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41.
Structural Effects in Visible‐Light‐Responsive Metal–Organic Frameworks Incorporating ortho‐Fluoroazobenzenes
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Dr. Sonia Castellanos Dr. Alexis Goulet‐Hanssens Fangli Zhao Alla Dikhtiarenko Alexey Pustovarenko Prof. Stefan Hecht Prof. Jorge Gascon Prof. Freek Kapteijn Dr. David Bléger 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(2):746-752
The ability to control the interplay of materials with low‐energy photons is important as visible light offers several appealing features compared to ultraviolet radiation (less damaging, more selective, predominant in the solar spectrum, possibility to increase the penetration depth). Two different metal–organic frameworks (MOFs) were synthesized from the same linker bearing all‐visible ortho‐fluoroazobenzene photoswitches as pendant groups. The MOFs exhibit different architectures that strongly influence the ability of the azobenzenes to isomerize inside the voids. The framework built with Al‐based nodes has congested 1D channels that preclude efficient isomerization. As a result, local light–heat conversion can be used to alter the CO2 adsorption capacity of the material on exposure to green light. The second framework, built with Zr nodes, provides enough room for the photoswitches to isomerize, which leads to a unique bistable photochromic MOF that readily responds to blue and green light. The superiority of green over UV irradiation was additionally demonstrated by reflectance spectroscopy and analysis of digested samples. This material offers promising perspectives for liquid‐phase applications such as light‐controlled catalysis and adsorptive separation. 相似文献
42.
43.
Gwilherm Evano Dr. Alexis Coste Kévin Jouvin 《Angewandte Chemie (International ed. in English)》2010,49(16):2840-2859
Ynamides display an exceptionally fine balance between stability and reactivity. They also offer unique and multiple opportunities for the inclusion of nitrogen‐based functionalities into organic molecules, and are emerging as especially useful and versatile building blocks for organic synthesis. Recent breakthroughs in the preparation of these substrates have revitalized interest in nitrogen‐substituted alkynes, and the beginning of the 21st century has witnessed an ever‐increasing number of publications reporting the development of new reactions or synthetic sequences starting from ynamides. This Review highlights major developments in this area. 相似文献
44.
Osvaldo Pessoa Jr. Olival Freire Jr. Alexis De Greiff 《Physics in Perspective (PIP)》2008,10(2):138-162
In 1966 the Brazilian physicist Klaus Tausk (b. 1927) circulated a preprint from the International Centre for Theoretical
Physics in Trieste, Italy, criticizing Adriana Daneri,Angelo Loinger,and Giovanni Maria Prosperi’s theory of 1962 on the measurement
problem in quantum mechanics. A heated controversy ensued between two opposing camps within the orthodox interpretation of
quantum theory, represented by Léon Rosenfeld and Eugene P.Wigner. The controversy went well beyond the strictly scientific
issues, however, reflecting philosophical and political commitments within the context of the Cold War, the relationship between
science in developed and Third World countries, the importance of social skills, and personal idiosyncrasies. 相似文献
45.
Hopf group-coalgebras 总被引:2,自引:0,他引:2
Alexis Virelizier 《Journal of Pure and Applied Algebra》2002,171(1):75-122
We study algebraic properties of Hopf group-coalgebras, recently introduced by Turaev. We show the existence of integrals and traces for such coalgebras, and we generalize the main properties of quasitriangular and ribbon Hopf algebras to the setting of Hopf group-coalgebras. 相似文献
46.
J. Kalinowski J. Godlewski R. Signerski 《Applied Physics A: Materials Science & Processing》1983,31(4):215-220
The recombination electroluminescence (REL) in an anthracene single crystal has been modulated by ac voltage at different dc biasing voltages. The frequency and ac voltage dependences observed are interpreted in terms of the presented model of sinusoidal current wave. The dc-voltage-induced changes in the modulation are explained by the voltage variation of the triplet exciton lifetime and wavelength of the current wave based on concomitant evolution of the triplet-to-singlet exciton concentration ratio responsible for the contribution of delayed and prompt components of the REL. 相似文献
47.
A method of determining the spatial distribution of recombination radiation in thin crystals is formulated and then applied to experimental results on double injection into tetracene. 相似文献
48.
Bishop AI Nieminen TA Heckenberg NR Rubinsztein-Dunlop H 《Physical review letters》2004,92(19):198104
We demonstrate an optical system that can apply and accurately measure the torque exerted by the trapping beam on a rotating birefringent probe particle. This allows the viscosity and surface effects within liquid media to be measured quantitatively on a micron-size scale using a trapped rotating spherical probe particle. We use the system to measure the viscosity inside a prototype cellular structure. 相似文献
49.
Parenty AD Smith LV Pickering AL Long DL Cronin L 《The Journal of organic chemistry》2004,69(18):5934-5946
A new class of phenanthridinium derivative has been isolated from the reaction of 2-bromoethyl-phenanthridinium bromide with a range of primary amines in excellent yields. The reaction pathway is unprecedented and proceeds via three cascade steps: nucleophilic attack of a primary amine on the iminium moiety of a heteroaromatic ring system and cyclization to form a five-membered ring, followed by hydride loss to yield a rearomatized dihydro-1H-imidazo[1,2-f]phenanthridinium derivative. A range of NMR phase transfer experiments were carried out to elucidate the mechanistic pathway, and the methodology has been further developed by means of a biphasic system using N-bromosuccinimide as a co-oxidizing agent. The method has also been extended to other N-heterocyclic cation derivatives such as quinolinium and quinazolinium. 相似文献
50.
We demonstrate experimentally and numerically that, by spectrally filtering the delayed optical feedback into a semiconductor laser, one can elicit novel dynamics in the frequency of the laser output light on a time scale that is set by the delay time of the feedback. In particular, we show that through a judicious choice of the filter bandwidth, and its frequency relative to that of the laser, one can produce controlled oscillations in the frequency of light from the laser. 相似文献