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91.
Polypropylene/poly(butyl methacrylate)(PP/PBMA) blends were prepared by diffusion and subsequent polymerization of butyl methacrylate(BMA) in commercial isotactic polypropylene(iPP) pellets.The diffusion kinetics,diametrical distribution of PBMA in a pellet and phase morphology of a typical PP/PBMA blend were investigated. 相似文献
92.
A rapid,sensitive,selective and reliable strip assay based on DNA-functionalized gold nanoparticles for Hg2+ detection has been developed,with a detection limit 5 nmol/L.The measurement principle was based on thymine-Hg2+-thymine(T-Hg2+-T) coordination chemistry and streptavidin-biotin interaction.The major advantages of this assay are that results can be read visually without any instrument in less than 10 min and that it does not require any sample pretreatment. 相似文献
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Sortases are a family of transpeptidases found in Gram-positive bacteria responsible for covalent anchoring of cell surface proteins to bacterial cell walls. It has been discovered that sortase A (SrtA) of Staphylococcus aureus origin is rather promiscuous and can accept various molecules as substrates. As a result, SrtA has been widely used to ligate peptides and proteins with a variety of nucleophiles, and the ligation products are useful for research in chemical biology, proteomics, biomedicine, etc. This review summarizes the recent applications of SrtA with special emphasis on SrtA-catalyzed ligation of carbohydrates with peptides and proteins. 相似文献
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This paper continues the analysis on the Lengyel–Epstein reaction- diffusion system of the chlorite-iodide-malonic acid-starch (CIMA) reaction for the rich Turing structures. The steady state structures, especially the double bifurcation one, and their stability and multiplicity are studied by the use of Lyapunov–Schmidt reduction technique and singularity theory. Numerical simulations are presented to support our theoretical studies. The results show that the richer stationary Turing patterns heavily rely both on the size of the reactor and on the effective diffusion rate in the CIMA reaction. 相似文献
100.
Chikkannagari Nagamani Jing Guo S. Thayumanavan 《Journal of polymer science. Part A, Polymer chemistry》2012,50(6):1187-1196
Biaryl hydroxy polymers with orthogonal disposition of proton transporting ? OH moieties have been synthesized via conventional free radical polymerization. The polymers are characterized for their thermal stability and proton conductivity, and the results are compared with the corresponding styrenic hydroxy polymers. The orthogonal disposition of ? OH moieties in biaryl polymers does result in lower Ea for proton transport. However, the lower Ea values in biaryl polymers did not translate into a net increase in proton conductivity. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献