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41.
Microbial biosynthesis of hydrocarbon from CO2 reduction driven by electron uptake process from the cathodic electrode has gained intensive attention in terms of potential industrial application. However, a lack of a model system for detailed studies on the mechanism of the CO2 reduction hinders the improvement in efficiency for microbial electrosynthesis. Here, we examined the mechanism of microbial CO2 reduction at the cathode by a well‐described microbe for extracellular electron uptake, Shewanella oneidensis MR‐1, capable of reducing gaseous CO2 to produce formic acid. Using whole‐cell electrochemical assay, we observed stable cathodic current production at ?0.65 V vs Ag/AgCl KCl sat. associated with the introduction of CO2. The observed cathodic current was enhanced by the addition of 4 μM riboflavin, which specifically accelerates the electron uptake process of MR‐1 by the interaction to its outer‐membrane c‐type cytochromes. The significant impact of an uncoupler agent and a mutant strain of MR‐1 lacking sole F‐type ATPase suggested the importance of proton import to the cytoplasm for the cathodic CO2 reduction. The present data suggest that MR‐1 potentially serves as a model system for microbial electrosynthesis from CO2. 相似文献
42.
Rabindra N. Roy Lakshmi N. Roy Kathleen A. Allen Casey J. Mehrhoff Isaac B. Henson Jessica M. Stegner Alexis L. Jenkins Ankita A. Shah Stephen D. Rocchio 《Journal of solution chemistry》2012,41(6):1044-1053
In this study, we report the pH values of two buffer solutions without chloride ion and eight buffer solutions with NaCl with an ionic strength I=0.16 mol?kg?1. Electromotive force (emf) techniques have been used to get the cell potentials at 12 temperatures from 5 to 55?°C, including 37?°C. An extended form of the Bates-Guggenheim convention is used in the entire ionic strength range, 0.04 to 0.16?mol?kg?1. The residual liquid junction potentials (??E j ) of the buffer solutions of MOBS have been estimated from previous measurements with a flowing junction cell. These values of ??E j have been used for correction in order to ascertain the operational pH values of four buffer solutions of MOBS at 25 and 37?°C. These solutions are recommended as pH standards for physiological application in the pH range 7.4 to 7.7. 相似文献
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44.
High pressure processing (HPP) has been shown to reduce microbial concentration in foods. The mechanisms of microbial inactivation by HPP have been associated with damage to cell membranes. The real-time response of bacteria to HPP was measured to elucidate the mechanisms of inactivation, which can aid in designing more effective processes. Different pressure cycling conditions were used to expose Enterobacter aerogenes cells to HPP. Propidium iodide (PI) was used as a probe, which fluoresces after penetrating cells with damaged membranes and binding with nucleic acids. A HPP vessel with sapphire windows was used for measuring fluorescence in situ. Membrane damage was detected during pressurization and hold time, but not during depressurization. The drop in fluorescence was larger than expected after pressure cycles at higher pressure and longer times. This indicated possible reversible disassociation of ribosomes resulting in additional binding of PI to exposed RNA under pressure and its release after depressurization. 相似文献
45.
Structural Effects in Visible‐Light‐Responsive Metal–Organic Frameworks Incorporating ortho‐Fluoroazobenzenes 下载免费PDF全文
Dr. Sonia Castellanos Dr. Alexis Goulet‐Hanssens Fangli Zhao Alla Dikhtiarenko Alexey Pustovarenko Prof. Stefan Hecht Prof. Jorge Gascon Prof. Freek Kapteijn Dr. David Bléger 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(2):746-752
The ability to control the interplay of materials with low‐energy photons is important as visible light offers several appealing features compared to ultraviolet radiation (less damaging, more selective, predominant in the solar spectrum, possibility to increase the penetration depth). Two different metal–organic frameworks (MOFs) were synthesized from the same linker bearing all‐visible ortho‐fluoroazobenzene photoswitches as pendant groups. The MOFs exhibit different architectures that strongly influence the ability of the azobenzenes to isomerize inside the voids. The framework built with Al‐based nodes has congested 1D channels that preclude efficient isomerization. As a result, local light–heat conversion can be used to alter the CO2 adsorption capacity of the material on exposure to green light. The second framework, built with Zr nodes, provides enough room for the photoswitches to isomerize, which leads to a unique bistable photochromic MOF that readily responds to blue and green light. The superiority of green over UV irradiation was additionally demonstrated by reflectance spectroscopy and analysis of digested samples. This material offers promising perspectives for liquid‐phase applications such as light‐controlled catalysis and adsorptive separation. 相似文献
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47.
Gwilherm Evano Dr. Alexis Coste Kévin Jouvin 《Angewandte Chemie (International ed. in English)》2010,49(16):2840-2859
Ynamides display an exceptionally fine balance between stability and reactivity. They also offer unique and multiple opportunities for the inclusion of nitrogen‐based functionalities into organic molecules, and are emerging as especially useful and versatile building blocks for organic synthesis. Recent breakthroughs in the preparation of these substrates have revitalized interest in nitrogen‐substituted alkynes, and the beginning of the 21st century has witnessed an ever‐increasing number of publications reporting the development of new reactions or synthetic sequences starting from ynamides. This Review highlights major developments in this area. 相似文献
48.
Osvaldo Pessoa Jr. Olival Freire Jr. Alexis De Greiff 《Physics in Perspective (PIP)》2008,10(2):138-162
In 1966 the Brazilian physicist Klaus Tausk (b. 1927) circulated a preprint from the International Centre for Theoretical
Physics in Trieste, Italy, criticizing Adriana Daneri,Angelo Loinger,and Giovanni Maria Prosperi’s theory of 1962 on the measurement
problem in quantum mechanics. A heated controversy ensued between two opposing camps within the orthodox interpretation of
quantum theory, represented by Léon Rosenfeld and Eugene P.Wigner. The controversy went well beyond the strictly scientific
issues, however, reflecting philosophical and political commitments within the context of the Cold War, the relationship between
science in developed and Third World countries, the importance of social skills, and personal idiosyncrasies. 相似文献
49.
Hopf group-coalgebras 总被引:2,自引:0,他引:2
Alexis Virelizier 《Journal of Pure and Applied Algebra》2002,171(1):75-122
We study algebraic properties of Hopf group-coalgebras, recently introduced by Turaev. We show the existence of integrals and traces for such coalgebras, and we generalize the main properties of quasitriangular and ribbon Hopf algebras to the setting of Hopf group-coalgebras. 相似文献
50.
Bishop AI Nieminen TA Heckenberg NR Rubinsztein-Dunlop H 《Physical review letters》2004,92(19):198104
We demonstrate an optical system that can apply and accurately measure the torque exerted by the trapping beam on a rotating birefringent probe particle. This allows the viscosity and surface effects within liquid media to be measured quantitatively on a micron-size scale using a trapped rotating spherical probe particle. We use the system to measure the viscosity inside a prototype cellular structure. 相似文献