Mobile interstitial model and mobile electron model of mechano-induced luminescence in coloured alkali halide crystals

A theoretical study is made on the mobile interstitial and mobile electron models of mechano-induced luminescence in coloured alkali halide crystals. Equations derived indicate that the mechanoluminescence intensity should depend on several factors like strain rate, applied stress, temperature, density of F-centres and volume of crystal. The equations also involve the efficiency and decay time of mechanoluminescence. Results of mobile interstitial and mobile electron models are compared with the experimental observations, which indicated that the latter is more suitable as compared to the former. From the temperature dependence of ML, the energy gaps between the dislocation band and ground state of F-centre is calculated which are 0.08, 0.072 and 0.09 eV for KCl, KBr and NaCl crystals, respectively. The theory predicts that the decay of ML intensity is related to the process of stress relaxation in crystals.     

Gaussian Analytic Functions in the Polydisk

We study hyperbolic Gaussian analytic functions in the unit polydisk of \(\mathbb {C}^n\). Following the scheme previously used in the unit ball, we first study the asymptotics of fluctuations of linear statistics as the directional intensities \(L_j\), \(j=1,\dots ,n\) tend to \(\infty \). Then, we estimate the probability of large deviations of such linear statistics and use the estimate to prove a hole theorem. Our proofs are inspired by the methods of M. Sodin and B. Tsirelson for the one-dimensional case, and B. Shiffman and S. Zelditch for the study of the analogous problem for compact Kähler manifolds.     

One‐pot Synthesis of Highly Functionalized Tetrahydropyridines: A Camphoresulfonic Acid Catalyzed Multicomponent Reaction

A simple and straight forward solvent free method for the synthesis of a series of highly functionalized tetrahydropyridine derivatives has been achieved via multicomponent reaction of aromatic aldehydes, various amines, and β‐keto esters at room temperature using readily available (±)‐camphor‐10‐sulfonic acid as an organocatalyst. The current protocol offers an atom economic and environmentally benign method for the synthesis of the title compounds under solvent free conditions in good yields with high substrate scope and avoids column chromatographic purification.     

Application of HR-MAS NMR spectroscopy for studying chemotype variations of Withania somnifera (L.) Dunal

Withania somnifera (L.) Dunal (Solanaceae), commonly known as Ashwagandha, is one of the most valued Indian medicinal plants with a number of pharmaceutical and nutraceutical applications. Metabolic profiling has been performed by HR-MAS NMR spectroscopy on fresh leaf and root tissue specimens from four chemotypes of W. somnifera. The HR-MAS NMR spectroscopy of lyophilized defatted leaf tissue specimens clearly distinguishes resonances of medicinally important secondary metabolites (withaferin A and withanone) and its distinctive quantitative variability among the chemotypes. A total of 41 metabolites were identified from both the leaf and root tissues of the chemotypes. The presence of methanol in leaf and root tissues of W. somnifera was detected by HR-MAS NMR spectroscopy. Multivariate principal component analysis (PCA) on HR-MAS (1) H NMR spectra of leaves revealed clear variations in primary metabolites among the chemotypes. The results of the present study demonstrated an efficient method, which can be utilized for metabolite profiling of primary and secondary metabolites in medicinally important plants.     

In-line reference-delayed digital holography using a low-coherence light source

We present a holographic imaging device with a low-coherence light source that uses the reflection of the objective lens as reference illumination. This results in a simple setup and allows applications to microscopy with only small modifications of the setup for aberration measurements. In addition, it opens the prospects to in vivo ophthalmic imaging. We present in vitro experiments using a resolution test target to quantify the system performance. We demonstrate that we can achieve diffraction-limited resolution and show the possibility of aberration correction. We also present preliminary results using a scattering sample.     

