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21.
Aminonaphthols are easily transformed into a variety of 1- and 2-naphthyl piperazines using a sequence of diazotization, iodide substitution and Pd(0) catalyzed coupling reactions. 相似文献
22.
Roland Glowinski Jiwen He Jacques Rappaz Joël Wagner 《Comptes Rendus Mathematique》2003,337(10):679-684
In this paper we present a method to solve numerically elliptic problems with multi-scale data using multiple levels of not necessarily nested grids. The method consists in calculating successive corrections to the solution in patches whose discretizations are not necessarily conforming. It resembles the FAC method (see Math. Comp. 46 (174) (1986) 439–456) and its convergence is obtained by a domain decomposition technique (see Math. Comp. 57 (195) (1991) 1–21). However it is of much more flexible use in comparison to the latter. To cite this article: R. Glowinski et al., C. R. Acad. Sci. Paris, Ser. I 337 (2003). 相似文献
23.
Ana Luísa Daniel‐da‐Silva João Carlos Moura Bordado José Miguel Martín‐Martínez 《Journal of Polymer Science.Polymer Physics》2007,45(22):3034-3045
The degree of phase separation in several moisture‐cured poly(urethane urea)s (PUUs) was studied by FTIR spectroscopy, wide angle X‐ray diffraction (WAXD), and temperature‐modulated differential scanning calorimetry (TMDSC). This latter technique was shown to be particularly useful in analysing the degree of phase separation in PUU polymers. Both phase mixing and phase segregation coexisted in the PUUs and the degree of phase separation increased as the urea hard segment (HS) content in the PUU increased. The maximum solubility of urea HSs into the polyol soft segments (SSs) was achieved for 50 wt % urea HS content in diol‐based PUUs, whereas for triol‐based PUUs the highest solubility between HS and SS was reached for lower urea HS amount. Finally, the higher the urea HS content the higher the extent of phase separation in the PUU. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3034–3045, 2007 相似文献
24.
Howard Anton and Robert C. Busby, John Wiley & Sons, Inc., 2002. 相似文献
25.
G. Lujanienë 《Czechoslovak Journal of Physics》2003,53(1):A57-A65
In order to understand better the way in which radioactive contamination may be transferred from the atmosphere to other ecological compartments it is necessary to obtain information of the deposition mechanisms of radionuclides. Concentration and speciation of 137Cs and 7Be in the atmospheric aerosol and deposition were studied. The mixed deposition velocities of water-soluble and insoluble 137Cs and 7Be were determined. The relation between activity concentrations of insoluble 7Be in the atmosphere and its amount in deposition was observed. It is supposed that in the deposition process of radiocesium the precipitation plays an important role in scavenging of water-soluble radiocesium by falling raindrops, in contrast to insoluble 137Cs where the dry deposition becomes predominant. 相似文献
26.
Fabio A. C. C. Chalub Peter A. Markowich Benoît Perthame Christian Schmeiser 《Monatshefte für Mathematik》2004,142(1-2):123-141
Kinetic models for chemotaxis, nonlinearly coupled to a Poisson equation for the chemo-attractant density, are considered. Under suitable assumptions on the turning kernel (including models introduced by Othmer, Dunbar and Alt), convergence in the macroscopic limit to a drift-diffusion model is proven. The drift-diffusion models derived in this way include the classical Keller-Segel model. Furthermore, sufficient conditions for kinetic models are given such that finite-time-blow-up does not occur. Examples are given satisfying these conditions, whereas the macroscopic limit problem is known to exhibit finite-time-blow-up. The main analytical tools are entropy techniques for the macroscopic limit as well as results from potential theory for the control of the chemo-attractant density.Present address: Centro de Matemática e Aplicações Fundamentais, Universidade de Lisboa, Av. Prof. Gama Pinto 2, 1649-003, Lisboa, Portugal 相似文献
27.
The control of piecewise-deterministic processes is studied where only local boundedness of the data is assumed. Moreover the discount rate may be zero. The value function is shown to be solution to the Bellman equation in a weak sense; however the solution concept is strong enough to generate optimal policies. Continuity and compactness conditions are given for the existence of nonrelaxed optimal feedback controls. 相似文献
28.
The purpose of this paper is to give the Reid ``Roundabout Theorem' for quadratic functionals with general boundary conditions.
In particular, we describe the so-called coupled point and regularity condition introduced in [16] in terms of Riccati equation
solutions.
Accepted 27 February 1996 相似文献
29.
Mustafa Çelebier Ertan Şahin Nilgün Ancın Nurşen Altuntaş Öztaş Selma Gül Öztaş 《应用有机金属化学》2007,21(10):viii-viii
The article referenced above was first published online on 30 August 2007 with incorrect pagination; the pagination has now been corrected online and in print. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
30.
J‐F. Masson Slaana Bundalo‐Perc Ana Delgado 《Journal of Polymer Science.Polymer Physics》2005,43(3):276-279
Differential scanning calorimetry (DSC) does not allow for easy determination of the glass‐transition temperature (Tg) of the polystyrene (PS) block in styrene–butadiene–styrene (SBS) block copolymers. Modulated DSC (MDSC), which deconvolutes the standard DSC signal into reversing and nonreversing signals, was used to determine the (Tg) of both the polybutadiene (PB) and PS blocks in SBS. The Tg of the PB block was sharp, at ?92 °C, but that for the PS blocks was extremely broad, from ?60 to 125 °C with a maximum at 68 °C because of blending with PB. PS blocks were found only to exist in a mixed PS–PB phase. This concurred with the results from dynamic mechanical analysis. Annealing did not allow for a segregation of the PS blocks into a pure phase, but allowed for the segregation of the mixed phase into two mixed phases, one that was PB‐rich and the other that was PS‐rich. It is concluded that three phases coexist in SBS: PB, PB‐rich, and PS‐rich phases. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 276–279, 2005 相似文献