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201.
Novel enzymatically recyclable poly(carbonate-urethane) consisting of a diurethane moiety as a hard segment and a carbonate linkage as an enzymatically cleavable unit was prepared by the polycondensation of biodegradable diurethanediol and diethyl carbonate using lipase. The produced poly(carbonate-urethane) was readily transformed by lipase into the corresponding cyclic oligomers which were more easily repolymerized by lipase to produce a higher molecular weight poly(carbonate-urethane) than that of the parent poly(carbonate-urethane). 相似文献
202.
Glycosides of Atractylodes ovata 总被引:3,自引:0,他引:3
Kitajima J Kamoshita A Ishikawa T Takano A Fukuda T Isoda S Ida Y 《Chemical & pharmaceutical bulletin》2003,51(9):1106-1108
A new coumarin glycoside and a new glycoside of an acetylene derivative were isolated from the water-soluble portion of the methanolic extract of Atractylodes ovata rhizome together with eight known compounds. Their structures were characterized as scopoletin beta-D-xylopyranosyl-(1-->6)-beta-D-glucopyranoside and (2E)-2-decene-4,6-diyne-1,8-diol 8-O-beta-D-apiofuranosyl-(1-->6)-beta-D-glucopyranoside, respectively, based on chemical and spectroscopic investigations. A comparison of the polar constituents among Atractylodes japonica, Atractylodes lancea, and A. ovata is led to the conclusion that A. ovata is distinguishable from A. lancea and A. japonica, as also shown by phylogenetic analysis. 相似文献
203.
Yoshikatsu Nagasawa Hideyuki Ishida Fusami Soeda Akira Ishitani Ichiro Yoshii Kazuhiko Yamamoto 《Mikrochimica acta》1988,94(1-6):431-434
FT-IR-ATR (Fourier transform infrared attenuated total reflectance) technique was used to measure the SiOH and SiH contents in the thermal oxide films grown on Si wafers. It was found that the SiOH groups in the bulk could be eliminated by low temperature annealing, whereas SiOH at the Si/SiO2 interface could only be removed by high temperature annealing. It was also found that gamma ray irradiation generated SiOH and SiH in the thin oxide film. 相似文献
204.
We investigate the minimum entanglement cost of the deterministic implementation of two-qubit controlled-unitary operations using local operations and classical communication (LOCC). We show that any such operation can be implemented by a three-turn LOCC protocol, which requires at least 1 ebit of entanglement when the resource is given by a bipartite entangled state with Schmidt number 2. Our result implies that there is a gap between the minimum entanglement cost and the entangling power of controlled-unitary operations. This gap arises due to the requirement of implementing the operations while oblivious to the identity of the inputs. 相似文献
205.
Akihito Yashiro Keita Onodera Chunlei Li Yukiko Suzuki Hiroshi Katagiri 《Supramolecular chemistry》2013,25(1):48-53
A phloroacetophenon[4]arene (3) consisting of four isomers was synthesised for the first time via the condensation of phloroacetophenone and benzaldehyde in a one-pot reaction with refluxing toluene in the presence of catalytic amounts of TsOH·H2O for a maximum yield of 64%. The conformational elucidation of four isomers (3a–d) by 1H NMR spectroscopy and X-ray crystal structure analysis showed them to be cone, partial cone, 1,3-alternate and 1,2-alternate types of conformations, respectively. 相似文献
206.
We have succeeded in forming highly ordered chevron-shaped arrays of continuous copper nano-dot lines by electroless deposition on hydrogen-terminated Si(111) (H-Si(111)) surfaces. Detailed investigations have shown that tiny Cu clusters are preferentially formed at step edges when the electroless deposition is carried out in a deoxygenated neutral aqueous solution of a low Cu2+ concentration (less than 10 microM) with pH approximately = 7. This finding was combined with highly ordered step-edge lines on H-Si(111) prepared by the previously reported method of Teflon scratching and NH4F etching, which has led to the above success. The present result indicates that designed ordered metal nanowires can be produced by the electroless deposition method, using H-Si(111) surfaces with well-regulated step lines as a substrate. 相似文献
207.
Naoto Tsutsumi Akihito Dohi Asato Nonomura Wataru Sakai 《Journal of Polymer Science.Polymer Physics》2011,49(6):414-420
We present the enhanced photorefractive performance of high molecular weight poly(N‐vinyl carbazole) (PVCz)‐based composites. Higher diffraction efficiency with faster speed of grating build‐up was obtained by optimizing the composition of the PVCz composites. At relatively low applied electric field of E = 45 V μm?1, diffraction efficiency of 26% for p‐polarized probe beam and corresponding that of 5.1% for s‐polarized probe beam were measured with faster grating build‐up speed of 48.3 s?1 for the composite with 2,4,7‐trinitrofluorenone (TNF) as a sensitizer. Fastest speed of grating build‐up of 100 s?1 and large optical gain up to 110 cm?1 were measured at E = 80 V μm?1 for the composite with fullerene derivative of PCBM as a sensitizer. These improved performances are due to a large orientational enhancement effect with faster response speed in addition to Pockels effect for the samples with appropriate glass transition temperature. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
208.
Mitsuji Yamashita Akihito Iida Hiroyuki Mizuno Yasushi Miyamoto Toru Morishita Naoaki Sata Kenji Kiguchi Akihiro Yabui Tatsuo Oshikawa 《Heteroatom Chemistry》1993,4(6):553-557
Reactions of 1-phenyl- and 1-methoxy-2-phospholene 1-oxides with bromine in aqueous organic solvents or in a protic medium, such as methanol, easily afforded the corresponding 2-bromo-3-hydroxy- or 2-bromo-3-methoxyphospholane 1-oxide derivatives. The reaction mechanism was postulated based on the stereochemistry of the products. 相似文献
209.
Akihito Hashidzume Atsushi Kajiwara Akira Harada Mikiharu Kamachi 《Macromolecular rapid communications》1996,17(8):529-537
The polymerizability of an azastyrene derivative, 2,6-diisopropyl-N-methyleneaniline (DiPMAn), was studied. Although DiPMAn could not be polymerized by radical and anionic initiators, it was polymerized with cationic initiators, such as trifluoroacetic acid (TFA), TiCl4-TFA, and SnCl4-TFA. The polymer is formed by 1,6-addition with electrophilic substitution of an activated monomer in para-position of the aromatic ring. 相似文献