全文获取类型
收费全文 | 1260篇 |
免费 | 33篇 |
国内免费 | 3篇 |
专业分类
化学 | 719篇 |
晶体学 | 9篇 |
力学 | 35篇 |
数学 | 149篇 |
物理学 | 384篇 |
出版年
2024年 | 1篇 |
2023年 | 9篇 |
2022年 | 19篇 |
2021年 | 42篇 |
2020年 | 33篇 |
2019年 | 37篇 |
2018年 | 37篇 |
2017年 | 29篇 |
2016年 | 52篇 |
2015年 | 45篇 |
2014年 | 55篇 |
2013年 | 92篇 |
2012年 | 93篇 |
2011年 | 103篇 |
2010年 | 70篇 |
2009年 | 71篇 |
2008年 | 93篇 |
2007年 | 76篇 |
2006年 | 73篇 |
2005年 | 57篇 |
2004年 | 35篇 |
2003年 | 14篇 |
2002年 | 26篇 |
2001年 | 20篇 |
2000年 | 17篇 |
1999年 | 12篇 |
1998年 | 5篇 |
1997年 | 4篇 |
1996年 | 16篇 |
1995年 | 13篇 |
1994年 | 10篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1991年 | 10篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1972年 | 1篇 |
1937年 | 1篇 |
排序方式: 共有1296条查询结果,搜索用时 93 毫秒
101.
Rafael Y. O. Moreira Davi S. B. Brasil Cláudio N. Alves Giselle M. S. P. Guilhon Lourivaldo S. Santos Mara S. P. Arruda Adolfo H. Müller Patrícia S. Barbosa Alcicley S. Abreu Edilene O. Silva Victor M. Rumjanek Jaime Souza Jr. Albérico B. F. da Silva Regina H. de A. Santos 《International journal of quantum chemistry》2008,108(3):513-520
Julocrotine, N‐(2,6‐dioxo‐1‐phenethyl‐piperidin‐3‐yl)‐2‐methyl‐butyramide, is a potent antiproliferative agent against the promastigote and amastigote forms of Leishmania amazonensis (L.). In this work, the crystal structure of Julocrotine was solved by X‐ray diffraction, and its geometrical parameters were compared with theoretical calculations at the B3LYP and HF level of theory. IR and NMR spectra also have been obtained and compared with theoretical calculations. IR absorptions calculated with the B3LYP level of theory employed together with the 6‐311G+(d,p) basis set, are close to those observed experimentally. Theoretical NMR calculations show little deviation from experimental results. The results show that the theory is in accordance with the experimental data. © 2007 Wiley Periodicals, Inc. Int J Quantum Chem, 2008 相似文献
102.
C Alves J M Valério de Carvalho 《The Journal of the Operational Research Society》2008,59(11):1520-1531
Apart from trim loss minimization, there are many other issues concerning cutting processes that arise in real production systems. One of these is related to the number of stacks that need to be opened near the cutting machines. Many researchers have worked in the last years on cutting stock problems with additional constraints on the number of open stacks. In this paper, we address a related problem: the Ordered Cutting Stock Problem (OCSP). In this case, a stack is opened for every new client's order, and it is closed only when all the items of that order are cut. The OSCP has been introduced recently in the literature. Our aim is to provide further insight into this problem. This paper describes three new integer programming formulations for solving it, and an exact algorithm based on column generation, branch-and-bound and cutting planes. We report on computational experiments on a set of random instances. The results show that good lower bounds can be computed quickly, and that optimal solutions can be found in a reasonable amount of time. 相似文献
103.
104.
105.
Fractal modeling of the rugged crack geometry is considered for the stable and dynamic fracture mechanics characterizing the morphology of a fracture surface and the influence of its growth. It is shown that the fractal dimension has a strong influence on the rising of the R-curve in brittle materials. For the unstable Griffith–Mott’s approach or dynamical crack growth the fractal dimension has a strong influence on the velocity limit of the crack growth. It is also shown that the limit of crack velocity lowers with increasing surface ruggedness (higher fractal dimension D = 2 − H) explaining the intangibility of the Rayleigh wave velocity by the cracks. 相似文献
106.
