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991.
Aerodynamic interaction of two bodies in a supersonic flow 总被引:1,自引:0,他引:1
992.
P.Veeraraghavan Ramachandran Kamlesh J Padiya Vivek Rauniyar M.Venkat Ram Reddy Herbert C Brown 《Journal of fluorine chemistry》2004,125(4):615-620
Asymmetric “allyl”boration of pentafluorobenzaldehyde with various α-pinene based “allyl”boranes provides homoallylic alcohols in high de and ee; the alcohols have been converted into δ-lactones via acryloylation, ring-closing metathesis and hydrogenation. Pentafluorophenyl analog of key pharmacophore of statin drugs has been synthesized using diastereoselective epoxidation and regioselective reduction as key steps. 相似文献
993.
994.
In the present paper, the Shubnikov–de Haas oscillation frequencies arising in laminated charge-ordered crystals with a monotonic negative reluctance due to scattering of current carriers on charged impurities with a short-range potential are calculated and classified. It is demonstrated that non-semiclassical oscillation frequencies can be a measure of charge ordering. 相似文献
995.
The catalytic activity of three groups of acid catalysts different in the nature and strength of acid sites in the skeletal isomerization of n-butane was studied. It was found that the strength of the sites did not correlate with the rate of the reaction. 相似文献
996.
The reaction pathway for the Ca3Al2O6 formation up to 1300°C, from mechanochemically treated mixtures of amorphous aluminum hydroxide and CaCO3, was studied in situ by differential thermal analysis, constant heating rate dilatometry and time-resolved neutron powder diffraction. The experiment was carried out, in an open system, on a sample with the nominal Ca3Al2O6 stoichiometry. The results obtained by neutron diffractometry and thermal analysis were in good agreement with the data obtained by scanning electron microscopy and X-ray diffraction on heat-treated and-quenched samples. The synthesis path implied the formation of cryptocrystalline Al2O3, crystalline CaO, CaAl2O4 and Ca12Al14O33 as transitory phases. Finally the nucleation and growth of the single phase Ca3Al2O6 took place at 1300°C and exhibited porous structure due to CO2 and H2O release. 相似文献
997.
Liquid-vapor equilibria and azeotropy in isobutanol-n-butanol-butyl butenyl ether ternary system and in isobutanol-butyl butenyl ether and n-butanol-butyl butenyl ether binary systems were studied experimentally and calculated, as well as azeotropy in butyl alcohols-butyl butenyl ether-water systems under atmospheric and reduced pressure. Recovery of commercial butyl alcohols by distillation of alcohol-ether fractions was studied. 相似文献
998.
C. Torres O. Alejos C. de Francisco J.M. Muñoz P. Hernández-Gómez 《Applied Physics A: Materials Science & Processing》2003,77(3-4):543-547
This paper describes a robust and fast fitting procedure applicable for relaxing processes that cannot be understood as a discrete sum of single processes but require an activation energy distribution. The method is based on a set of closed-form expressions that allow the computation of the relaxation parameters directly from the isochronal curves obtained experimentally. The usefulness of this method is checked by analyzing the isochronal curves given by a theoretical energy distribution and the magnetic disaccommodation spectra observed in yttrium iron garnet (YIG) samples. PACS 02.60.Ed; 75.60.Lr; 75.50.Gg 相似文献
999.
S. P. Gavva 《Optics and Spectroscopy》2003,95(2):208-212
In the context of the theory of molecular vibrations, by applying the direct product operation of matrices, an equation for the vibrations of vibrationally excited molecules at combination and difference frequencies is obtained. From the solution of this equation, elements of vibration patterns and expressions that can be used for the study of changes in the molecular structural parameters and the coefficients of kinematic interactions are determined. The formulas obtained are applied to the calculation of the anharmonic electro-optical parameters of the molecules of water H2O and its two isotopes H2 17O and H2 18O. These calculations are performed in terms of the semiempirical quantum-chemical CNDO/2 method and by numerical differentiation of dipole moment functions by employing a cubic spline approximation. 相似文献
1000.
Cerium(IV) ammonium nitrate in substoichiometric amounts, promotes the intramolecular cyclization of epoxypropyl cinnamyl ethers to the corresponding 3,4,5-trisubstituted tetrahydropyran derivatives in moderate to good yields. 相似文献