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91.
Abstract A new type of fire-retardant polymer has been formed by modification of dispersions of chitosan [(1,4)-2-amino-2-deoxy-β-D-glucan] in inert organic liquids using hexachlorocyclotriphos-phazene or octachlorocyclotetraphosphazene as well as mixtures thereof in the presence of an acid acceptor. The reaction products are essentially insoluble and infusible, contain up to 8% phosphorus, and have IR spectra indicative of exclusive reaction at the amino groups of the aminopolysaccharide. The influence of reaction conditions on the characteristics of the products is discussed. 相似文献
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Hamoud Moustafa A. Allan Karam F. Sanad Wafaa A. Saad Ebtissam A. Mahmoud Mamdoh R. 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(2):647-661
Polyacrylonitrile/ferrocyanide composite incorporated with cetrimonium bromide (PFICB) was synthesized and evaluated as a novel bifunctional adsorbent for coremoval of Cs+ and HCrO4?. Results of the reaction time effect showed that adsorption of Cs+ and HCrO4? onto PFICB were rapid processes. The effect of the solution pH in the range 2.5–10 revealed that PFICB had the ability to simultaneously remove Cs+ and HCrO4?. The maximum adsorption capacity of PFICB was found to be 41.79 mg/g for Cs+ and 19.39 mg/g for HCrO4?. These values were compared with those reported in literature using other adsorbents.
相似文献95.
Sumit Dadhwal Arnold Lee Shailesh K. Goswami Sarah Hook Allan B. Gamble 《Journal of polymer science. Part A, Polymer chemistry》2021,59(7):646-658
Self-immolative aryl azides can react with trans-cyclooctenes (TCO), triphenylphosphines or hydrogen sulfide (H2S) to activate prodrugs, imaging probes and drug delivery systems. To date, the synthesis of polymers containing these aryl azide self-immolative linkers and their reactivity with a strained alkene (i.e., in a bioorthogonal reaction) has not been explored. Also, due to the instability of aryl azides towards light and high temperatures, the polymerization methods compatible with aryl azides are limited. Through systematic investigation of the reversible addition-fragmentation chain transfer (RAFT) and atom transfer radical polymerization (ATRP) methods, a self-immolative PEG-aryl azide block copolymer (PEG45-b-ABOC28 2 ) and a non-responsive 4-fluoroaryl block copolymer (PEG45-b-FBOC24 3 ) was prepared. ATRP provided the desired polymers in a highly controlled manner, whereas the RAFT conditions led to higher levels of aryl azide polymer degradation. The ATRP derived polymers 2 and 3 were formulated into nanoparticles of approximately 200 nm diameter, and particle triggering was demonstrated by the [3+2]-cycloaddition reaction of TCO with PEG45-b-ABOC28 2 in solution (pure polymer) and as a formulated nanoparticle. Preliminary in vitro cell viability studies suggested that the stimuli-responsive aryl azide polymers/nanoparticles are not cytotoxic up to 200 μg/ml concentrations. 相似文献
96.
A series of enantioenriched six-membered metallocyclic amidomagnesium naphtholates were prepared and used to probe the structure–reactivity/selectivity relationships of heteroleptic magnesium base complexes within asymmetric deprotonation reactions. An effective complex was identified and applied within enantioselective enolisation processes, delivering good levels of enantioselectivity and also revealing key structural requirements for achieving such selectivity. 相似文献
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Magdy H. Metry Allan R. Sampson 《Journal of computational and graphical statistics》2013,22(2):209-223
Abstract This article introduces an approach for characterizing the classes of empirical distributions that satisfy certain positive dependence notions. Mathematically, this can be expressed as studying certain subsets of the class SN of permutations of 1, …, N, where each subset corresponds to some positive dependence notions. Explicit techniques for it-eratively characterizing subsets of SN that satisfy certain positive dependence concepts are obtained and various counting formulas are given. Based on these techniques, graph-theoretic methods are used to introduce new and more efficient algorithms for constructively generating and enumerating the elements of various of these subsets of SN. For example, the class of positively quadrant dependent permutations in SN is characterized in this fashion. 相似文献
99.
Allan R. Wilks 《Journal of computational and graphical statistics》2013,22(4):400-414
Abstract Pictor is an environment for statistical graphics that promotes simple commands for common uses and offers the ability to experiment with whole new paradigms. Pictor describes graphs as graphical objects whose component pieces are related by several sorts of constraints. This article describes in detail the constraint system that Pictor uses. 相似文献
100.
Vladimir Fal’ko Andre Geim Sankar Das Sarma Allan MacDonald Philip Kim 《Solid State Communications》2009,149(27-28):1039-1040