A Procedure to Measure Biaxial Near Yield Residual Stresses Using the Deep Hole Drilling Technique

Deep Hole Drilling (DHD) is a mechanical strain relief technique used to measure residual stresses within engineering components. Such techniques measure strains or displacements when part of the component is machined away and typically assume elastic unloading. However, in components containing high levels of residual stress, elastic–plastic unloading can occur which may introduce substantial error. For the case of the DHD technique, a modification to the technique referred to here as the incremental or iDHD technique has been developed to allow such high levels of residual stress to be measured. Previous work has demonstrated the accuracy of the iDHD technique, although only for axisymmetric residual stress distributions. In the present investigation, the application of the iDHD technique has been extended to the general case of biaxial residual stress fields. Finite element simulations are first carried out to demonstrate the ability of the iDHD technique to measure biaxial residual stress. Experimental measurements were then made on shrink fit components and ring welded components containing biaxial residual stress to investigate the performance of the technique in practice. Good agreements between iDHD measurements, neutron diffraction measurements and FE predictions of the residual stresses were obtained, demonstrating the generally improved accuracy of the iDHD technique compared to the standard DHD approach.     

Absorption-free superluminal light propagation in a quantum-dot molecule

The propagation of a weak probe field in a three-level quantum-dot molecule is investigated by employing the tunnel coupling. It is shown that in the absence of tunnel coupling, the propagation of light pulse is superluminal, similar to a simple two-level system. A high-resolution dip appears in optical spectra due to the presence of tunnel coupling. We show that this narrow dip leads to the subluminal light propagation with doublet absorption, so the group velocity of a light pulse can be controlled by interdot tunnel coupling. It is also demonstrated that by applying an indirect incoherent pumping field to the probe transition, the absorption doublet switches to the gain doublet and then the absorption-free superluminal light propagation is appeared.     

Amberlite XAD-4 functionalized with m-phenylendiamine: Synthesis, characterization and applications as extractant for preconcentration and determination of rhodium (III) in water samples by Inductive Couple Plasma Atomic Emission Spectroscopy (ICP-AES)

A new chelating resin is prepared by coupling Amberlite XAD-4 with metaphenylendiamine through an azo spacer, characterized (elemental analysis, IR and thermogravimetric analysis (TGA)) and studied for preconcentration Rh (III) using Inductive Couple Plasma Atomic Emission Spectroscopy (ICP-AES) for rhodium monitoring. The optimum pH value for sorption of the metal ion was 6.5 (recovery 100%). The sorption capacity was found 0.256 mmol g^− 1 of resin for Rh (III). The method has a detection limit and limit of quantification of 0.05 and 0.08 μg mL^− 1 at pH 6.5, respectively. The chelating resin can be reused for 10 cycles of sorption-desorption without any significant change in sorption capacity. A recovery of 100% was obtained for the metal ion with 1.5 M HCl as eluting agent. The equilibrium adsorption data of Rh (III) on modified resin were analyzed by Langmuir and Freundlich models. Adsorption data were modeled using the pseudo-first-order, pseudo-second-order and intra-particle diffusion kinetics equations. Isotherms have also been used to obtain the thermodynamic parameters such as free energy, enthalpy and entropy of adsorption. The positive value of the enthalpy change (2.48 kJ/mol) indicates that the adsorption is an endothermic process. The method was applied for rhodium ions determination from tap water sample.     

Essentiality and Injectivity

Essentiality is an important notion closely related to injectivity. Depending on a class M\mathcal M of morphisms of a category A{\mathcal A}, three different types of essentiality are considered in literature. Each has its own benefits in regards with the behaviour of M\mathcal M-injectivity. In this paper we intend to study these different notions of essentiality and to investigate their relations to injectivity and among themselves. We will see, among other things, that although these essential extensions are not necessarily equivalent, they behave almost equivalently with regard to injectivity.     

