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91.
M. W. Rahman M. J. Alam M. M. Hossain N. C. Dafader M. E. Haque 《International Journal of Polymer Analysis and Characterization》2014,19(1):39-47
The role of divalent metals in the degradation of the physico-mechanical properties of radiation-vulcanized natural rubber latex (RVNRL) films was investigated. RVNRL films were prepared by the addition of metals (Cu, Mg, etc.) of different concentrations (0–30ppm) to natural rubber latex and irradiated with various radiation doses (0–20kGy). The radiation doses were optimized (12kGy), and the adverse effect of metal ions was studied against a reference film prepared with no metal ions. Tensile strength, tear strength, and cross-linking density of the irradiated rubber films decreased with increasing metal ion concentrations and decreasing radiation doses. The mechanical properties of the films were reduced by 10–15% for 30ppm metal ions and at the optimum dose. In contrast, elongation at break, permanent set, and swelling ratio of the films increased at the same conditions. The relative effect of metal ions can be explained by the classical electron concept, reported in this article. 相似文献
92.
Md. Aminul Haque Md. Rajibul Akanda Delwar Hossain M. Aminul Haque Ismail A. Buliyaminu Shaik Inayath Basha Munetaka Oyama Md. Abdul Aziz 《Electroanalysis》2020,32(3):528-535
In this study, the electrocatalytic characteristics of nitrogen‐doped carbon (NDC) prepared from Clerodendrum Infortunatum L leaves on a glassy carbon electrode (GCE) surface was evaluated with regards to its ability to detect the electroactive drug ketoconazole (KCZ). The NDC was prepared by carrying out a simple pyrolysis of dry powder of the leaves at 850 °C. The prepared NDC was characterized using field‐emission scanning electron microscopy, energy dispersive spectroscopy, transmission electron microscopy, X‐ray photoelectron spectroscopy and Brunauer‐Emmett‐Teller analysis, and was then used as an electrode material. The performance of the electrochemical KCZ sensor with the NDC‐modified glassy carbon electrode (NDC/GCE) was found to be optimal when using PBS buffer at pH 3 and a concentration of 0.1 mg/ml of NDC in the conjugate with Nafion polymer. Under these conditions, the NDC/GCE displayed a KCZ detection limit of 3 μM and a linear dependence of its response on KCZ concentration over a wide range of KCZ concentrations from 47 μM to 752 μM (R2=0.9742). These results confirmed the potential of NDC as an electrocatalyst. 相似文献
93.
Afif Ahmed Radenahmad Nikdalila Rahman Seikh Mohammad Habibur Torino Nico Saqib Muhammad Hossain Shahzad Park Jun-Young Azad Abul Kalam 《Journal of Solid State Electrochemistry》2022,26(1):111-120
Journal of Solid State Electrochemistry - Protonic ceramic fuel cells have become extremely interesting due to their high power output at the intermediate temperature range... 相似文献
94.
Structural Chemistry - The N-methyl-D-aspartate (NMDA) is the family of glutamate receptor, which is involved in controlling synaptic plasticity and memory function; but overactivation of this... 相似文献
95.
Anjan K. Saha M. Mahmun Hossain Desiree S. Grubisha Dennis W. Bennett 《Journal of chemical crystallography》1995,25(7):383-387
Benzophenone azine crystallizes in the monoclinic space groupA2/a (No. 15) witha=16.303(3) Å,b=5.4864(2) Å,c=21.973(5) Å, =85.52(2)°,V=1959.4(8) Å3, andD
calc=1.22 g cm–3 forZ=4. The structure was solved by direct methods and refined againstF to a finalR value of 0.047. The unit cell contains four molecules of the title compound; the asymmetric unit consists of half a molecule. Despite the high crystallographic symmetry, the two halves of the molecule arenot related by a center of symmetry; instead, the molecule adopts C2 symmetry; the molecular C2 axis is coincident with the crystallographic twofold axis. The formation of benzophenone azine from the reaction of the iron-containing Lewis acid complex [(5-C5H5)Fe(CO)2(THF)]+ [BF4]– and diphenyldiazomethane provides strong evidence for an Fe(II) carbene intermediate. 相似文献
96.
