全文获取类型
收费全文 | 2332篇 |
免费 | 47篇 |
国内免费 | 13篇 |
专业分类
化学 | 1359篇 |
晶体学 | 24篇 |
力学 | 57篇 |
数学 | 306篇 |
物理学 | 646篇 |
出版年
2021年 | 16篇 |
2020年 | 18篇 |
2019年 | 16篇 |
2018年 | 17篇 |
2017年 | 13篇 |
2016年 | 32篇 |
2015年 | 24篇 |
2014年 | 33篇 |
2013年 | 104篇 |
2012年 | 124篇 |
2011年 | 129篇 |
2010年 | 58篇 |
2009年 | 41篇 |
2008年 | 118篇 |
2007年 | 107篇 |
2006年 | 85篇 |
2005年 | 94篇 |
2004年 | 90篇 |
2003年 | 71篇 |
2002年 | 67篇 |
2001年 | 41篇 |
2000年 | 51篇 |
1999年 | 31篇 |
1998年 | 22篇 |
1997年 | 23篇 |
1996年 | 41篇 |
1995年 | 35篇 |
1994年 | 32篇 |
1993年 | 41篇 |
1992年 | 39篇 |
1991年 | 20篇 |
1990年 | 29篇 |
1989年 | 32篇 |
1988年 | 37篇 |
1987年 | 26篇 |
1986年 | 17篇 |
1985年 | 43篇 |
1984年 | 42篇 |
1983年 | 28篇 |
1982年 | 39篇 |
1981年 | 28篇 |
1980年 | 36篇 |
1979年 | 30篇 |
1978年 | 39篇 |
1977年 | 31篇 |
1976年 | 34篇 |
1975年 | 20篇 |
1974年 | 29篇 |
1973年 | 30篇 |
1972年 | 15篇 |
排序方式: 共有2392条查询结果,搜索用时 265 毫秒
171.
Various equations for tc obtained from approximations to the Eliashberg theory are numerically solved and Tcvs λ curves are drawn. Specifically, the weak coupling Kirzhnits, Maksimov and Khomskii (KMK) equation, Eliashberg equation and BCS equation with Bardeen Pines interaction are considered with the α2F function of Nb. The KMK equation gives quite a high value or Tc and the BCS equation overestimates Tc by an even larger factor when compared with the results of the Eliashberg equation. 相似文献
172.
The liquid-phase thermolysis of 1,2-dihydronaphthalene was studied in a batch reactor in the range of 350–400°C. The measured product distributions were in good agreement with calculations based on a free-radical scheme with rate constants estimated by thermochemical methods. The kinetic calculations were carried out by numerical integration and by the long-chain approximation (LCA), which yielded a closed-form solution. 相似文献
173.
Ken D.?OlumEmail author Allen?EverettEmail author 《Foundations of Physics Letters》2005,18(4):379-385
In a recent paper, Mallett found a solution of the Einstein equations in which closed timelike curves (CTC’s) are present in the empty space outside an infinitely long cylinder of light moving in circular paths around an axis. Here we show that, for physically realistic energy densities, the CTC’s occur at distances from the axis greater than the radius of the visible universe by an immense factor. We then show that Mallett’s solution has a curvature singularity on the axis, even in the case where the intensity of the light vanishes. Thus it is not the solution one would get by starting with Minkowski space and establishing a cylinder of light. 相似文献
174.
Cui C Shafir A Schmidt JA Oliver AG Arnold J 《Dalton transactions (Cambridge, England : 2003)》2005,(8):1387-1393
Reaction of SmCl3 with 1 eq of KL (L =[DippNC(Me)CHC(Me)NDipp]; Dipp = 2,6-i-Pr2C6H3) in THF afforded the dimeric samarium dichloride LSmCl2(THF)Cl2SmL (1) in high yield. Reactions of 1 with NaN(SiMe3)2, KNHAr (Ar = 2,4,6-t-Bu3C6H2), KBHEt3, and KCp*(Cp*= C5Me5) yielded various new complexes: LSmClN(SiMe3)2 (2), LSm[N(SiMe3)2]2 (3), LSmNHAr(HBEt3) (4), LSm(NHAr)2 (5), and LSmCp*Cl (6). Reaction of 1 with one eq of NaN(SiMe3)2 followed by treatment with excess AlMe3 afforded a unique bimetallic samarium tetramer Cl3L2Sm2(AlMe4)2Sm2L2Cl3 (7). Reaction of 6 with LiMe or LiCH2SiMe3 afforded LSmCp*Me (8) and LSmCp*CH2SiMe3 (9) in excellent yield. Methyl abstraction from with B(C6F5)3 in toluene yielded the cationic borate species (LSmCp*)[MeB(C6F5)3] (10). Molecular structures of 1-7 and 9 were determined by X-ray single crystal analysis. 相似文献
175.
176.
We show how an effective nonlocality in imaging can lead to the sampling of a spatial region which is not significantly illuminated by an imaging probe. The nonlocality is embodied in the effective nonlocal potential describing inelastic scattering which occurs when coupled channel Schr?dinger equations are reduced to a single integro-differential equation. The context in which this prediction will be illustrated is atomic resolution imaging based on energy-loss spectroscopy in scanning transmission electron microscopy. 相似文献
177.
Terahertz absorption in waveguides loaded with InAs/AlSb super-superlattice mesas reveals a frequency dependent crossover from loss to gain that is related to the Stark ladder produced by an applied dc electric field. Electric field domains appear to be suppressed in the super-superlattice composed of many very short segments of superlattice, interrupted by heavily doped InAs regions. Resonant crossover is indicated by an increase in terahertz transmission as the Stark splitting or Bloch frequency determined by the applied dc electric field exceeds the measurement frequency. 相似文献
178.
Griffith BR Allen BL Rapraeger AC Kiessling LL 《Journal of the American Chemical Society》2004,126(6):1608-1609
We report the design and synthesis of well-defined polymers for the noncovalent oligomerization of proteins. The reported scaffolds, which were generated by atom-transfer radical polymerization (ATRP), take advantage of the well-characterized interaction between a Ni2+ complex and an oligohistidine sequence (His tag). Thus, our polymers are designed to facilitate the oligomerization of any protein possessing a His tag. We demonstrate that they can oligomerize fibroblast growth factor-8b (FGF-8b) and promote FGF-8b-mediated cell proliferation in the absence of heparin. 相似文献
179.
Szöke E Máday E Gershenzon J Allen JL Lemberkovics E 《Journal of chromatographic science》2004,42(5):229-233
Gas chromatography (GC) and GC-mass spectrometry are used to identify a new sesqiterpene, beta-eudesmol, which seems to be a characteristic essential oil component of the intact and in vitro organized root of chamomile [Chamomilla recutita (L.) Rauschert]. It is identified on three types of stationary phases by GC. The confirmation of identity is carried out by comparison of mass spectra with those reported in the literature and measured from a reference compound. The percentage evaluation of the oil component is made by area normalization, on the basis of three parallel measurements. Among the cultivated and wild chamomile species examined, the wild species from the areas of Szeghalom contain the highest quantity of beta-eudesmol (9.25% in the total essential oil). 相似文献
180.
We applied a finite-difference time domain algorithm to the study of field and intensity correlations in random media. Close to the onset of Anderson localization, we observe deviations of the correlation functions, in both shape and magnitude, from those predicted by the diffusion theory. Physical implications of the observed phenomena are discussed. 相似文献