Investigating the effects of precursor concentration and gelling parameters on droplet-based generation of Ca-Alginate microgels: identifying new stable modes of droplet formation

Droplet-based microfluidics is an attractive approach for producing microgels due to its high potential to control the size and shape of the particles and precisely entrap the substances within the hydrogel matrix. However, the microfluidic generation of monodisperse microgels with desired structures is still challenging. Indeed, the rheological and interfacial properties of the immiscible fluids, as well as the adopted gelling strategy, play important roles in microfluidic methods. Herein, sodium alginate droplets with different concentrations are generated via a microfluidic device with a flow-focusing unit. Besides, a combined in situ and ex situ strategy is optimized to crosslink sodium alginate droplets in the presence of calcium ions. The effects of alginate concentration and junction width in the flow focusing unit are investigated on droplet size and droplet formation regimes. It is observed that by increasing the alginate concentration, the dripping regime of droplet formation may be transformed to one of the binary dripping or quasijetting regimes. In the binary dripping regime, two successive different-sized droplets are generated in each period of droplet formation, which leads to low monodispersity in the collected droplets. However, the droplets produced in the quasijetting regime are interestingly monodisperse and also smaller than those of the dripping and binary dripping regimes. The breakup dynamics of the alginate thread is also analyzed with a computational fluid dynamics (CFD) code. This analysis discloses that the viscous stresses, as well as the viscous dissipation, have important roles in controlling the stable modes of droplet formation.     

Voltammetric determination of droxidopa in the presence of carbidopa using a nanostructured base electrochemical sensor

A novel carbon paste electrode modified with ZnO nanorods and 2-(4-oxo-3-phenyl-3,4-dihydroquinazolinyl)-N′-phenyl-hydrazinecarbothioamide (2PHCZNCPE) was fabricated and employed to study the electrocatalytic oxidation of droxidopa, using cyclic voltammetry, chronoamperometry and square wave voltammetry as diagnostic techniques. It has been found that the oxidation of droxidopa at the surface of modified electrode occurs at a potential of about 435 mV less positive than that of an unmodified carbon paste electrode. Square wave voltammetry exhibits a linear dynamic range from 7.0 × 10^–8 to 3.0×10^?4 M and a detection limit of 45.0 nM for droxidopa. Finally this modified electrode was used for simultaneous determination of droxidopa and carbidopa.     

Internal injectivity of Boolean algebras in MSet

This paper deals with the internal notion of injectivity for Boolean algebras in the topos of M-sets. Given that, for ordinary Boolean algebraas, injectivity is the same as completeness (Sikorski's theorem) and the injective hull is the same as normal completion, we investigate here how the internal notion of completeness relates to internal injectivity. Further, we consider the internal injectivity of the initial Boolean algebra 2 which is equivalent to the prime ideal theorem for Boolean algebras in this topos. Before we turn specificially to Boolean algebras, we develop the bassic general facts concerning internal injectivity in MSet for arbitrary equational classes of algebras.     

Image quality assessment using the singular value decomposition theorem

In objective image quality metrics, one of the most important factors is the correlation of their results with the perceived quality measurements. In this paper, a new method is presented based on comparing between the structural properties of the two compared images. Based on the mathematical concept of the singular value decomposition (SVD) theorem, each matrix can be factorized to the products of three matrices, one of them related to the luminance value while the two others show the structural content information of the image. A new method to quantify the quality of images is proposed based on the projected coefficients and the left singular vector matrix of the disturbed image based on the right singular vector matrix of the original image. To evaluate this performance, many tests have been done using a widespread subjective study involving 779 images of the Live Image Quality Assessment Database, Release 2005. The objective results show a high rate of correlation with subjective quality measurements.     

A comprehensive study of domain-specific emoji meanings in sentiment classification

Computational Management Science - The inclusion of emojis when solving natural language processing problems (e.g., text‐based emotion detection, sentiment classification, topic analysis)...     

Preparation and electromagnetic wave absorption properties of polymer nanocomposites based on new functionalized graphene oxide iron pentacarbonyl and ionic liquid

Research on Chemical Intermediates - This paper presents the preparation of a new epoxy nanocomposite of functionalized graphene oxide (FGO) and iron pentacarbonyl [Fe(CO)5] (IPC) as...