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21.
Milligan JR Aguilera JA Hoang O Ly A Tran NQ Ward JF 《Journal of the American Chemical Society》2004,126(6):1682-1687
By using gamma-irradiation in the presence of thiocyanate ions, we have generated guanyl radicals in plasmid DNA. These can be detected by using an Escherichia coli base excision repair endonuclease to convert their stable end products to strand breaks. The yield of enzyme-sensitive sites is strongly attenuated by the presence of micromolar concentrations of one of a series of singly substituted phenols, and it is possible to derive bimolecular rate constants for the reduction of DNA guanyl radicals by these phenols. More strongly reducing phenols were found to react more rapidly. This electron-transfer reaction also involves a proton transfer. By comparing the expected energetics of the reaction with the observed rate constants, the electron transfer is found to be mechanistically coupled with the proton transfer. 相似文献
22.
23.
Pedro López García Fabio Pereira Gomes Maria Inês Rocha Miritello Santoro Érika Rosa Maria Kedor-Hackmann Jose Luis Vilchez Quero Alberto Navalón Montón Guillermo Crovetto Montoya Mercedes Aguilera Cabrera 《Chromatographia》2011,73(7-8):799-805
Vecuronium bromide is a neuromuscular blocking agent used for anesthesia to induce skeletal muscle relaxation. HPLC and CZE analytical methods were developed and validated for the quantitative determination of vecuronium bromide. The HPLC method was achieved on an amino column (Luna 150 × 4.6 mm, 5 μm) using UV detection at 205 nm. The mobile phase was composed of acetonitrile:water containing 25.0 mmol L?1 of sodium phosphate monobasic (50:50 v/v), pH 4.6 and flow rate of 1.0 mL min?1. The CZE method was achieved on an uncoated fused-silica capillary (40.0 cm total length, 31.5 cm effective length and 50 μm i.d.) using indirect UV detection at 230 nm. The electrolyte comprised 1.0 mmol L?1 of quinine sulfate dihydrate at pH 3.3 and 8.0% of acetonitrile. The results were used to compare both techniques. No significant differences were observed (p > 0.05). 相似文献
24.
Aguilera EF Amador-Valenzuela P Martinez-Quiroz E Lizcano D Rosales P García-Martínez H Gómez-Camacho A Kolata JJ Roberts A Lamm LO Rogachev G Guimarães V Becchetti FD Villano A Ojaruega M Febbraro M Chen Y Jiang H DeYoung PA Peaslee GF Guess C Khadka U Brown J Hinnefeld JD Acosta L Rossi ES Huiza JF Belyaeva TL 《Physical review letters》2011,107(9):092701
Fusion cross sections were measured for the exotic proton-halo nucleus ?B incident on a ??Ni target at several energies near the Coulomb barrier. This is the first experiment to report on the fusion of a proton-halo nucleus. The resulting excitation function shows a striking enhancement with respect to expectations for normal projectiles. Evidence is presented that the sum of the fusion and breakup yields saturates the total reaction cross section. 相似文献
25.
On the structure of the stochastic process of mortgages in Spain 总被引:1,自引:1,他引:0
P. R. Bouzas A. M. Aguilera M. J. Valderrama N. Ruiz-Fuentes 《Computational Statistics》2006,21(1):73-89
Summary The number of mortgages in Spain is a counting process that can be modelled as a doubly stochastic Poisson process (DSPP).
A modelling method for the intensity of a DSPP is proposed. A first step consists on estimating discrete sample paths of it
from observed ones of the DSPP, then a continuous modelling is derived by means of Functional Principal Component Analysis.
The method is validated by a simulation. Finally, it is applied to the real process of the mortgages in Spain discussing the
interpretation of the principal components and factors. 相似文献
26.
Advances in characterization of laser induced plasmas by optical emission spectroscopy are reviewed in this article. The review is focused on the progress achieved in the determination of the physical parameters characteristic of the plasma, such as electron density, temperature and densities of atoms and ions. The experimental issues important for characterization by optical emission spectroscopy, as well as the different measurement methods are discussed. The main assumptions of the methods, namely the optical thin emission of spectral lines and the existence of local thermodynamic equilibrium in the plasma are evaluated. For dense and inhomogeneous sources of radiation such as laser induced plasmas, the characterization methods are classified in terms of the optical depth and the spatial resolution of the emission used for the measurements. The review deals firstly with optically thin spatially integrated measurements. Next, local measurements and characterization in not optically thin conditions are discussed. Two tables are included that provide reference to the works reporting measurements of electron density and temperature of laser induced plasmas generated with diverse samples. 相似文献
27.
