全文获取类型
收费全文 | 88068篇 |
免费 | 16462篇 |
国内免费 | 9121篇 |
专业分类
化学 | 60730篇 |
晶体学 | 915篇 |
力学 | 5647篇 |
综合类 | 512篇 |
数学 | 10082篇 |
物理学 | 35765篇 |
出版年
2024年 | 230篇 |
2023年 | 1991篇 |
2022年 | 2759篇 |
2021年 | 3175篇 |
2020年 | 3874篇 |
2019年 | 3450篇 |
2018年 | 3088篇 |
2017年 | 2748篇 |
2016年 | 4430篇 |
2015年 | 4133篇 |
2014年 | 5093篇 |
2013年 | 6542篇 |
2012年 | 8038篇 |
2011年 | 8396篇 |
2010年 | 5546篇 |
2009年 | 5379篇 |
2008年 | 5779篇 |
2007年 | 5064篇 |
2006年 | 4761篇 |
2005年 | 3818篇 |
2004年 | 2940篇 |
2003年 | 2294篇 |
2002年 | 2107篇 |
2001年 | 1815篇 |
2000年 | 1604篇 |
1999年 | 1840篇 |
1998年 | 1591篇 |
1997年 | 1576篇 |
1996年 | 1563篇 |
1995年 | 1322篇 |
1994年 | 1150篇 |
1993年 | 996篇 |
1992年 | 858篇 |
1991年 | 783篇 |
1990年 | 643篇 |
1989年 | 501篇 |
1988年 | 370篇 |
1987年 | 308篇 |
1986年 | 323篇 |
1985年 | 261篇 |
1984年 | 151篇 |
1983年 | 117篇 |
1982年 | 100篇 |
1981年 | 57篇 |
1980年 | 42篇 |
1979年 | 10篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1957年 | 31篇 |
1922年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 140 毫秒
851.
852.
853.
草酸锰分解过程的机理函数判别和动力学研究 总被引:6,自引:1,他引:6
用等温热重和线性升温热重分析法研究了草酸锰热分解过程,提出了判断其机理函数的3步判别法。经实验和理论分析证明,该反应受随机成核和晶核随后生长的过程(A_3a机理)支配,其活化能E=103.95 kJ/mol,频率因子A=4.448×10~8min~(-1).动力学补偿效应为IgA=0.09661E-1.2856 相似文献
854.
855.
856.
6-Acetoxy-4-alkenyl arenes undergo regio- and stereoselective intramolecular Friedel-Crafts reaction affording benzocycles in moderate to excellent yields in TFA/HOAc (3:1). It was observed that introduction of alkyls or phenyl group to the allylic acetate moiety facilitates the cyclization reaction. The optically active tricyclic (4bR,8aS)-4b,7,8,8a,9,10-hexahydrophenanthrene skeleton could also be easily obtained in excellent yields. 相似文献
857.
858.
Effects of sugar inhibition on cellulases and β-glucosidase during enzymatic hydrolysis of softwood substrates 总被引:1,自引:0,他引:1
Zhizhuang Xiao Xiao Zhang David J. Gregg John N. Saddler 《Applied biochemistry and biotechnology》2004,115(1-3):1115-1126
A quantitative approach was taken to determine the inhibition effects of glucose and other sugar monomers during cellulase
and β-Glucosidase hydrolysis of two types of cellulosic material: Avicel and acetic acid-pretreated softwood. The increased
glucose content in the hydrolysate resulted in a dramatic increase in the degrees of inhibition on both β-Glucosidase and
cellulase activities. Supplementation of mannose, xylose, and galactose during cellobiose hydrolysis did not show any inhibitory
effects on β-Glucosidase activity. However, these sugars were shown to have significant inhibitory effects on cellulase activity
during cellulose hydrolysis. Our study suggests that high-substrate consistency hydrolysis with supplementation of hemicellulose
is likely to be a practical solution to minimizing end-product inhibition effects while producing hydrolysate with high glucose
concentration. 相似文献
859.
860.
Zhen-Qian Zhang Hong Li Juan Xu Su Yao Zheng-He Xu Jin-Gang Liu Liang-Nian Ji 《Transition Metal Chemistry》2007,32(6):776-780
The effects of copper ion on the interaction of [Ru(bpy)2HPIP]2+(bpy = 2,2′-bipyridine, HPIP = 2-(2-hydroxyphenyl) imidazo [4,5-f] [1, 10] phenanthroline) with DNA have been investigated
by electronic absorption spectroscopy and fluorescence spectroscopy. HPIP ligand of the complex with an intramolecular hydrogen
bond can bind Cu2+ in the absence of DNA, as revealed by the absorbance and fluorescence decrease for [Ru(bpy)2HPIP]2+. The resultant heterometallic complex binds to DNA via intercalation of HPIP into the DNA base pairs and its DNA-binding ability is stronger than [Ru(bpy)2HPIP]2+ itself. The DNA bound [Ru(bpy)2HPIP]2+ cannot bind Cu2+ at low Cu2+ concentration and the intramolecular hydrogen bond in HPIP is located inside the DNA helix. While the Cu2+ concentration is relative high, Cu2+ can quench the fluorescence of DNA bound [Ru(bpy)2HPIP]2+. The quenching reason is proposed. 相似文献