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121.
While handling liquids in rigid intermediate bulk containers (RIBC), the assessment of ignition sources due to electrostatic discharges is of especial interest since it is often difficult to rule out all possible conditions which can lead to the generation of an effective discharge. Far from suggesting new criteria for the selection or construction of RIBC or standards for its design, this paper has the aim of describing three incidents where an electrostatic discharge caused a flammable mixture of vapours with air to ignite. Situations presented could usually be rated as highly remote on its probability of occurrence by operators since they are common and never caused an incident, but on the other hand it is rather easy, from a theoretical point of view, to explain the phenomena observed by applying the basic assessment rules for the generation of electrostatic ignition sources.If existing guidelines were to have been followed (mainly CENELEC 50404 and BGR132), those incidents would have not occurred. 相似文献
122.
Protein Extraction and Enzymatic Hydrolysis of Ammonia-Treated Cassava Leaves (Manihot esculenta Crantz) 总被引:2,自引:0,他引:2
Lauris Urribarrí David Chacón Orlaidy González Alexis Ferrer 《Applied biochemistry and biotechnology》2009,153(1-3):94-102
In the present work, cassava leaves were treated with 0.5 kg ammonia/kg dry matter at 78 °C and 30% moisture content in a 2-kg reactor. Protein extraction was carried out with a calcium hydroxide solution (pH 10) for 30 min at several temperatures (30 °C, 45 °C, 60 °C, 75 °C, and 90 °C) and solid/liquid ratios (1:10 and 1:15) in a thermostatized bath. Soluble protein content of the extracts was determined by Lowry’s method. Dry substrate concentrations of 5%, 7.5%, and 10% and enzyme doses of 2 and 5 IU/g dry matter were used for the enzymatic hydrolysis in an orbital incubator at 50 °C and 100 rpm. Both cellulase and xylanase were used. Reducing sugars produced were determined with the dinitrosalicylic acid method. The highest protein extraction yield for the ammonia-treated leaves was 29.10%, which was 50% higher than with the untreated leaves (20%), and was obtained at 90 °C with a 1:10 solid/liquid ratio. The concentrate had a protein content of 36.35% and the amino acid profile was suitable for swine and poultry. The highest sugar yield was 54.72% with respect to theoretical and was obtained with 5% solids and an enzyme dose of 5 IU/g dry matter. This yield was 3.4 times higher than the yield of the untreated leaves (16.13%). These results indicate that cassava leaves have a great potential for animal feeding and ethanol production. Both protein extraction and sugar yields may be enhanced by optimizing the ammonia treatment. 相似文献
123.
Fuat E. Celik Tae‐Jin Kim Dr. Alexis T. Bell Prof. 《Angewandte Chemie (International ed. in English)》2009,48(26):4813-4815
Carbonylation gets a phase lift : The usual liquid‐phase, high‐pressure processes for carbonylating formaldehydes are avoided in a novel vapor‐phase reaction. Using an acid zeolite (Faujasite) at near‐atmospheric pressure dimethoxymethane (DMM; the dimethyl acetal of formaldehyde; see scheme) is carbonylated to produce methyl methoxyacetate (MMAc). This approach provides a new route to ethylene glycol under mild conditions.
124.
Bourikas K Kordulis C Lycourghiotis A 《Advances in colloid and interface science》2006,121(1-3):111-130
The mechanism of the protonation of solid metal (hydr)oxides in aqueous media was investigated using simulation and experimental work. It was found that the apparent acidity/basicity of each kind of surface sites of metal (hydr)oxides in aqueous suspensions is strongly influenced by the overall surface charge of the (hydr)oxide and thus by the electrical potential smeared out at the interfacial region. Depending on its sign this increases or decreases the hydrogen ion concentration on the surface, thus promoting or hindering protonation. This is manifested by the shifts of the protonation peaks of the various kinds of sites with respect to the -pK values of the corresponding intrinsic protonation constants and the appearance of an extra peak in the d[H+cons,surf]/dpH vs. pH curves. Potentiometric titrations experiments performed for four technologically important oxides showed that the proposed protonation mechanism describes indeed the protonation of polycrystalline (hydr)oxides in aqueous media. 相似文献
125.
Alexis Larranaga 《理论物理通讯》2011,55(1):72-74
We study the entropy of the Gibbons-Maeda-Garfinkle-Horowitz-Strominger (GMGHS) charged black hole, originated from the effective action thatemerges in the low-energy of string theory, beyond semiclassical approximations. Applying the properties of exact differentials for three variables to the first law thermodynamics we derive the quantum correctionsto the entropy of the black hole. The leading (logarithmic) and non leading corrections to the area law are obtained. 相似文献
126.
In this article, we investigate the kinetic/fluid coupling on a toy model, which we obtain rigorously from a hydrodynamical limit. The idea is that at the level of the full kinetic model, the coupling is obvious. We then investigate the coupling obtained when passing into the limit. We show that, especially in presence of a shock stuck on the interface, the coupling involves a kinetic layer known as the Milne problem. Due to this layer, the limit process is quite delicate and some blow-up techniques are needed to ensure its strong convergence. 相似文献
127.