Faustino Aguilera‐Granja Jesús Carrete Andrés Vega Luis J. Gallego 《International journal of quantum chemistry》2015,115(8):523-528
We performed density‐functional‐theoretic calculations to investigate the structural, magnetic and vibrational properties of the stoichiometric clusters (CrN)n ( ). We show that the building block of the ground‐state structures of these clusters is a square CrNCrN unit; the only exception with n > 2 occurs for (CrN)3, but this cluster has an isomer not very far in energy from the ground state consisting of a pair of CrNCrN squares sharing a CrN bond. In the smaller CrN, (CrN)2, and (CrN)3 clusters the magnetic moments of the N atoms are non‐negligible and antiparallel to those of the Cr atoms, but for the larger species (CrN)4, (CrN)5, (CrN)6, and (CrN)9 the cluster magnetic moments are almost entirely due to the Cr atoms. Lack of imaginary vibrational frequencies in the predicted ground‐state structures of (CrN)n ( ) confirms that they are mechanically stable equilibrium states. © 2015 Wiley Periodicals, Inc. 相似文献
28.
Tomás Alonso‐Lanza Dr. Andrés Ayuela Prof. Faustino Aguilera‐Granja 《Chemphyschem》2015,16(17):3700-3710
We carried out density functional calculations to study the adsorption of Co13 clusters on graphene. Several free isomers were deposited at different positions with respect to the hexagonal lattice nodes, allowing us to study even the hcp 2d isomer, which was recently obtained as the most stable one. Surprisingly, the Co13 clusters attached to graphene prefer icosahedron‐like structures in which the low‐lying isomer is much distorted; in such structures, they are linked with more bonds than those reported in previous works. For any isomer, the most stable position binds to graphene by the Co atoms that can lose electrons. We find that the charge transfer between graphene and the clusters is small enough to conclude that the Co–graphene binding is not ionic‐like but chemical. Besides, the same order of stability among the different isomers on doped graphene is kept. These findings could also be of interest for magnetic clusters on graphenic nanostructures such as ribbons and nanotubes. 相似文献
29.
Nordström J Aguilera L Matic A 《Langmuir : the ACS journal of surfaces and colloids》2012,28(9):4080-4085
We have investigated the stability and interactions in dispersions of colloidal fumed silica, Aerosil 200, and the ionic liquid 1-butyl-3-methylimidazolium tetraflouroborate (BMImBF(4)) as a function of the Li salt concentration (LiBF(4)). Photon correlation spectroscopy was used to study the aggregation behavior at low silica concentrations, and Raman spectroscopy was used to investigate the interactions in the ionic liquid and with the silica surface. We find that the addition of LiBF(4) increases the stability of the dispersions, with smaller agglomerates of silica particles and higher gelation concentrations in the presence of Li salt. The increased stability with the addition of Li salt is explained by the formation of a more stable solvation layer, where Li ions accumulate on the surface. This leads to an increased interaction between lithium ions and the BF(4)(-) anions in the solvation layer, as seen by Raman spectroscopy. Upon gelation, the Li ions are expelled from the surface because hydrogen bonding between the silica particles are formed. For both neat BMImBF(4) and Li-salt-doped BMImBF(4)/silica dispersions, a weak gel phase was found preceding the formation of a strong gel at slightly higher silica concentrations. 相似文献
30.
The development of new materials for water purification is of universal importance. Among these types of materials are layered double hydroxides (LDHs). Non-ionic materials pose a significant problem as pollutants. The interaction of methyl orange (MO) and acidic scarlet GR (GR) adsorption on hydrocalumite (Ca/Al-LDH-Cl) was studied by X-ray diffraction (XRD), infrared spectroscopy (MIR), scanning electron microscope (SEM), and near-infrared spectroscopy (NIR). The XRD results revealed that the basal spacing of Ca/Al-LDH-MO was expanded to 2.45 nm, and the MO molecules were intercalated with a interpenetrating bilayer model in the gallery of LDH, with 49° tilting angle. Yet, Ca/Al-LDH-GR was kept the same d-value as Ca/Al-LDH-Cl. The NIR spectrum for Ca/Al-LDH-MO showed a prominent band around 5994 cm(-1), assigned to the combination result of the NH stretching vibrations, which was considered as a mark to assess MO(-) ion intercalation into Ca/Al-LDH-Cl interlayers. From SEM images, the particle morphology of Ca/Al-LDH-MO mainly changed to irregular platelets, with a "honey-comb" like structure. Yet, the Ca/Al-LDH-GR maintained regular hexagon platelets, which was similar to that of Ca/Al-LDH-Cl. All results indicated that MO(-) ion was intercalated into Ca/Al-LDH-Cl interlayers, and acidic scarlet GR was only adsorbed upon Ca/Al-LDH-Cl surfaces. 相似文献