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131.
The influence of annealing on the structure and opto-electronic properties of Cu0.9In1.0Se2.0 films prepared by solution growth technique has been studied. The films annealed at 500–520°C in air, vacuum (10?4 torr), In-vapour and Se-vapour show polycrystalline chalcopyrite structure with orientation perpendicular to the (220) plane. Films annealed in Se-vapour at 500°C for 30 min have maximum grain size (560 Å), minimum optical energy gap, maximum absorption coefficient, lowest resistivity, maximum photosensitivity and thus are suitable for photovoltaic applications. Annealing in In-vapour or in vacuum changesp-type CuInSe2 inton-type which possibly arises due to the increase in Se vacancies. 相似文献
132.
Acyclic digraphs, such as the covering digraphs of ordered sets, are usually drawn upward, i.e., with the edges monotonically increasing in the vertical direction. A digraph is upward planar if it admits an upward planar drawing. In this survey paper, we overview the literature on the problem of upward planarity testing. We present several characterizations of upward planarity and describe upward planarity testing algorithms for special classes of digraphs, such as embedded digraphs and single-source digraphs. We also sketch the proof of NP-completeness of upward planarity testing.Research supported in part by the National Science Foundation under grant CCR-9423847. 相似文献
133.
S.K. Malik R. Vijayaraghavan S.K. Garg R.J. Ripmeester 《Solid State Communications》1977,21(3):245-247
The 119Sn Knight shift in SmSn3 has been measured in the temperature range 15—300 K, and it is found that the 4f-contribution to the Knight shift does not show a sign reversal in this temperature interval. The range of crystal field parameters for which simultaneous fit to the magnetic susceptibility and the extended Knight shift results in SmSn3 is obtained can be substantially narrowed from that reported earlier. 相似文献
134.
A method to study domain structure in ferroelectrics, using pyroelectric effect is described. Variation of pyroelectric signal
from the surface of a triglycine sulphate crystal plate has been studied by scanning the surface of the crystal with a low
wattage He-Ne laser beam. The integrated pyroelectric signal is due to two components, namely, (1) the primary component arising
out of the change in spontaneous polarization with temperature and (2) the delayed component arising out of the possible polarization
reversal. The component of an electric field along the ferroelectric axis due to thermal hemisphere within the crystal plate
formed by the laser beam has been calculated and shown to exceed coercive field, making polarization reversal possible. The
delayed pyroelectric signal is a measure of polarization reversal within the patch illuminated and its observed variation
over the surface yields information of the domain structure. 相似文献
135.
Complexation of 3-nitroso-4-hydroxy-5, 6-benzocoumarin with iron (II) is used to detect iron in presence of various ions present in the scheme of semi-micro qualitative analysis. The method finds application in detection of iron in alloys, inorganic salts and various pharmaceutical products. 相似文献
136.
Mössbauer absorption of Fe57 in naturally occuring and synthetic crystals of FeS2, marcasite, has been studied in the ideal absorber thickness in the transmission geometry from a Co57/Rh and Co57/LiNbO3 source. The recoilles fraction at room temperature, 298 K, has been obtained to be 0.2 and the mean square displacement < r2 > was found to be 13×10-19 cm2 at room temperature, 298 K. Because of the small size of marcasite crystals it has not been possible to record good spectra of the monocrystals as a function of the orientation of the incident gamma rays from Co57/LiNbO3 source. 相似文献
137.
M.S. Sethi P.S. Raghavan B.S. Garg R.P. Singh Mahendra K. Gadia 《Microchemical Journal》1981,26(2):210-216
Polarography of 1,2-acenaphthaquinone monoxime has been carried out in buffers (pH 3.5–13.0) of constant ionic strength 0.5 M and 40% alcohol at 25 ± 0.5 °C. The oxime group underwent diffusion-controlled reduction (4e) over the whole pH range. The number of electrons involved in the reduction was found by coulometric method as well as by incorporating the values of diffusion coefficients, obtained by using a McBain-Dawson cell, into the Ilkovi? equation. Koutecky's method has been used to compute the kinetic parameters (αnaand ?log Kf.h) for the reduction of the oxime group and a reduction mechanism is proposed. 相似文献
138.
139.
D. W. Davidson S. K. Garg S. R. Gough Y. P. Handa C. I. Ratcliffe J. S. Tse J. A. Ripmeester 《Journal of inclusion phenomena and macrocyclic chemistry》1984,2(1-2):231-238
X-ray and neutron diffraction studies show argon and krypton to preferentially form clathrate hydrates of structure II, rather than structure I as previously assumed; methane and hydrogen sulphide do form structure I. Re-examination of solid-solution thermodynamic theory shows that structure II is basically the more stable; structure I is generally formed only when the guest molecule is in the size range that favours occupancy of the 14-hedral over the 12-hedral cages. For molecules too large to enter the 12-hedra the relative stability of structure II is greatest at 0°C, in agreement with the observed sequence of change of stability of cyclopropane hydrate: I to II at –16° and II to I at 1.5°. Carbon dioxide hydrate is observed to decompose on prolonged standing at 105K in accord with the low-temperature instability predicted by Miller. 相似文献
140.