全文获取类型
收费全文 | 367篇 |
免费 | 8篇 |
国内免费 | 1篇 |
专业分类
化学 | 214篇 |
晶体学 | 5篇 |
力学 | 7篇 |
数学 | 37篇 |
物理学 | 113篇 |
出版年
2023年 | 11篇 |
2022年 | 11篇 |
2021年 | 10篇 |
2020年 | 15篇 |
2019年 | 14篇 |
2018年 | 9篇 |
2017年 | 6篇 |
2016年 | 12篇 |
2015年 | 6篇 |
2014年 | 13篇 |
2013年 | 28篇 |
2012年 | 23篇 |
2011年 | 21篇 |
2010年 | 15篇 |
2009年 | 5篇 |
2008年 | 14篇 |
2007年 | 15篇 |
2006年 | 13篇 |
2005年 | 12篇 |
2004年 | 6篇 |
2003年 | 5篇 |
2002年 | 4篇 |
2000年 | 4篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 5篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 7篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 4篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1977年 | 5篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1970年 | 2篇 |
1969年 | 3篇 |
1968年 | 2篇 |
1965年 | 2篇 |
1959年 | 2篇 |
排序方式: 共有376条查询结果,搜索用时 11 毫秒
51.
Thermochemistry of gas-phase ion-water clusters together with estimates of the hydration free energy of the clusters and the water ligands are used to calculate the hydration free energy of the ion. Often the hydration calculations use a continuum model of the solvent. The primitive quasichemical approximation to the quasichemical theory provides a transparent framework to anchor such efforts. Here we evaluate the approximations inherent in the primitive quasichemical approach and elucidate the different roles of the bulk medium. We find that the bulk medium can stabilize configurations of the cluster that are usually not observed in the gas phase, while also simultaneously lowering the excess chemical potential of the ion. This effect is more pronounced for soft ions. Since the coordination number that minimizes the excess chemical potential of the ion is identified as the optimal or most probable coordination number, for such soft ions the optimum cluster size and the hydration thermodynamics obtained with and without account of the bulk medium on the ion-water clustering reaction can be different. The ideas presented in this work are expected to be relevant to experimental studies that translate thermochemistry of ion-water clusters to the thermodynamics of the hydrated ion and to evolving theoretical approaches that combine high-level calculations on clusters with coarse-grained models of the medium. 相似文献
52.
Gautam Pankaj Sahu Daya Ram Dixit Avinash Som Tanmoy 《Journal of Optimization Theory and Applications》2021,190(2):491-523
Journal of Optimization Theory and Applications - In this paper, the first-order forward–backward–half forward dynamical systems associated with the inclusion problem consisting of... 相似文献
53.
V. K. Dixit K. S. Keerthi H. L. Bhat Parthasarathi Bera M. S. Hegde 《Applied Surface Science》2003,220(1-4):321-326
The growth of epitaxial InBixAsySb(1−x−y) layers on highly lattice mis-matched semi-insulating GaAs substrates has been successfully achieved via the traditional liquid phase epitaxy. Orientation and single crystalline nature of the film have been confirmed by X-ray diffraction. Scanning electron micrograph shows abrupt interface at micrometer resolution. Surface composition of Bi(x) and As(y) in the InBixAsySb(1−x−y) film was measured using energy dispersive X-ray analysis and found to be 2.5 and 10.5 at.%, respectively, and was further confirmed with X-ray photoelectron spectroscopy. Variation of the composition with depth of the film was studied by removing the layers with low current (20 μA) Ar+ etching. It was observed that with successive Ar+ etching, In/Sb ratio remained the same, while the As/Sb and Bi/Sb ratios changed slightly with etching time. However after about 5 min etching the As/Sb and Bi/Sb ratios reached constant values. The room temperature band gap of InBi0.025As0.105Sb0.870 was found to be in the range of 0.113–0.120 eV. The measured values of mobility and carrier density at room temperature are 3.1×104 cm2 V−1 s−1 and 8.07×1016 cm−3, respectively. 相似文献
54.
JPC – Journal of Planar Chromatography – Modern TLC - A thin-layer chromatographic method with densitometric UV detection at λ = 232 nm has been developed for standardization of... 相似文献
55.
56.
M. D. Agrawal C. S. Bhandari M. K. Dixit N. C. Sogani 《Monatshefte für Chemie / Chemical Monthly》1976,107(1):75-82
Stability constants of praseodymium chelates of 3,4,5-trihydroxy sodium benzoate are determined by using Bjerrum-Calvin pH titration technique at constant ionic strength 0.1M-sodium perchlorate and at 28±0.1°C. Values calculated by different methods are in good agreement. The study reveals that during complexation only one proton of the ligand molecule is replaced by the metal and oxygen of adjacent phenolic group acts as a coordinating atom. IR and NMR spectral studies of the ligand reveal that one of the OH groups (in meta position to carboxylic group) remains free while two other phenolic groups are involved in intramolecular hydrogen bonding. One water molecule is found attached in crystalline gallic acid.
Mit 2 Abbildungen 相似文献
Mit 2 Abbildungen 相似文献
57.
58.
G. R. Mason G. A. Beer M. S. Dixit S. K. Kim J. A. MacDonald A. Olin R. M. Pearce 《Nuclear Physics A》1980,340(2):240-248
Energies and lorentzian widths of pionic K X-ray transitions have been measured in liquid 3He with improved accuracy. The strong interaction on the π3He 1s level is found to be attractive and to produce an increase in the K transition energies of 34 ± 4 eV; the measured lorentzian width is 36 ±7 eV. Measured values are also presented for K X-ray energies in liquid π4He and μ4He, the lorentzian width of the 1s level in π4He, and relative intensities of K X-ray transitions in π3He, π4He and μ4He. The measurements are compared with those of others and with recent theoretical calculations. 相似文献
59.
60.
The spectra of P16O and P18O were excited in sealed discharge tubes containing neon (2–3 mm. pressure), oxygen gas enriched to 65 per cent. of18O and trace amounts of phosphorus vapour and photographed on a 3 m. grating spectrograph at a dispersion of 2·5 Å/mm. Isotope shift studies in theβ-bands confirmed the earlier vibrational scheme of Curryet al. and showed conclusively that the red as well as the violet degraded bands belonged to the sameβ-system. The present studies of isotope shifts also confirmed the vibrational assignments of the extensive ultraviolet bands involving the2 Σ ??X2 Π transition and theγ-bands (A2 Σ +?X2 Π). In the case of the visible bands, they provided evidence for the first time that the bands at 5585 Å, 5962 Å and 6385 Å belonged to one system and involved 0–0, 0–1 and 0–2 transitions respectively. 相似文献