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51.
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The ethyl esters of pyridine carboxylic acids were obtained by reaction of the ethoxycarbonyl radical with methyl-substituted pyridines. A mechanism is proposed for the carboxylation reaction.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 224–225, February, 1976. 相似文献
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M. G. Vinogradova R. S. Min V. S. Aksenov G. I. Nikishin 《Russian Chemical Bulletin》1982,31(9):1760-1765
Conclusions Kinetic data indicate that the principal path followed in the oxidative addition of acetone to aromatic compounds (ArH) under the action of Mn(III) acetate in AcOH solution to be the formation of a [CH2=C(CH3)-OMnIII·ArH] complex, which breaks down with rupture of the MnIII-O bond and subsequent addition of the acetonyl radical to the coordinated ArH (limiting step); this is, in turn, followed by rapid one-electron oxidation of the intermediate adduct radical by the Mn(III) ion, and formation of the final product.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1994–1999, September, 1982. 相似文献
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Yu. N. Khaydukov B. Nagy J. -H. Kim T. Keller A. Rühm Yu. V. Nikitenko K. N. Zhernenkov J. Stahn L. F. Kiss A. Csik L. Bottyán V. L. Aksenov 《JETP Letters》2013,98(2):107-110
Here we report on a feasibility study aiming to explore the potential of Polarized Neutron Reflectometry (PNR) for detecting the inverse proximity effect in a single superconducting/ferromagnetic bilayer. Experiments, conducted on the V (40 nm)/Fe (1 nm) S/F bilayer, have shown that experimental spin asymmetry measured at T = 0.5T C is shifted towards higher Q values compared to the curve measured at T = 1.5T C . Such a shift can be described by the appearance in superconducting vanadium of magnetic sublayer with a thickness of 7 nm and a magnetization of +0.8 kG. 相似文献
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V. V. Kriventsov E. P. Yakimchuk B. N. Novgorodov D. I. Kochubey I. L. Simakova D. A. Zyuzin D. G. Aksenov A. V. Chistyakov A. S. Fedotov K. V. Golubev V. Yu. Murzin M. V. Tsodikov 《Bulletin of the Russian Academy of Sciences: Physics》2013,77(9):1190-1194
Model low-percentage metal oxide palladium catalysts are prepared from acetate complexes of Pd and Mn to study the nature of the activity and the genesis of nanostructured membrane catalyst Pd-Mn systems. A comprehensive study of the prepared model precursor compounds; specific features of their metal components in gels and oxides; and the genesis of the active component, local structure, and charge state is performed by EXAFS and XANES. Possible versions of structural models for the stabilization of metals on oxide supports aare discussed. 相似文献
59.
Buryi D. S. Dotsenko V. V. Levashov A. S. Lukina D. Yu. Strelkov V. D. Aksenov N. A. Aksenova I. V. Netreba E. E. 《Russian Journal of General Chemistry》2019,89(5):886-895
Russian Journal of General Chemistry - The reaction of acetylenic ketones with cyanothioacetamide in the presence of morpholine yields 4,6-disubstituted... 相似文献
60.
Buryi D. S. Dotsenko V. V. Aksenov N. A. Aksenova I. V. Krivokolysko S. G. Dyadyuchenko L. V. 《Russian Journal of General Chemistry》2019,89(8):1575-1585
The reaction of 3-pentylpentane-2,4-dione with cyanothioacetamide afforded 4,6-dimethyl-5-pentyl-2-thioxo-1,2-dihydropyridine-3-carbonitrile. Alkylation of the latter led to the formation of 2-alkylsulfanyl-4,6-dimethyl-5-pentylpyridine-3-carbonitriles or 3-amino-4,6-dimethyl-5-pentylthieno[2,3-b]pyridines, depending on the alkylating agent and reaction conditions. The structures of the key compounds were proved by 2D NMR spectroscopy and X-ray analysis. Biological activity of the synthesized compounds was evaluated in silico. Some compounds were experimentally found to stimulate growth of sunflower seedlings.
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