leqslant k + l \leqslant n} {a_{kl} x^k y^l }$$ exists such that ∥f?p∥ C(Δ) ≤ε. The admissible convex domains include triangles and parallelograms with a vertex at the origin and sections of unit disk. 相似文献