X-Ray Diffraction Study of Micro Amounts of Polycrystalline Samples

With the use of reference polycrystalline 6h-Al₂O₃ (NIST SRM- 1976) and MoO₃ samples we consider the most significant geometric and physical factors affecting the accuracy of X-ray diffraction data obtained on a diffractometer equipped with a flat two-dimensional detector (Debye-Scherrer scheme). A general strategy to measure polycrystalline samples in the amount of 20–30 fug is proposed. By the example of SRM-1976 it is shown that with the proper processing of two-dimensional diffraction patterns and the introduction of certain corrections the angles 2θ can be measured with the accuracy not less than ±0.01°. Even with a strong tendency of particles towards preferred orientation the relative intensities of diffraction reflections are shown to be obtained with the accuracy not less than ±10%.     

Unusual dimerization of 1-ethyl-1,2,4-triazinium salts into 4a,4b,9,10-tetrahydro-1,3,6,8,8a,10a-hexaazaphenanthrenes

1- Ethyl-3-alkylthio-5-phenyl-l,2,4-triazinium tetrafluoroborates were found to undergo an unusual dimerization on treatment with triethylamine in methanol or ethanol solution. A mechanism for the formation of 4a,4b,9,10-tetrahydro-l,3,6,8,8a,l0a-hexaazaphenanthrenes is proposed.     

Effect of the Ar-Ni(s) potential on the cross section for Ar+CH4/Ni{111} collision-induced desorption and the need for a more accurate CH4/Ni{111} potential

In a previous paper [L. Sun, P. de Sainte Claire, O. Meroueh, and W. L Hase, J. Chem. Phys. 114, 535 (2001)], a classical trajectory simulation was reported of CH(4) desorption from Ni{111} by Ar-atom collisions. At an incident angle theta(i) of 60 degrees (with respect to the surface normal), the calculated collision-induced desorption (CID) cross sections are in excellent agreement with experiment. However, for smaller incident angles the calculated cross sections are larger than the experimental values and for normal collisions, theta(i)=0 degrees , the calculated cross sections are approximately a factor of 2 larger. This trajectory study used an analytic function for the Ar+Ni(s) intermolecular potential which gives an Ar-Ni{111} potential energy minimum which is an order of magnitude too deep. In the work reported here, the previous trajectory study is repeated with an Ar+Ni(s) analytic intermolecular potential which gives an accurate Ar-Ni{111} potential energy minimum and also has a different surface corrugation than the previous potential. Though there are significant differences between the two Ar+Ni(s) analytic potentials, they have no important effects on the CID dynamics and the cross sections reported here are nearly identical to the previous values. Zero-point energy motions of the surface and the CH(4)-Ni(s) intermolecular modes are considered in the simulation and they are found to have a negligible effect on the CID cross sections. Calculations of the intermolecular potential between CH(4) and a Ni atom, at various levels of theory, suggest that there are substantial approximations in the ab initio calculation used to develop the CH(4)+Ni{111} potential. The implication is that the differences between the trajectory and experimental CID cross sections may arise from an inaccurate CH(4)+Ni{111} potential used in the trajectory simulation.     

Efficient laser induced consolidation of nanoparticulate ZnO thin films with reduced thermal budget

Layers of ZnO nanoparticles with thicknesses of about 40 nm were prepared on Si substrates. It was shown that UV laser irradiation is suitable for consolidation and significant densification of the ZnO particle layers under ambient conditions. Both experiments and simulations show that an underlying SiO₂ particle layer has a beneficial effect in inhibiting heat transfer towards the substrate and thus enables the application of temperature-sensitive carrier substrates like polymer foils despite the extremely high melting temperature of ZnO.     

