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991.
钠硼解石——水体系溶解和相平衡的研究(英) 总被引:3,自引:0,他引:3
Ulexite dissolution in water has been studied in the wide temperature range from 10℃ to 93℃ and two higher temperatures at 120 ℃ and 240 ℃. The analytical results showed that ulexite dissolved congruently from 10 ℃ to 35 ℃ and incongruently from 40 to 68 ℃. The solid component of ulexite, NaCaB5O6(OH)6·5H2O was dehydrated to form NaCaB5O6(OH)6·H2O from 50 to 68 ℃ and finally amorphous solid at 68 ℃. This amorphous solid converted into priceite at 71 ℃ and then converted completely to priceite at the boiling point(93℃) of the solution. At both 120 and 240 ℃, the dissolution of ulexite was an incongruent process. Above 120 ℃, ulexite became amorphous solid and then transformed into priceite. In addition to the solid to solid transformation, crystallization of priceite from the solution has also been observed. Based on our experimental results, mechanisms of dissolution, transformation, and crystallization of borate in ulexite-water system are discussed. 相似文献
992.
以金属硝酸盐为原料,分别采用高分子前驱体法、柠檬酸盐凝胶法制备了纳米级的Ce-Zr-Ba-O复合氧化物超细粒子,采用X-射线衍射(XRD)、透射电镜(TEM)、BET比表面测定、热重-差热(TG-DTA)技术对催化剂进行了表征,并考察了催化剂的CO氧化活性和热稳定性。实验结果表明,高分子前驱体法和柠檬酸盐凝胶法制备的催化剂粉体都达到了纳米级。两种方法中,高分子前驱体法所制得的催化剂的BET比表面达118.96m2·g-1,CO氧化反应活性较高,同时该方法制得的催化剂分散性好,无团聚,经1000℃高温焙烧后仍基本无烧结、无团聚现象,具有较高的热稳定性。 相似文献
993.
高效液相色谱法测定橡胶促进剂TBBS 总被引:3,自引:0,他引:3
采用反相高效液相色谱法(HPLC)测定了橡胶促进剂N-叔丁基-2-苯并噻唑次磺酰胺(TBBS)的纯度,标准偏差小于0.3。 相似文献
994.
995.
The rates of cleavage of the Si–H bond in penta-or tetramethyldisiloxane, catalyzed by potassium hydroxide have been studied in moist ethanol at 25°C. The reaction is first order in the catalyst and in the silane. The apparent kinetic constant varies with the inverse of the square root of the initial silane concentration. The mechanism involves either a fast equilibrium between hydroxide ion and the silane, followed by the approach ofa hydroxylated molecule in the rate-determining step, or a concerted attack on the silicon atom.
Si–H - , , 25 °C. , . . , .相似文献
996.
M. B. Fleisher L. O. Golender M. V. Shimanskaya 《Reaction Kinetics and Catalysis Letters》1988,36(2):441-446
A possibility is shown for describing indirect interactions between adsorbate molecules (H2O, NH3) on the surface of -Al2O3 in terms of the previously suggested quantum-chemical cluster model using CNDO/2 calculations.
(H2O, NH3) -Al2O3 - /2.相似文献
997.
Mark F. Zaranyika Canissius Nyakonda Peter Moses 《Fresenius' Journal of Analytical Chemistry》1991,341(10):577-585
Summary The effects of excess Na on the ionization and excitation of K in an air-acetylene flame were studied using absorbance signal and emission signal ratios, A/A and E/E respectively, as probes, where A and E are the line absorbance and line emission readings in the presence of excess Na interferent, and unprimed quantities represent readings in the absence of the interferent. An emission signal enhancement which increases exponentially as the ratio of interferent to analyte increases (up to about 2000), was observed irrespective of whether measurements were made from the primary or secondary reaction zones of the flame, while a similar line absorbance signal enhancement was observed only when measurements were made from the primary reaction zone. For both line emission and line absorbance, the maximum enhancements observed are in excess of those predicted on the basis of complete suppression of ionization of analyte atoms as a result of the increased partial pressure of electrons. A steady state kinetic model is presented, which takes into account radiative recombination collisional excitation of K+ ions and collisional charge transfer between the heavy particles, and whose predictions are consistent with the observed interference effects. 相似文献
998.
M. S. El-Shahawi A. Z. Abu Zuhri S. M. Al-Daheri 《Fresenius' Journal of Analytical Chemistry》1994,350(12):674-677
A simple and convenient extractive spectrophotometric method for the determination of ruthenium has been developed. It is based on the oxidation of the different ruthenium (II, III or IV) species to perruthenate with potassium periodate at pH 7.8. The perruthenate is then extracted with benzyltributylammonium chloride in chloroform followed by direct spectrophotometric measurements at 342 and 380 nm. The optimum concentration range was found to be 0.1–5 mg l–1, the standard deviation ±2.1%. The method has been successfully applied to the determination of ruthenium in organoruthenium compounds. 相似文献
999.
Inductively coupled plasma mass spectrometry: Application to the determination of arsenic species 总被引:1,自引:0,他引:1
The application of ion-pair reversed phase chromatography (HPLC) and inductively coupled plasma mass spectrometry to the determination of six species of arsenic is described: arsenious acid (AsIII), arsenic acid (AsV), monomethylarsinic acid (MMA), dimethylarsinic acid (DMA), arsenocholine (AsC) and arsenobetaine (AsB) in marine biota and in natural fresh water. The coupling conditions of HPLC-ICP-MS are given and also the evaluation of the extraction procedure applied to determine these species in marine organisms. The limits of detection are between 6 and 25 g.l–1. 相似文献
1000.
The synthesis and characterisation of five newβ-aminodiketones is reported: (a) 3,3,5,8,10,10-hexamethyl-5,8-diazadodecane-2,11-dione; (b) 3,3,11,11-tetramethyl-5,8-diazatridecane-2,12-dione;
(c) 3,3,12,12-tetramethyl-5,10-diazatetradecane-2,13-dione; (d) 3,3,10,10-tetramethyl-5,8-diphenyl-5,8-diazadodecane-2,11,dione
and (e) 6,7-benzo-3,3,10,10-tetramethyl-5,8-diazadodecane-2,11-dione. These compounds are discussed as potential precursors
in the synthesis of tetra-aza macrocyclic complexes. 相似文献