排序方式: 共有53条查询结果,搜索用时 15 毫秒
41.
A. Chrissanthopoulos N.P. Tzanetos A.K. Andreopoulou J. Kallitsis E. Dalas 《Journal of Crystal Growth》2005,280(3-4):594-601
The nucleation and further crystallization of calcite on oxadiazole-terpyridine copolymer were investigated by the constant composition method. The apparent order of the crystallization process was found to be 2.3±0.2 indicative of a surface diffusion-controlled spiral growth mechanism. The number of ions forming the critical nucleus was found experimentally to be (n*=) 3 in accordance with the simulation by the PM3 method included in the MOPAC program package. The surface energy of the growing phase was found to be 29.5 mJ m−2. 相似文献
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Sofia Drakopoulou Emmanouil Orfanakis Ioulia Karagiannaki Fragiskos Gaitis Stavroula Skoulika Andreas Papaioannou George Boukouvalas George Petropoulos Vassilios Katsoudas Renate Kontzedaki Aggelos Philippidis Aikaterini Zoumi Marilena Dasenaki Nikolaos S. Thomaidis Michalis Velegrakis 《Molecules (Basel, Switzerland)》2022,27(4)
Extra virgin olive oil (EVOO) is a key component of the Mediterranean diet, with several health benefits derived from its consumption. Moreover, due to its eminent market position, EVOO has been thoroughly studied over the last several years, aiming at its authentication, but also to reveal the chemical profile inherent to its beneficial properties. In the present work, a comparative study was conducted to assess Greek EVOOs’ quality and authentication utilizing different analytical approaches, both targeted and untargeted. 173 monovarietal EVOOs from three emblematic Greek cultivars (Koroneiki, Kolovi and Adramytiani), obtained during the harvesting years of 2018–2020, were analyzed and quantified as per their fatty acids methyl esters (FAMEs) composition via the official method (EEC) No 2568/91, as well as their bioactive content through liquid chromatography coupled to high resolution mass spectrometry (LC-HRMS) methodology. In addition to FAMEs analysis, EVOO samples were also analyzed via HRMS-untargeted metabolomics and optical spectroscopy techniques (visible absorption, fluorescence and Raman). The data retrieved from all applied techniques were analyzed with Machine Learning methods for the authentication of the EVOOs’ variety. The models’ predictive performance was calculated through test samples, while for further evaluation 30 commercially available EVOO samples were also examined in terms of variety. To the best of our knowledge, this is the first study where different techniques from the fields of standard analysis, spectrometry and optical spectroscopy are applied to the same EVOO samples, providing strong insight into EVOOs chemical profile and a comparative evaluation through the different platforms. 相似文献
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Andreas A. Stefopoulos Eleftherios K. Pefkianakis Konstantinos Papagelis Aikaterini K. Andreopoulou Joannis K. Kallitsis 《Journal of polymer science. Part A, Polymer chemistry》2009,47(10):2551-2559
Surface functionalization of CNTs (SWCNTs or MWCNTs) with dendronized alkoxy terpyridine‐Ru(II)‐terpyridine complexes has been accomplished using either the “grafting to” or the “grafting from” approaches. Different sets of easily processable hybrid metallo‐CNTs composites have been efficiently synthesized bearing either monomeric or polymeric side chain tpy‐Ru(II)‐tpy dicomplexes. Their characterization through TGA, UV‐Vis, and Raman techniques revealed various modification degrees depending on the methodology employed. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 2551–2559, 2009 相似文献
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Nikolaos Kritikos Aikaterini Iliou Amalia D. Kalampaliki Evangelos Gikas Ioannis K. Kostakis Benoît Y. Michel Yannis Dotsikas 《Molecules (Basel, Switzerland)》2022,27(6)
Quantitation of chromophore-free analytes is always a challenge. To this purpose, derivatization of the analyte constitutes a common strategy, leading to a product with a strong signal. In the current study, a novel xanthone analogue was utilized for the first time for the derivatization of pregabalin, a model analyte with a primary amine moiety that lacks a chromophore. The fact that only the xanthene-based derivative, formed after the derivatization reaction fluoresces, enables avoiding its chromatographic separation from the reagent and thus reducing the analysis time of a series of samples in 1–2 min via a plate reader. The reaction conditions were optimized via a central composite design (CCD), with fluorescence signal as the measure of the yield. The following factors that affect the derivatization reaction were chosen: (a) temperature, (b) reaction time, and (c) triethylamine solution volume used to drive the reaction to completion. After the identification of the optimal conditions, the method was validated according to ICH guidelines, using a fluorescence plate reader for signal measurement (λex = 540, λem = 615 nm). Finally, the newly developed high-throughput method was applied to the determination of drug content in pregabalin bulk. 相似文献
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Charalampos M. Liapis Aikaterini Karanikola Sotiris Kotsiantis 《Entropy (Basel, Switzerland)》2021,23(12)