We study the contraction properties (up to shift) for admissible Rankine–Hugoniot discontinuities of \({n\times n}\) systems of conservation laws endowed with a convex entropy. We first generalize the criterion developed in (Serre and Vasseur, J l’Ecole Polytech 1, 2014), using the spatially inhomogeneous pseudo-distance introduced in (Vasseur, Contemp Math AMS, 2013). Our generalized criterion guarantees the contraction property for extremal shocks of a large class of systems, including the Euler system. Moreover, we introduce necessary conditions for contraction, specifically targeted for intermediate shocks. As an application, we show that intermediate shocks of the two-dimensional isentropic magnetohydrodynamics do not verify any of our contraction properties. We also investigate the contraction properties, for contact discontinuities of the Euler system, for a certain range of contraction weights. None of the results involve any smallness condition on the initial perturbation or on the size of the shock. 相似文献
128.
Libia L. Julio Jesus Lezama Alexis Maldonado José R. Mora Gabriel Chuchani 《Journal of Physical Organic Chemistry》2014,27(5):450-455
The kinetics of the gas‐phase elimination of α‐methyl‐trans‐cinamaldehyde catalyzed by HCl in the temperature range of 399.0–438.7 °C, and the pressure range of 38–165 Torr is a homogeneous, molecular, pseudo first‐order process and undergoing a parallel reaction to produce via (A) α‐methylstyrene and CO gas and via (B) β‐methylstyrene and CO gas. The decomposition of substrate E‐2‐methyl‐2‐pentenal was performed in the temperature range of 370.0–410.0 °C and the pressure range of 44–150 Torr also undergoing a molecular, pseudo first‐order reaction gives E‐2‐pentene and CO gas. These reactions were carried out in a static system seasoned reactions vessels and in the presence of toluene free radical inhibitor. The rate coefficients are given by the following Arrhenius expressions:
- Products formation from α‐methyl‐trans‐cinamaldehyde
- α‐methylstyrene :
- β‐methylstyrene :
- Products formation from E‐2‐methyl‐2‐pentenal
- E‐2‐pentene :
129.
Edgar Marquez Alexis Maldonado Felix Rosas Beatriz Ramirez Gabriel Chuchani 《Molecular physics》2014,112(3-4):462-473
The kinetics and mechanisms of thermal decomposition of phenyl acetate and p-tolyl acetate in the gas phase were studied by means of electronic structure calculations using density functional theory methods: B3LYP/6-31G(d,p), B3LYP/6-31++G(d,p), B3PW91/6-31G(d,p), B3PW91/6-31++G(d,p), MPW1PW91/6-31G(d,p), MPW1PW91/6-31++G(d,p), PBE/6-31G(d,p) and PBE/6-31++G(d,p). Two possible mechanisms have been considered: mechanism A is a stepwise process involving electrocyclic [1,5] hydrogen shift to eliminate ketene through concerted six-membered cyclic transition-state structure, followed by tautomerisation of cyclohexadienone or by 4-methyl cyclohexadienone intermediate to give the corresponding phenol. Mechanism B is a one-step concerted [1,3] hydrogen shift through a four-membered cyclic transition-state geometry, to produce ketene and phenol or p-cresol. Theoretical calculations showed reasonable agreement with experimental activation parameters when using the Perdew, Burke and Ernserhof (PBE)functional, through the stepwise [1,5] hydrogen-shift mechanism. For mechanism B, large deviation for the entropy of activation was observed. No experimental data were available for p-tolyl acetate; however, theoretical calculations showed similar results to phenyl acetate, thus supporting the stepwise mechanism for both phenyl acetate and p-tolyl acetate. 相似文献
130.
Thomas L. Moore Rama Podilakrishna Apparao Rao Frank Alexis 《Particle & Particle Systems Characterization》2014,31(8):886-894
Graphene—2D carbon—has received significant attention thanks to its electronic, thermal, and mechanical properties. Recently, nano‐graphene (nGr) has been investigated as a possible platform for biomedical applications. Here, a polymer‐coated nGr to deliver drugs to glioblastoma after systemic administration is reported. A biodegradable, biocompatible poly(lactide) (PLA) coating enables encapsulation and controlled release of the hydrophobic anticancer drug paclitaxel (PTX), and a hydrophilic poly(ethylene glycol) (PEG) shell increases the solubility of the nGr drug delivery system. Importantly, the polymer coating mediates the interaction of nGr with U‐138 glioblastoma cells and decreases cytotoxicity compared with pristine untreated nGr. PLA‐PEG‐coated nGr is also able to encapsulate PTX at 4.15 wt% and sustains prolonged PTX release for at least 19 d. PTX‐loaded nGr‐PLA‐PEGs are shown to kill up to 20% of U‐138 glioblastoma cells in vitro. Furthermore, nGr‐PLA‐PEG and CNT‐PLA‐PEG, two carbon nanomaterials with different shapes, are able to kill U‐138 in vitro as well as free PTX at significantly lower doses of drug. Finally, in vivo biodistribution of nGr‐PLA‐PEG shows accumulation of nGr in intracranial U‐138 glioblastoma xenografts and organs of the reticuloendothelial system. 相似文献