Compton scattering from the deuteron and extracted neutron polarizabilities

Differential cross sections for Compton scattering from the deuteron were measured at MAX-Lab for incident photon energies of 55 and 66 MeV at nominal laboratory angles of 45 degrees, 125 degrees, and 135 degrees. Tagged photons were scattered from liquid deuterium and detected in three NaI spectrometers. By comparing the data with theoretical calculations in the framework of a one-boson-exchange potential model, the sum and the difference of the isospin-averaged nucleon polarizabilities, alpha(N)+beta(N)=17.4+/-3.7 and alpha(N)-beta(N)=6.4+/-2.4 (in units of 10(-4) fm(3)), have been determined. By combining the latter with the global-averaged value for alpha(p)-beta(p) and using the predictions of the Baldin sum rule for the sum of the nucleon polarizabilities, we have obtained values for the neutron electric and magnetic polarizabilities of alpha(n)=8.8+/-2.4(total)+/-3.0(model) and beta(n)=6.5-/+2.4(total)-/+3.0(model), respectively.     

Dualities for the Domany–Kinzel Model

We study the Domany–Kinzel model, which is a class of discrete-time Markov processes in one-dimension with two parameters (p ₁,p ₂)[0,1]². When p ₁= and p ₂=(2– ²) with (,)[0,1]², the process can be identified with the mixed site-bond oriented percolation model on a square lattice with probabilities of a site being open and of a bond being open. This paper treats dualities for the Domany–Kinzel model _t ^A and the DKdual _t ^A starting from A. We prove that , as long as one of A,B is finite and p ₂p ₁.     

Product systems over right-angled Artin semigroups

We build upon Mac Lane's definition of a tensor category to introduce the concept of a product system that takes values in a tensor groupoid . We show that the existing notions of product systems fit into our categorical framework, as do the -graphs of Kumjian and Pask. We then specialize to product systems over right-angled Artin semigroups; these are semigroups that interpolate between free semigroups and free abelian semigroups. For such a semigroup we characterize all product systems which take values in a given tensor groupoid . In particular, we obtain necessary and sufficient conditions under which a collection of -graphs form the coordinate graphs of a -graph.     

Synthesis and studies of a tetradecanuclear manganese(II)/(III) cage

A novel Mn14 cluster is reported; this is a new nuclearity for manganese cages and highly unusual in that the ligands are not exclusively oxygen donors.     

Thiol–ene polymerizations using imide‐based monomers

New diene and dithiol monomers, based on aromatic imides such as benzophenone‐3,3′,4,4′‐tetracarboxylic diimide were synthesized and used in thiol‐ene polymerizations which yield poly(imide‐co‐thioether)s. These linear polymers exhibit limited solubility in various organic solvents. The molecular weights of the polymers were found to decrease with increasing imide content. The glass transition temperature (T_g) of these polymers is dependent on imide content, with T_g values ranging from ?55 °C (with no imide) up to 13 °C (with 70% imide). These thermal property improvements are due to the H‐bonding and rigidity of the aromatic imide moieties. Thermal degradation, as studied by thermogravimetric analysis, was not significantly different to the nonimide containing thiol‐ene polymers made using trimethyloylpropane diallyl ether and 3,5‐dioxa‐1,8‐dithiooctane. It is expected that such monomers may lead to increased glass transition temperatures in other thiol‐ene polymer systems as these normally exhibit low glass transition temperatures. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 4637–4642     

Electrochemical performance of multi-walled carbon nanotube composite electrodes is enhanced with larger diameters and reduced specific surface area

Multi-walled carbon nanotubes (MWCNT) have been widely used to fabricate composite electrodes due to their electrochemical properties. MWCNTs can be fabricated by various approaches and a range of MWCNT types and sizes has been developed. This study focuses on understanding the influence MWCNT diameter and specific surface area has on the electrochemical properties of a composite electrode. MWCNTs with fixed length range and diameters ranging from 10–20 to 50–80 nm were examined in this study. The amount of MWCNT utilised to fabricate the electrodes was identical and above the percolation threshold. MWCNT electrodes fabricated with larger diameters showed enhanced thermodynamic and kinetic properties towards common redox species which covered surface-insensitive, surface-sensitive and adsorption-based processes. Overall, these findings indicate that the number of strands of MWCNT alone is not essential for enhanced conductivity in composite materials but other geometric parameters play important roles.     

Liquid flow patterns about barbotage bubbles

This paper summarizes the results of a flow visualization study on the liquid motion around barbotage bubbles during growth and departure. Flow patterns, as well as for the first time, instantaneous velocities, are reported as a function of time and location about the bubbles. The experiments, employing the hydrogen-bubble technique and high-speed cine photography, were with: water as the liquid, air as the bubbled gas, orifice diameters of 0.116 and 0.252 cm, and different air flow rates; the two limiting cases of constant supply pressure and constant volumetric flow rate were covered. It was found that the liquid around a barbotage bubble assumes two velocity maxima, the first an outward maximum during bubble growth and the second in the opposite direction approximately at the time of bubble departure; further, liquid velocities were found to be higher close to the bubbling site. Certain differences in liquid velocities between the constant pressure and constant flow cases are explained in terms of available theoretical solutions to the bubble growth rate. Qualitative comparisons of the barbotage liquid flow patterns and those recently reported for boiling flow patterns are also presented.