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61.
62.
Analytical and Bioanalytical Chemistry - 相似文献
63.
R. A. Sawyer H. B. Vincent H. V. Knorr V. M. Albers G. N. Thomis W. V. Thorpe R. T. Williams und L. Kulberg 《Fresenius' Journal of Analytical Chemistry》1940,120(1-2):21-22
Ohne Zusammenfassung 相似文献
64.
The reactions of dipotassium germacyclopentadienediide with two Group 13 dichlorides, Cp*BCl2 and Cp*AlCl2, yield two structurally different products. In the case of boron a borole complex of germanium(ii) is obtained. The aluminium halide gives an unprecedented neutral germaaluminocene. Both compounds were fully characterised by multinuclear NMR spectroscopy supported by DFT computations. The molecular structure of the germaaluminocene was determined by XRD.Boron vs. aluminum: the synthesis of a borole complex of Ge(ii) is reported. Changing just the element from boron to aluminum unexpectedly yields an unprecedented neutral germaaluminocene. 相似文献
65.
Saracino MA Gandolfi O Dall'olio R Albers L Kenndler E Raggi MA 《Journal of chromatography. A》2006,1122(1-2):21-27
A sensitive and selective method was developed for the determination of the antipsychotic drug Olanzapine levels in rat brain tissue, based on HPLC with electrochemical detection. The analyses were carried out on a C8 reversed phase column (150 mm x 4.6 mm, 5 microm), using a mobile phase composed of methanol and a phosphate buffer (44.0 mM, pH 3.5), containing triethylamine (21:79, v/v), flowing at 1.2 mL min(-1). A high sensitivity coulometric detection analytical cell containing two flow-through low volume working electrodes was used: electrode 1 was set at +0.350 V and electrode 2 at -0.200 V. Olanzapine, administered to rats in different doses or in different times, was extracted from tissue homogenate of either the whole brain or specific areas (cortex, hyppocampus, nucleus striatum) with a rapid solid phase extraction procedure (SPE) on Oasis HLB cartridges. The method provided a high extraction yield of Olanzapine and internal standard (2-methylolanzapine) from brain tissue homogenate with absolute recovery values higher than 90.0%. The detector response was linear over a concentration range of 0.2-100.0 ng mL(-1) of Olanzapine. The limit of quantification (LOQ) was 0.2 ng mL(-1). Precision results, expressed by the intra-day and the inter-day relative standard deviation values, were satisfactory, better than 4.6%. Accuracy was satisfactory as well. This method proved to be suitable for the analysis of Olanzapine in rat brain tissues and for the study of distribution and pharmacokinetics of Olanzapine in rat brain after a single treatment with the antipsychotic drug. 相似文献
66.
67.
Michel O. Albers Hester E. Oosthuizen David J. Robinson Alan Shaver Eric Singleton 《Journal of organometallic chemistry》1985,282(3):c49-c52
Facile substitution of the cyclooctadiene and/or chloro ligands in [(η5-C5H5)Ru(C8H12Cl] (C8H12 = cycloocta-1,5-diene) under mild reaction conditions provides high yield synthetic routes to a range of new neutral and cationic cyclopentadienylruthenium(II) complexes. 相似文献
68.
Michel O. Albers Neil J. Coville Eric Singleton 《Journal of organometallic chemistry》1982,232(3):261-266
The reaction between Fe(CO)5, and group V donor ligands L, (L PPh3, AsPh3, SbPh3, PMePh2, PMe2Ph, Asme2Ph, P(C6H11)3, P(n-Bu)3, P(i-Bu)3, P(OPh)3, P(OEt)3, P(OMe)3) in the presence of [(η5-C5Me5Fe(CO)2]2 (R H, Me) or [(η5-C5Me5)Fe(CO)2]2 as catalyst in refluxing toluene, rapidly gives the complexes Fe(CO)4L in yields > 85%. The reaction rate is essentially independent of the nature of L for [(η5-C5Me5)Fe(CO)2]2 as catalyst. For the other catalysts, the rate is influenced predominantly by the steric properties of L. These results are interpreted in terms of the interaction between the catalyst and the ligand L to give derivatives of the type (η5-C5H4R)2Fe2,(CO)3,(L). These derivatives were also found to catalyse the reaction between Fe(CO)5, and L. The complexes [(η-C5H4R)Fe(CO)2]2 (R H, Me) and [(η5-C5Me5)Fe(CO)2]2 also catalyse the reaction between Mn2(CO)10 and PPh3 to give Mn2(CO)8- PPh3)2 in > 80% yield. 相似文献
69.
Leontine A. De Graaf Pieter-Jan W. Albers Martin Mller 《Journal of Polymer Science.Polymer Physics》1996,34(11):1839-1852
The adhesion behavior of semi-interpenetrating polymer networks (semi-IPNs) of linear polystyrene (PS) in crosslinked poly-2-ethylhexylmethacrylate (EHMA) was studied by variation of the bulk and surface morphology, i.e., domain size, continuity, and concentration in the domains. Semi-IPNs were prepared by liquid-liquid demixing upon cooling of a homogeneous solution of PS in methacrylate monomer, followed by gelation of the PS-rich phase and UV polymerization of the methacrylate resin. Welding of films allowed the preparation of larger objects provided that (1) the samples were phase separated to a high degree and contained domains with a high PS concentration (>90%) and (2) polystyrene was present at the interface. For semi-IPN films, a linear dependence of the adhesion strength on the (crack healing time)1/4 was obtained. Based on these considerations, a process was developed to obtain melt-processable semi-IPN particles, by quenching droplets of the polymer solution into a cold liquid. These particles obtained a PS-rich skin layer and showed good adhesion after blending with a thermoplast. © 1996 John Wiley & Sons, Inc. 相似文献
70.
Hans Albers 《Nachrichten aus der Chemie》1987,35(10):1025-1025