Oscillating Neutrino Mass States and Double Beta Decay

Physics of Atomic Nuclei - Neutrino oscillation is an experimentally established phenomenon by which neutrinos undergo flavor transformations periodically as they propagate large enough distances....     

Synthesis of a model bicyclic core related to Microscleroderma spirophora steroids

An approach to the strained B,C-bicyclic nucleus of a heterocyclic class of steroids is described. The approach relies on a sigmatropic shift for installation of the strained bridge.     

Photon production from baryon rich quark-gluon plasma

We study high energy photon production from a quark-gluon plasma at finite baryon density. We find that the photon production spectrum from the quark-gluon plasma maintained at constant temperature is only mildly dependent on the quark chemical potential.     

Multiplicity dependence of intermittency in one and two dimensions in proton-nucleus interactions at 800 GeV

The intermittency effect has been observed in interactions of 800 GeV protons with emulsion-nuclei in one-(pseudorapidity/azimuthal angle) and two-dimensional (pseudorapidity and azimuthal angle) phase spaces in different multiplicity intervals. The intermittency strength is found to decrease with increasing multiplicity. Compared to one dimension, the two dimensional distribution is found to reflect better the intermittent behavior of the interactions. The dependence of various intermittency parameters on order of moment gives clear evidence of self-similar cascade mechanism in the interactions but there is no definite indication of the presence of different phases in the cascade.     

Measurement of diffusion coefficient of transparent liquid solutions using Michelson interferometer

The study of diffusivity is important for the design of chemical equipment and its knowledge is needed for mass transfer studies and is the most fundamental property of any chemical system in which the chemical engineers are interested. Here, we report a new interferometric technique to determine the diffusion coefficient of transparent liquid solutions using Michelson interferometer geometry. The experimental cell containing the diffusing solution was kept in one of the arms of Michelson Interferometer. The liquids of differing concentrations were introduced in the cell. Two separate circular interference fringe systems were formed due to the two solutions and they were recorded on a PC using a CCD camera. The time variation of these interferograms yields the diffusion coefficient. The obtained diffusivity values matched very well with the existing experimental results. Detailed theoretical and experimental analysis is given in the paper.     

Mean sample spacings, sample size and variability in an auction-theoretic framework

In terms of a standard model for English auctions and sealed-bid auctions, we study the impact of an increase in bidding competition and in variance of the distribution of valuations on the winner's expected rent using tools from order statistics and stochastic ordering.     

Polymerization of styrene with the VOCL3–AlEt2Br catalyst system

The rate of polymerization with the VOCl₃–AlEt₂Br catalyst system at 30°C. in n-hexane reached a maximum at an Al/V molar ratio of 1.5. At this ratio, the rate of polymerization was first-order with respect to catalyst and second-order with respect to monomer concentrations. The apparent activation energy calculated was 6.4 kcal./mole. Diethylzine was found to act as a chain transfer agent. However, the molecular weights of polymers obtained were low. The possibility of bromide-containing catalyst sites acting in the termination reaction has been investigated. The average valence of vanadium is discussed in relation to molecular weights.     

Mesoscale constitutive modeling of magnetic dispersions: material functions for shear flows

We recently developed a constitutive model for magnetic dispersions by modeling the magnetic particles as rigid dumbbells dispersed in a solvent. The theory yielded a constitutive equation in which the stress tensor could be expressed as a function of the velocity gradient, an orientational order tensor, S, an average alignment vector, J, and any imposed external magnetic field, H. The constitutive equation is used here to predict material functions for steady shear flow (shear-rate dependent viscosity and first normal stress coefficient) as well as those for unsteady shear flows (stress growth upon inception of steady shear and small-amplitude oscillatory shear). The importance of effects of concentration, equilibrium nematic ordering in the dispersion, and anisotropy in the hydrodynamic drag are emphasized. Comparisons with available experimental data on viscosity for magnetic inks under steady shear flow and inception of steady shear flow show reasonably good agreement.     

Reaction of benzyl chloride with ammonium sulfide under liquid–liquid phase transfer catalysis: Reaction mechanism and kinetics

The reaction between benzyl chloride and aqueous ammonium sulfide was carried out in an organic solvent – toluene, using tetrabutylammonium bromide (TBAB) as phase transfer catalyst (PTC). Two products, namely dibenzyl sulfide (DBS) and benzyl mercaptan (BM), were identified in the reaction mixture. The selectivity of DBS was maximised by changing various parameters such as NH₃/H₂S mole ratio, stirring speed, catalyst loading, concentration of benzyl chloride, volume of aqueous phase, and temperature. The highest selectivity of DBS obtained was about 90% after 445 min of reaction with excess benzyl chloride at 60 °C. Complete conversion of benzyl chloride could be achieved at the cost of very low selectivity of DBS and very high selectivity of BM. The apparent activation energy for the kinetically controlled reaction was found to be 12.3 kcal/mol. From the detailed study of the effects of various parameters on the reaction, a suitable mechanism was established which could explain the course of the reaction.     

Solution properties of polyurethane

Polyurethane was fractionated and the fractions were characterized by gel permeation chromatography (GPC) and viscometry. The intrinsic viscosities of polyurethane in ten solvents varying in their polarity were determined and are in the order of mineral spirit < acetone < cyclohexane < cyclohexanone < xylene < ethyl benzene < toluene < benzene < methyl ethyl ketone < tetrahydrofuran. The Mark-Houwink relations suggested that solvent blend MEK: n-heptane (1:3) is a poor solvent with an a value of 0·52 and tetrahydrofuran is a good solvent with an a value of 0·78. The weight average molecular weight has been estimated by an extrapolation technique based on a linear relationship between the viscosity average molecular weight _v and the Mark-Houwink constant. The weight average molecular weights obtained from viscosity studies were used to evaluate the unpertureb dimension of the chain.