Filgueira Dde M Guterres LP Votto AP Vargas MA Boyle RT Trindade GS Nery LE 《Photochemistry and photobiology》2010,86(6):1278-1284
The purpose of this study was to verify the occurrence of pigment dispersion in retinal pigment cells exposed to UVA and UVB radiation, and to investigate the possible participation of a nitric oxide (NO) pathway. Retinal pigment cells from Neohelice granulata were obtained by cellular dissociation. Cells were analyzed for 30 min in the dark (control) and then exposed to 1.1 and 3.3 J cm−2 UVA, 0.07 and 0.9 J cm−2 UVB, 20 n m β-PDH (pigment dispersing hormone) or 10 μ m SIN-1 (NO donor). Histological analyses were performed to verify the UV effect in vivo . Cultured cells were exposed to 250 μ m L-NAME (NO synthase blocker) and afterwards were treated with UVA, UVB or β-PDH. The retinal cells in culture displayed significant pigment dispersion in response to UVA, UVB and β-PDH. The same responses to UVA and UVB were observed in vivo . SIN-1 did not induce pigment dispersion in the cell cultures. l-NAME significantly decreased the pigment dispersion induced by UVA and UVB but not by β-PDH. All retinal cells showed an immunopositive reaction against neuronal nitric oxide synthases. Therefore, UVA and UVB radiation are capable of inducing pigment dispersion in retinal pigment cells of Neohelice granulata and this dispersion may be nitric oxide synthase dependent. 相似文献
107.
The adsorption of HSA onto CHI/ALG multilayer assemblies was assessed in situ using QCM-D. It was found that the behavior of HSA on biomaterials surface can be tuned by adjusting parameters of the polyelectrolyte system such as pH, layer number, crosslinker and polymer terminal layer. Our results confirmed the key role of electrostatic interactions during HSA adsorption, since oppositely charged surfaces were more effective in promoting protein adhesion. QCM-D data revealed that crosslinking (CHI/ALG)(5) CHI films allows HSA to become adsorbed in physiological conditions. Our results suggested that the biological potential of biopolymers and the mild conditions of the LbL technique turn these natural nanoassemblies into a suitable choice to be used as pH-sensitive coatings. 相似文献
108.
Mariana R. Almeida Rafael S. Alves Laura B. L. R. Nascimbem Rodrigo Stephani Ronei J. Poppi Luiz Fernando C. de Oliveira 《Analytical and bioanalytical chemistry》2010,397(7):2693-2701
Fourier transform Raman spectroscopy and chemometric tools have been used for exploratory analysis of pure corn and cassava starch samples and mixtures of both starches, as well as for the quantification of amylose content in corn and cassava starch samples. The exploratory analysis using principal component analysis shows that two natural groups of similar samples can be obtained, according to the amylose content, and consequently the botanical origins. The Raman band at 480 cm?1, assigned to the ring vibration of starches, has the major contribution to the separation of the corn and cassava starch samples. This region was used as a marker to identify the presence of starch in different samples, as well as to characterize amylose and amylopectin. Two calibration models were developed based on partial least squares regression involving pure corn and cassava, and a third model with both starch samples was also built; the results were compared with the results of the standard colorimetric method. The samples were separated into two groups of calibration and validation by employing the Kennard-Stone algorithm and the optimum number of latent variables was chosen by the root mean square error of cross-validation obtained from the calibration set by internal validation (leave one out). The performance of each model was evaluated by the root mean square errors of calibration and prediction, and the results obtained indicate that Fourier transform Raman spectroscopy can be used for rapid determination of apparent amylose in starch samples with prediction errors similar to those of the standard method. Figure
Raman spectroscopy has been successfully applied to the determination of the amylose content in cassava and corn starches by means of multivariate calibration analysis. 相似文献
109.
We propose a Moreau–Yosida regularization for maximal monotone operators of type (D), in non-reflexive Banach spaces. It generalizes
the classical Moreau–Yosida regularization as well as Brezis–Crandall–Pazy’s extension of this regularization to strictly
convex (reflexive) Banach spaces with strictly convex duals. Our main results are obtained by making use of recent results
by the authors on convex representations of maximal monotone operators in non-reflexive Banach spaces. 相似文献
110.
Abazov VM Abbott B Acharya BS Adams M Adams T Alexeev GD Alkhazov G Alton A Alverson G Alves GA Aoki M Arov M Askew A Asman B Atramentov O Avila C Backusmayes J Badaud F Bagby L Baldin B Bandurin DV Banerjee S Barberis E Baringer P Barreto J Bartlett JF Bassler U Bazterra V Beale S Bean A Begalli M Begel M Belanger-Champagne C Bellantoni L Beri SB Bernardi G Bernhard R Bertram I Besançon M Beuselinck R Bezzubov VA Bhat PC Bhatnagar V Blazey G Blessing S Bloom K Boehnlein A Boline D Boos EE 《Physical review letters》2011,107(1):011804
We present a study of the dijet invariant mass spectrum in events with two jets produced in association with a W boson in data corresponding to an integrated luminosity of 4.3 fb(-1) collected with the D0 detector at √s = 1.96 TeV. We find no evidence for anomalous resonant dijet production and derive upper limits on the production cross section of an anomalous dijet resonance recently reported by the CDF Collaboration, investigating the range of dijet invariant mass from 110 to 170 GeV/c(2). The probability of the D0 data being consistent with the presence of a dijet resonance with 4 pb production cross section at 145 GeV/c(2) is 8×10(-6). 相似文献