Perfluordicarbonsäuren,VI [1] Darstellung der perfluorpyridin-2,3-dicarbonsäure durch oxidation von perfluorchinolin

The oxidation of perfluoroquinoline with nitric acid (98%) yields perfluoropyridine-2.3-dicarboxylic acid (V) besides 2.3.4.6.7-pentafluoro-5.8-dioxo-5.8-dihydro-quinoline (IV) and 3.4.5.6.7.8-Hexafluoro-2-oxo-1.2-dihydro-quinoline (VIa).     

Non-centrosymmetric coordination polymers based on thallium and acetylenedicarboxylate

Single crystals of anhydrous thallium acetylenedicarboxylate (Tl₂(C₄O₄), 1) and thallium acetylenedicarboxylate oxalate (Tl₄(C₄O₄)(C₂O₄), 2) precipitated from aqueous solutions containing thallium(I)-acetate and the respective organic acids. Both compounds crystallize in non-centrosymmetric space groups (1: P2₁2₁2₁; 2: C2) and contain stereochemically active lone pairs at Tl(I). The crystal structures of 1 and 2 show some similarities. Tl atoms are organized in corrugated layers, which are connected by the respective carboxylate anions. Upon heating 1 decomposes at 195 °C to form elemental pyrophorous thallium powder. 2 starts decomposing at approx. 150 °C forming elemental thallium next to another compound, which could not be identified up to now. TlHADC was also synthesized, but its crystal structure could not be solved either from powder or single crystal diffraction data. Upon heating it decomposes to form 1.     

Modelling of self-aligned total internal reflection waveguide mirrors: an interlaboratory comparison

Results of modelling of light propagation in 45° self-aligned total internal reflection rib waveguide mirrors on InP substrate are compared. Six laboratories participated in the comparison with the following six modelling methods: the standard fast-Fouriertransform beam propagation method (BPM), the standard finite-difference (FD) BPM using the Crank-Nicholson scheme (two laboratories), the FD-BPM with the correction for the slowly varying envelope approximation, the method of lines, the eigenmode expansion and propagation method, and a simple method based on the field overlap. All the laboratories used the effective-index method to reduce the three-dimensional problem to two dimensions. The differences among the results obtained by different methods are briefly discussed and qualitatively compared to measured values.     

The photometric determination of silicon as α-silicomolybdic acid

A photometric method for the determination of silicon based on the yellow color of α-silicomolybdic acid is described. The pH must be kept within the range 3.0–3.7, and the equilibrium state is established by beating the solution. Since the color of this modification is remarkably stable and reproducible, a high degree of precision can be attained.     

Finite-size scaling and universality of the thermal resistivity of liquid 4He near Tlambda

We present measurements of the thermal resistivity rho(t,P,L) near the superfluid transition of 4He at saturated vapor pressure and confined in cylindrical geometries with radii L=0.5 and 1.0 microm [t identical with T/T(lambda)(P)-1]. For L=1.0 microm measurements at six pressures P are presented. At and above T(lambda) the data are consistent with a universal scaling function F(X)=(L/xi(0))(x/nu)(rho/rho(0)), X=(L/xi(0))(1/nu)t valid for all P (rho(0) and x are the pressure-dependent amplitude and effective exponent of the bulk resistivity rho, and xi=xi(0)t(-nu) is the correlation length). Indications of breakdown of scaling and universality are observed below T(lambda).     

Heat transport in turbulent rayleigh-Benard convection

We present measurements of the Nusselt number N as a function of the Rayleigh number R in cylindrical cells with aspect ratios 0. 510(7) they are consistent with N = asigma-1/12R1/4+bsigma-1/7R3/7 as proposed by Grossmann and Lohse for sigma greater, similar2.