首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   616篇
  免费   24篇
  国内免费   3篇
化学   256篇
晶体学   3篇
力学   194篇
数学   87篇
物理学   103篇
  2023年   2篇
  2022年   15篇
  2021年   18篇
  2020年   5篇
  2019年   14篇
  2018年   9篇
  2017年   8篇
  2016年   14篇
  2015年   12篇
  2014年   32篇
  2013年   37篇
  2012年   41篇
  2011年   49篇
  2010年   38篇
  2009年   38篇
  2008年   50篇
  2007年   23篇
  2006年   19篇
  2005年   13篇
  2004年   15篇
  2003年   16篇
  2002年   18篇
  2001年   9篇
  2000年   11篇
  1999年   7篇
  1998年   7篇
  1997年   8篇
  1996年   10篇
  1995年   12篇
  1994年   3篇
  1993年   9篇
  1992年   10篇
  1991年   10篇
  1990年   5篇
  1989年   5篇
  1988年   7篇
  1986年   3篇
  1985年   4篇
  1984年   3篇
  1983年   3篇
  1982年   2篇
  1981年   3篇
  1980年   2篇
  1979年   2篇
  1974年   3篇
  1973年   4篇
  1972年   2篇
  1941年   2篇
  1933年   1篇
  1923年   1篇
排序方式: 共有643条查询结果,搜索用时 31 毫秒
631.
632.
考虑感应磁场的影响,研究不可压缩粘性流体在伸展表面上,作稳定磁流体动力学(MHD)的驻点流动.通过相似变换,将非线性的偏微分方程,变换成为常微分方程.用打靶法数值地求解变换后的边界层方程,得到不同的磁场参数和Prandtl数Pr时的数值解.对a/c>1和a/c<1两种情况(其中a和c均为正值),讨论感应磁场参数对表面摩擦因数、局部Nusselt数、速度和温度的影响,绘出变化曲线并给予讨论.  相似文献   
633.
This article considers the problem of mixed convection stagnation-point flow towards a vertical plate embedded in a porous medium with prescribed surface heat flux. It is assumed that the free stream velocity and the surface heat flux vary linearly from the stagnation point. Using a similarity transformation, the governing system of partial differential equations is transformed into a system of ordinary differential equations, before being solved numerically by a finite-difference method. The features of the flow and the heat transfer characteristics are analyzed and discussed. It is found that dual solutions exist for both buoyancy assisting and opposing flows.  相似文献   
634.
The physico-chemical property data for l-glutamic acid in aqueous NaCl solutions were obtained at 0, 0.5, 1.0 and 2.0 mol·kg?1 NaCl and amino acid molalities from 0 to 0.0669 mol·kg?1 between 293.15 and 323.15 K. The influence of NaCl addition on the volumetric and viscometric properties of the amino acid has been studied. From the experimental densities, the apparent molar volumes and transfer volumes of l-glutamic acid in aqueous electrolyte solutions have been calculated. The viscosity data in the studied domain of amino acid molalities have led to the evaluation of the Falkenhagen and Jones–Dole viscosity coefficients of l-glutamic acid in NaCl aqueous solutions. The results have been discussed in terms of interactions occurring in the systems.  相似文献   
635.
α-Amylase catalyzes hydrolysis of starch to oligosaccharides, which are further degraded to simple sugars. The enzyme has been widely used in food and textile industries and recently, in generation of renewable energy. An α-amylase from yeast Saccharomycopsis fibuligera R64 (Sfamy) is active at 50 °C and capable of degrading raw starch, making it attractive for the aforementioned applications. To improve its characteristics as well as to provide information for structural study ab initio, the enzyme was chemically modified by acid anhydrides (nonpolar groups), glyoxylic acid (GA) (polar group), dimethyl adipimidate (DMA) (cross-linking), and polyethylene glycol (PEG) (hydrophilization). Introduction of nonpolar groups increased enzyme stability up to 18 times, while modification by a cross-linking agent resulted in protection of the calcium ion, which is essential for enzyme activity and integrity. The hydrophilization with PEG resulted in protection against tryptic digestion. The chemical modification of Sfamy by various modifiers has thereby resulted in improvement of its characteristics and provided systematic information beneficial for structural study of the enzyme. An in silico structural study of the enzyme improved the interpretation of the results.  相似文献   
636.