Surface plasmon band tailoring of plasmonic nanostructure under the effect of water radiolysis by synchrotron radiation

Plasmonic metal nanostructures have a significant impact on a diverse domain of fields, including photocatalysis, antibacterial, drug vector, biosensors, photovoltaic cell, optical and electronic devices. Metal nanoparticles (MNps) are the simplest nanostructure promising ultrahigh stability, ease of manufacturing and tunable optical response. Silver nanoparticles (AgNp) dominate in the class of MNps because of their relatively high abundance, chemical activity and unique physical properties. Although MNps offer the desired physical properties, most of the synthesis and fabrication methods lag at the electronic grade due to an unbidden secondary product as a result of the direct chemical reduction process. In this paper, a facile protocol is presented for fabricating high‐yield in situ plasmonic AgNps under monochromatic X‐rays irradiation, without the use of any chemical reducing agent which prevents the formation of secondary products. The ascendancy of this protocol is to produce high quantitative yield with control over the reaction rate, particle size and localized surface plasmon resonance response, and also to provide the feasibility for in situ characterization. The role of X‐ray energy, beam flux and integrated dose towards the fabrication of plasmonic nanostructures has been studied. This experiment extends plasmonic research and provides avenues for upgrading production technologies of MNps.     

Projected Shell Model Description of Positive Parity Band of <Superscript>130</Superscript>Pr Nucleus

Theoretical investigation of positive parity yrast band of odd-odd ¹³⁰Pr nucleus is performed by applying the projected shell model. The present study is undertaken to investigate and verify the very recently observed side band in ¹³⁰Pr theoretically in terms of quasi-particle (qp) configuration. From the analysis of band diagram, the yrast as well as side band are found to arise from two-qp configuration πh _11/2???νh _11/2. The present calculations are viewed to have qualitatively reproduced the known experimental data for yrast states, transition energies, and B(M1) / B(E2) ratios of this nucleus. The recently observed positive parity side band is also reproduced by the present calculations. The energy states of the side band are predicted up to spin 25⁺, which is far above the known experimental spin of 18⁺ and this could serve as a motivational factor for future experiments. In addition, the reduced transition probability B(E2) for interband transitions has also been calculated for the first time in projected shell model, which would serve as an encouragement for other research groups in the future.     

Design and Performance Analysis of High Speed Optical Binary Code Converter using Micro-Ring Resonator

The present paper describes various attractive logical code conversions using optical micro-ring resonator. We have proposed an all-optical switching activity using silicon waveguide based micro-ring resonator under low-power operation through two-photon absorption effect. The different properties of the optical switch are analyzed through numerical simulation. We have also proposed and described all-optical binary-to-octal, binary-coded-decimal-to-excess-3 and binary-to-Gray-code converter circuits by this proposed architecture. Numerical simulation results for code conversion verifying the proposed methods are given in this paper. We identify a combination of feasible ring radius and detuning through numerical simulation that allows analyzing the system performance of the scheme.     

Signals of leptophilic dark matter at the ILC

Adopting a model independent approach, we constrain the various effective interactions of leptophilic DM particles with the visible world from the WMAP and Planck data. The thermally averaged indirect DM annihilation cross section and the DM–electron direct-detection cross section for such a DM candidate are observed to be consistent with the respective experimental data. We study the production of cosmologically allowed leptophilic DM in association with \(Z\, (Z\rightarrow f\bar{f})\), \(f\equiv q,\,e^-,\, \mu ^-\) at the ILC. We perform the \(\chi ^2\) analysis and compute the 99% C.L. acceptance contours in the \(m_\chi \) and \(\varLambda \) plane from the two-dimensional differential distributions of various kinematic observables obtained after employing parton showering and hadronisation to the simulated data. We observe that the dominant hadronic channel provides the best kinematic reach of 2.62 TeV (\(m_\chi \) = 25 GeV), which further improves to \(\sim \)3 TeV for polarised beams at \(\sqrt{s} = 1\) TeV and an integrated luminosity of 1 ab\(^{-1}\).     

Total synthesis and structure revision of petrobactin

The total synthesis and the revised structural assignment of petrobactin, a siderophore isolated from the marine bacterium Marinobacter hydrocarbonoclasticus, is reported. The key step in the synthesis involved condensation of N¹-(2,3-dibenzoyloxybenzoyl)-N⁴-benzylspermidine with 1,3-di-(p-nitrophenyl)-2-tert-butyl citrate. Proton NMR spectra of the synthesized product compared with those reported for the natural product revealed that the compound did not contain 2,3-dihydroxybenzoyl moieties as published; instead, the splitting pattern suggested 3,4-dihydroxybenzoyl fragments. The 3,4-dihydroxybenzoyl analogue was accessed via a similar route; the proton and carbon-13 NMR spectra of this compound were consistent with those reported for natural petrobactin.