In practice, time series forecasting involves the creation of models that generalize data from past values and produce future predictions. Moreover, regarding financial time series forecasting, it can be assumed that the procedure involves phenomena partly shaped by the social environment. Thus, the present work is concerned with the study of the use of sentiment analysis methods in data extracted from social networks and their utilization in multivariate prediction architectures that involve financial data. Through an extensive experimental process, 22 different input setups using such extracted information were tested, over a total of 16 different datasets, under the schemes of 27 different algorithms. The comparisons were structured under two case studies. The first concerns possible improvements in the performance of the forecasts in light of the use of sentiment analysis systems in time series forecasting. The second, having as a framework all the possible versions of the above configuration, concerns the selection of the methods that perform best. The results, as presented by various illustrations, indicate, on the one hand, the conditional improvement of predictability after the use of specific sentiment setups in long-term forecasts and, on the other, a universal predominance of long short-term memory architectures. 相似文献
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Marilena Vlachou Angeliki-Sofia Foscolos Angeliki Siamidi Angeliki Syriopoulou Nikitas Georgiou Aikaterini Dedeloudi Antonis D. Tsiailanis Andreas G. Tzakos Thomas Mavromoustakos Ioannis P. Papanastasiou 《Molecules (Basel, Switzerland)》2022,27(1)
The aqueous dissolution profile of the isomeric synthetic adamantane phenylalkylamine hydrochlorides I and II was probed. These adducts have shown significant antiproliferative/anticancer activity associated with an analgesic profile against neuropathic pain. They are both devoid of toxic effects and show appreciable enzymatic human plasma stability. The structures of these two compounds have been elucidated using 2D NMR experiments, which were used to study their predominant conformations. Compound II’s scaffold appeared more flexible, as shown by the NOE spatial interactions between the alkyl bridge chain, the aromatic rings, and the adamantane nucleus. Conversely, compound I appeared very rigid, as it did not share significant NOEs between the aforementioned structural segments. MD simulations confirmed the NOE results. The aqueous dissolution profile of both molecules fits well with their minimum energy conformers’ features, which stem from the NOE data; this was nicely demonstrated, especially in the case of compound II. 相似文献
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Elefterios K. Pefkianakis Nikolaos P. Tzanetos Christos L. Chochos Aikaterini K. Andreopoulou Joannis K. Kallitsis 《Journal of polymer science. Part A, Polymer chemistry》2009,47(7):1939-1952
Semiconducting oligomers and polymers decorated with two or one dendronized tpy‐Ru(II)‐tpy metallocomplexes are presented. Initially, free terpyridine end‐functionalized semiconducting oligomers (distyrylanthracene, quinquephenylene, mono‐ and trifluorenes) were prepared while in a second approach, atom transfer radical polymerization was employed for the preparation of side‐chain oligomeric and polymeric (oxadiazole)s using a terpyridine initiator. These terpyridine‐bearing oligomers and polymers were complexated with a Percec‐type first‐generation (G1) dendronized terpyridine–Ru(III)Cl3 monocomplex, having two dodecyloxy groups. All oligomeric and polymeric metallocomplexes were characterized via NMR spectroscopies for their structural perfection and via UV‐Vis and PL spectroscopies for their optical properties. The existence of the organic semiconducting blocks in combination with the terpyridine–Ru(II)–terpyridine groups afforded hybrid metallo‐semiconducting species presenting the optical features of both their components. Moreover, their thin‐film morphologies were investigated through atomic force microscopy, revealing, in some cases, an organization tendency in the nanometer scale. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1939–1952, 2009 相似文献
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The continuous development in analytical instrumentation has brought the newly developed Orbitrap‐based gas chromatography / mass spectrometry (GC/MS) instrument into the forefront for the analysis of complex mixtures such as crude oil. Traditional instrumentation usually requires a choice to be made between mass resolving power or an efficient chromatographic separation, which ideally enables the distinction of structural isomers that is not possible by mass spectrometry alone. Now, these features can be combined, thus enabling a deeper understanding of the constituents of volatile samples on a molecular level. Although electron ionization is the most popular ionization method employed in GC/MS analysis, the need for softer ionization methods has led to the utilization of atmospheric pressure ionization sources. The last arrival to this family is the atmospheric pressure photoionization (APPI), which was originally developed for liquid chromatography / mass spectrometry (LC/MS). With a newly developed commercial GC‐APPI interface, it is possible to extend the characterization of unknown compounds. Here, first results about the capabilities of the GC/MS instrument under high or low energy EI or APPI are reported on a volatile gas condensate. The use of different ionization energies helps matching the low abundant molecular ions to the structurally important fragment ions. A broad range of compounds from polar to medium polar were successfully detected and complementary information regarding the analyte was obtained. 相似文献