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151.
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Alex ZeaAndrea-Nekane R. Alba Natalia BravoAlbert Moyano Ramon Rios 《Tetrahedron》2011,67(14):2513-2529
Asymmetric organocatalytic additions of anthrones to activated alkenes are discussed. The reaction between anthrone or dithranol and α,β-unsaturated aldehydes is catalyzed by diphenylprolinol trimethylsilyl ether in toluene at −40 °C, giving the Michael adducts with good yields and enantioselectivities. Bifunctional amino-thioureas efficiently catalyze the additions of anthrones to both nitroalkenes and maleimides, and high enantioselectivities can be achieved in both instances at room temperature. In the case of nitroalkenes, a Michael addition takes exclusively place. Anthrone generally gives Diels-Alder cycloadducts in the reaction with maleimides, while dithranol affords the Michael adducts. Transition state working models in which the bifunctional catalyst binds simultaneously to the alkene and to the anthrone enolate account for the stereochemical outcome of these additions. 相似文献
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We investigate finite lattice approximations to the Wilson renormalization group in models of unconstrained spins. We discuss first the properties of the renormalization group transformation (RGT) that control the accuracy of this type of approximation and explain different methods and techniques to practically identify them. We also discuss how to determine the anomalous dimension of the field. We apply our considerations to a linear sigma model in two dimensions in the domain of attraction of the Ising fixed point using a Bell–Wilson RGT. We are able to identify optimal RGTs which allow accurate computations of quantities such as critical exponents, fixed-point couplings and eigenvectors with modest statistics. We finally discuss the advantages and limitations of this type of approach. 相似文献
155.
Technical details are given on how to use Fourier acceleration with iterative processes such as relaxation and conjugate gradient methods. These methods are often used to solve large linear systems of equations, but become hopelessly slow very rapidly as the size of the set of equations to be solved increases. Fourier acceleration is a method designed to alleviate these problems and result in a very fast algorithm. The method is explained for the Jacobi relaxation and conjugate gradient methods and is applied to two models: the random resistor network and the random central-force network. In the first model, acceleration works very well; in the second, little is gained. We discuss reasons for this. We also include a discussion of stopping criteria. 相似文献
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Let Ω be a simply connected domain in the complex plane, and , the space of functions which are defined and analytic on , if K is the operator on elements defined in terms of the kernels ki(t, s, a1, …, an) in by is the identity operator on , then the operator I ? K may be factored in the form (I ? K)(M ? W) = (I ? ΠK)(M ? ΠW). Here, W is an operator on defined in terms of a kernel w(t, s, a1, …, an) in by Wu = ∝antw(t, s, a1, …, an) u(s, a1, …, an) ds. ΠW is the operator; ΠWu = ∝an ? 1w(t, s, a1, …, an) u(s, a1, …, an) ds. ΠK is the operator; ΠKu = ∑i = 1n ? 1 ∝aitki(t, s, a1, …, an) ds + ∝an ? 1tkn(t, s, a1, …, an) u(s, a1, …, an) ds. The operator M is of the form m(t, a1, …, an)I, where and maps elements of into itself by multiplication. The function m is uniquely derived from K in the following manner. The operator K defines an operator on functions u in , by . A determinant of the operator is defined as an element of . This is mapped into by setting an + 1 = t to give m(t, a1, …, an). The operator I ? ΠK may be factored in similar fashion, giving rise to a chain factorization of I ? K. In some cases all the matrix kernels ki defining K are separable in the sense that ki(t, s, a1, …, an) = Pi(t, a1, …, an) Qi(s, a1, …, an), where Pi is a 1 × pi matrix and Qi is a pi × 1 matrix, each with elements in , explicit formulas are given for the kernels of the factors W. The various results are stated in a form allowing immediate extension to the vector-matrix case. 相似文献
159.
A study has been made to determine the scope of the cyclocarbonylation reaction of olefinic tosylates with Na2Fe(CO)4. 相似文献
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We propose to quantify the correlation inherent in a many-electron (or many-fermion) wave function psi by comparing it to the unique uncorrelated state that has the same 1-particle density operator as does /|psi>相似文献