Singular Values Distribution of Squares of Elliptic Random Matrices and Type B Narayana Polynomials

We consider Gaussian elliptic random matrices X of a size \(N \times N\) with parameter \(\rho \), i.e., matrices whose pairs of entries \((X_{ij}, X_{ji})\) are mutually independent Gaussian vectors with \(\mathbb {E}\,X_{ij} = 0\), \(\mathbb {E}\,X^2_{ij} = 1\) and \(\mathbb {E}\,X_{ij} X_{ji} = \rho \). We are interested in the asymptotic distribution of eigenvalues of the matrix \(W =\frac{1}{N^2} X^2 X^{*2}\). We show that this distribution is determined by its moments, and we provide a recurrence relation for these moments. We prove that the (symmetrized) asymptotic distribution is determined by its free cumulants, which are Narayana polynomials of type B:

$$\begin{aligned} c_{2n} = \sum _{k=0}^n {\left( {\begin{array}{c}n\\ k\end{array}}\right) }^2 \rho ^{2k}. \end{aligned}$$

     

Lifetime difference and CP-violating phase in the Bs0 system

From an analysis of the decay Bs0-->J/psi phi, we obtain the width difference between the light and heavy mass eigenstates DeltaGamma identical with (GammaL-GammaH)=0.17+/-0.09(stat)+/-0.02(syst) ps-1 and the CP-violating phase phis=-0.79+/-0.56(stat)(-0.01)(+0.14)(syst). Under the hypothesis of no CP violation (phis identical with 0), we obtain 1/Gamma=tau(Bs0)=1.52+/-0.08(stat)(-0.03)(+0.01)(syst) ps and DeltaGamma=0.12(-0.10)(+0.08)(stat)+/-0.02(syst) ps-1. The data sample corresponds to an integrated luminosity of about 1.1 fb-1 accumulated with the D0 detector at the Fermilab Tevatron collider. This is the first direct measurement of the CP-violating mixing phase in the Bs0 system.     

Search for the standard model Higgs boson in the H→WW→lνq'q decay channel

We present a search for the standard model Higgs boson (H) in pp collisions at sqrt(s)=1.96 TeV in events containing a charged lepton (?), missing transverse energy, and at least two jets, using 5.4 fb(-1) of integrated luminosity recorded with the D0 detector at the Fermilab Tevatron Collider. This analysis is sensitive primarily to Higgs bosons produced through the fusion of two gluons or two electroweak bosons, with subsequent decay H→WW→?νq'q, where ? is an electron or muon. The search is also sensitive to contributions from other production channels, such as WH→?νbb. In the absence of a signal, we set limits at the 95% C.L. on the cross section for H production σ(pp→H+X) in these final states. For a mass of M(H)=160 GeV, the limit is a factor of 3.9 larger than the cross section in the standard model and consistent with an a priori expected sensitivity of 5.0.     

First study of the radiation-amplitude zero in Wgamma production and limits on anomalous WWgamma couplings at sqrt[s]=1.96 TeV

We present results from a study of pp-->Wgamma+X events utilizing data corresponding to 0.7 fb{-1} of integrated luminosity at sqrt[s]=1.96 TeV collected by the D0 detector at the Fermilab Tevatron Collider. We set limits on anomalous WWgamma couplings at the 95% C.L. The one-dimensional 95% C.L. limits are 0.49相似文献   

Precision measurement of the ratio B(t→Wb)/B(t→Wq) and extraction of V(tb)

We present a measurement of the ratio of top quark branching fractions R=B(t→Wb)/B(t→Wq), where q can be a d, s, or b quark, in the lepton+jets and dilepton tt final states. The measurement uses data from 5.4 fb(-1) of pp collisions collected with the D0 detector at the Fermilab Tevatron Collider. We measure R=0.90±0.04, and we extract the Cabibbo-Kobayashi-Maskawa (CKM) matrix element |V(tb)| as |V(tb)|=0.95±0.02, assuming unitarity of the 3×3 CKM matrix.     

Motion of compliant capsules on corrugated surfaces: A means of sorting by mechanical properties

We discuss a novel method for capturing the dynamic coupling between a fluid and an elastic solid, the so-called fluid–structure interaction. This method integrates a lattice Boltzmann model to capture the fluid dynamics with a lattice spring model to capture the micromechanics of the solid phase. We then examine the fluid-driven motion of microcapsules, which are modeled as fluid-filled, elastic shells, along a corrugated substrate. We show that the ability of the capsules to navigate along the surface depends critically on capsule's elastic modulus. In particular, we illustrate how this substrate can be utilized to design a device for sorting microcapsules by their mechanical properties. These results apply not only to polymeric microcapsules, but also describe the interaction between the substrate and certain biological cells (e.g., leukocytes and other cells with cytoskeletons). Hence, by isolating species of a certain stiffness, the device could be highly useful for applications in biotechnology and tissue engineering or in the quality control of fabricated microcapsules. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2667–2678, 2006