The front photopyroelectric configuration was applied to measure the thermal effusivity of some composite materials, inserted as backing layers in the detection cell. The technique is based on the scanning procedure of the coupling fluid’s thickness (TWRC method). Two particular composite materials were selected for investigation: (i) a liquid one: water based nanofluids with gold nanoparticles and (ii) a solid one: urea—fumaric acid (1:1) cocrystal. The thermal effusivity was found independent on the size and concentration of gold particles. Concerning the urea—fumaric acid cocrystal, the thermal effusivity value of the compound is different from the pure starting materials, indicating the formation of the compound.  相似文献   
637.
This paper presents the modeling and simulation of the thermal analysis on the hydrogenerator stator winding. The insulation aging is predetermined first by the insulation temperatures that, in turn, are influenced by the environmental conditions and second by the speed increase of the high temperature chemical reaction in materials. By increasing the temperature in the electro-insulated material, many molecules enter in chemical reaction accelerating the insulation aging. The heat transfer is a natural process, caused by inner energy, between bodies with high temperature and bodies with lower temperature. This process can also take place between parts of the same body that have different temperatures. The heat is transmitted by conduction, convection, and radiation. The heat transfer and especially the thermal conduction are a domain in which the finite element method is successfully applied. The thermal conduction problems will be solved by the finite elements method. The analysis of the thermal transfer process was made using the modeling and simulation program with finite elements ANSYS, and the results of the simulations were compared with measurement values. The analyzed stator winding is supplied with high voltage of 11 kV that is used for a high power hydrogenerator. To realize the thermal analysis of the winding stator, the coil will be supplied with 11 kV. The results of the analysis on a prototype model present the thermal transfer in coil–insulation–air system when the coil is hot.  相似文献   
638.
Cannabis sativa L. (hemp) is a plant used in the textile industry and green building material industry, as well as for the phytoremediation of soil, medical treatments, and supplementary food products. The synergistic effect of terpenes, flavonoids, and cannabinoids in hemp extracts may mediate the biogenic synthesis of metal nanoparticles. In this study, the chemical composition of aqueous leaf extracts of three varieties of Romanian hemp (two monoecious, and one dioecious) have been determined by Fourier-Transformed Infrared spectroscopy (FT-IR), high-performance liquid chromatography, and mass spectrometry (UHPLC-DAD-MS). Then, their capability to mediate the green synthesis of silver nanoparticles (AgNPs) and their pottential antibacterial applications were evaluated. The average antioxidant capacity of the extracts had 18.4 ± 3.9% inhibition determined by 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 78.2 ± 4.1% determined by 2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS™) assays. The total polyphenolic content of the extracts was 1642 ± 32 mg gallic acid equivalent (GAE) L−1. After this, these extracts were reacted with an aqueous solution of AgNO3 resulting in AgNPs, which were characterized by UV−VIS spectroscopy, FT-IR, scanning electron microscopy (SEM-EDX), and dynamic light scattering (DLS). The results demonstrated obtaining spherical, stable AgNPs with a diameter of less than 69 nm and an absorbance peak at 435 nm. The mixture of extracts and AgNPs showed a superior antioxidant capacity of 2.3 ± 0.4% inhibition determined by the DPPH assay, 88.5 ± 0.9% inhibition as determined by the ABTS•+ assay, and a good antibacterial activity against several human pathogens: Escherichia coli, Klebsiella pneumoniae, Pseudomonas fluorescens, and Staphylococcus aureus.  相似文献   
639.
Heat transfer over a stretching surface with uniform or variable heat flux in micropolar fluids is investigated in this Letter. The boundary layer equations are transformed into ordinary differential equations, and then they are solved numerically by a finite-difference method. The effects of the material parameter K, Prandtl number Pr, velocity exponent parameter m, and heat flux exponent parameter n on the heat transfer characteristics are studied. It is found that the local Nusselt number is higher for micropolar fluids compared to Newtonian fluids.  相似文献   
640.
The characteristics of optical radiation produced under bombardment by ions (1–15 keV) and electrons (100–1000 eV) of a ruby surface are studied. Two broad bands with maxima at 330 and 450 nm attributed to defects of the crystal lattice are discovered in the spectral region of 200 to 800 nm. Characteristic radiation related to radiative relaxation of excited Cr3+ ions in the near-surface region of the crystal is observed. The dependence of the radiation intensity on the energy and current density of the bombarding particles is obtained experimentally. The degree of radiation polarization is determined.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号