Jakia Akter G.M. Golzar Hossain Shariff E. Kabir K.M. Abdul Malik 《Journal of chemical crystallography》2000,30(12):773-776
Decacarbonyl--hydrido--1,8-2-quinoline-triosmium crystallizes in the triclinic space group P
with a = 7.8551(6), b = 9.1283(8), c = 16.7915(8) Å, = 74.788(2), = 88.086(2), = 66.392(3)°, V = 1062.22(13)° Å3, T = 150 K, and Z = 2. The molecule consists of an Os3 triangle with the hydride and the heterocyclic ligand bridging the same Os—Os edge. The heterocyclic ligand is coordinated through the C(8) carbon and nitrogen atoms in a new -1,8-2-bonding mode. The Os—Os distances lie in the close range 2.8837(4)–2.9034(4) Å with an average value of 2.892(7) Å. 相似文献
97.
Abraham F. Jalbout Xin-Hua Li Mohammad R. Hassan G. M. Golzar Hossain 《Transition Metal Chemistry》2008,33(5):597-603
Three different types of metal-organic polymers have been prepared by a solution diffusion process carried out at room temperature.
Crystals of the copper coordination polymers [CuX(4,4′-bipy)]
n
(X = Cl, Br, I) have been obtained by the reaction of 4,4′-bipyridine ligands with Cu2X2 fragments to yield a three-dimensional network consisting of four interlocking planar lattices. Single crystals of [Cu2(1,2,4,5-BTC)(DMF)2]
n
(1,2,4,5-BTC = 1,2,4,5-benzene tetracarboxylate) have been grown by slow diffusion from solutions of a mixture of CuBr2, 2,2′-dithiosalicylic acid, and sodium azide plus a mixture of 1,2,4,5-H4BTC and 4-cyanopyridine. The complex [Co(1,3,5-BTC)(4,4′-bipy)]
n
(1,3,5-BTC = 1,3,5-benzene tricarboxylate) has a 3D open framework structure involving terminal cobalt atoms plus bridging
1,3,5-BTC and 4,4′-bipyridine ligands. 相似文献
98.
First Synthesis of Continuous Mesoporous Copper Films with Uniformly Sized Pores by Electrochemical Soft Templating
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Dr. Cuiling Li Bo Jiang Dr. Zhongli Wang Yunqi Li Dr. Md. Shahriar A. Hossain Prof. Dr. Jung Ho Kim Dr. Toshiaki Takei Dr. Joel Henzie Prof. Dr. Ömer Dag Prof. Dr. Yoshio Bando Prof. Dr. Yusuke Yamauchi 《Angewandte Chemie (International ed. in English)》2016,55(41):12746-12750
Although mesoporous metals have been synthesized by electrochemical methods, the possible compositions have been limited to noble metals (e.g., palladium, platinum, gold) and their alloys. Herein we describe the first fabrication of continuously mesoporous Cu films using polymeric micelles as soft templates to control the growth of Cu under sophisticated electrochemical conditions. Uniformly sized mesopores are evenly distributed over the entire film, and the pore walls are composed of highly crystalized Cu. 相似文献
99.
To explore the role of competing forward and reversed chain reactions in the growth of a one-dimensional (1D) molecular line on the Si(100)-(2 x 1)-H surface, controlled experiments were performed with various alkene molecules by scanning tunneling microscopy (STM) at various temperatures. It was observed that the end dangling bond (DB) of a styrene line, fabricated by a chain reaction on the Si(100)-(2 x 1)-H surface at 300 K, initiated a reverse chain reaction at 400 K, leading to the complete disappearance of the styrene line with zero-order desorption kinetics (rate constant k = 1.17 x 10-2 s-1 at 400 K). In the case of 2,4-dimethylstyrene, the reversed chain reaction was observed even at 300 K. These results suggest that the appearance of a molecular line in an STM image is determined by the rates of competing forward and reversed chain reactions at a given temperature. As predicted, 1D lines formed by the DB-initiated chain reaction of 1-hexene and 1-heptene on Si(100)-(2 x 1)-H were observed at 180 K because of the reduced desorption rate, despite the fact that those molecules showed no line growth at 300 K. These results indicate that the scope of forming 1D molecular lines on the Si(100)-(2 x 1)-H surface with various alkenes is much wider than anticipated in previous studies. 相似文献
100.
Ghosh S Roehm B Begum RA Kut J Hossain MA Day VW Bowman-James K 《Inorganic chemistry》2007,46(23):9519-9521
The crystal structures of two metallo oxides, perrhenate and dichromate, are reported with a diprotonated tetraamido/diamino-based macrocycle, L, in which the floppy ligand assumes a folded conformation. When the four amides are deprotonated, this same ligand binds transition-metal ions in its tetraanionic form, H-4L. For the divalent metal ions Cu2+ and Ni2+, H-4L again folds and dinuclear complexes are formed. With trivalent metal ions Co3+ and Fe3+, the ligand wraps about the metal ions, resulting in mononuclear complexes. 相似文献