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91.
Reaction of nitrilimines 1 with 2-cyanomethylbenzimidazole 2 gave the 3-arylazo-2-methylpyrrolo[1,2-a]benzimidazole 4a rather than the reported 2-arylazo-3-methylpyrrolo[1,2-a]benzimidazole 3a. The correct structure of the product was determined using X-ray crystal structure analysis. The similar reaction of nitrilimines with 2-aminobenzimidazole 5 gave the acyclic nucleophilic addition product 6. 相似文献
92.
M. Sadegh Movahed Marzieh Farhang Sohrab Rahvar 《International Journal of Theoretical Physics》2009,48(4):1203-1230
We study one of the simplest covariant modified-gravity models based on the Dvali-Gabadadze-Porrati (DGP) brane cosmology,
a self-accelerating universe. In this model gravitational leakage into extra dimensions is responsible of late-time acceleration.
We mainly focus on the effects of the model parameters on the geometry and the age of universe. Also we investigate the evolution
of matter density perturbations in the modified gravity model, and obtain an analytical expression for the growth index, f. We show that increasing
leads to less growth of the density contrast δ, and also decreases the growth index. We give a fitting formula for the growth index at the present time and indicate that
dominant term in this expression verifies the well-known approximation relation f≃Ω
m
γ
. As the observational test, the new Supernova Type Ia (SNIa) Gold sample and Supernova Legacy Survey (SNLS) data, size of
baryonic acoustic peak from Sloan Digital Sky Survey (SDSS), the position of the acoustic peak from the CMB observations and
the Cluster Baryon Gas Mass Fraction (gas) are used to constrain the parameters of the DGP model. We also combine previous
results with large scale structure formation (LSS) from the 2dFGRS survey. Finally to check the consistency of the DGP model,
we compare the age of old cosmological objects with age of universe in this model. 相似文献
93.
This paper is concerned with the existence of positive homoclinic solutions for the second-order differential equation where \(c\ge 0\) is a constant and the functions a and f are continuous and not necessarily periodic in t. Under other suitable assumptions on a and f, we obtain the existence of positive homoclinic solutions in both cases sub-quadratic and super-quadratic by using critical point theorems.
相似文献
$$\begin{aligned} u^{\prime \prime }+cu^{\prime }-a(t)u+f(t,u)=0, \end{aligned}$$
94.
The reaction of nitrilimine 6a with ethyl pyridine-2-acetate (7) gave the corresponding pyrrolo[1,2-a]pyridine 8, while the reaction of 6b containing an ester moiety afforded the acyclic adduct 9. The reaction of 6a with 2-aminopyrimidine (10) gave the novel unexpected pyrimido[2,1-d]1,2,3,5-tetrazine 11. Acyclic adducts 16 and 17 were obtained from the reaction of 6b with 2-cyanomethylbenzimidazole (14) and 2-aminobenzimidazole (15), respectively. 相似文献
95.
This paper aims to present a general framework of the quadratic spline functions to develop a numerical method for solving the nonlinear space fractional Fisher's equation. Using Von Neumann method, the proposed method is shown to be conditionally stable. Finally, a numerical example is given to verify the effectiveness of the proposed algorithm. The results reveal that the proposed approach is very effective, convenient, and quite accurate to such considered problems. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
96.
Farag A. El-Essawy Ahmed F. Khattab Adel A.-H. Abdel-Rahman 《Monatshefte für Chemie / Chemical Monthly》2007,47(4):777-785
1-Carbethoxymethyl-4,6-dimethyl-1H-[1,2,3]triazolo[4,5-d]pyrimidine-5,7(4H,6H)-dione was synthesized and treated with hydrazine hydrate to give the corresponding hydrazide. The latter hydrazide was treated
either with phenylisothiocyanate or with carbon disulfide/alc. KOH to afford the corresponding thiosemicarbazide and oxadiazole
derivatives. Alkylation of 2-mercapto-1,3,4-oxadiazole with dimethyl sulfate or ethyl chloroacetate gave the corresponding
2-methylthio-, and 2-ethylthioglycolate derivatives. Formation of 1,3,4-thiadiazole, 5-mercapto-1,2,4-triazole, and 1,3,4-oxadiazole
were carried out by treating of the latter thiosemicarbazide with conc. H2SO4, NaOH/HCl, and HgO. Treating of 5-mercapto-1,2,4-triazole with ethyl chloroacetate afforded the thioglycolate ester. Hydrolysis
of the latter with hydrazine hydrate afforded the hydrazide derivatives. Condensation of these hydrazides with monosaccharide
aldoses gave the corresponding sugar hydrazones. The novel compounds were tested for antiviral activity against hepatitis
B virus and showed moderate activities. 相似文献
97.
Masoumeh Taei Foroozan Hasanpour Mohammad Dinari Nasrin Sohrabi Mohammad Sadegh Jamshidi 《中国化学快报》2017,28(2):240-247
In this study,Au nanoparticles/poly 5-[(2-hydroxynaphthalen-l-yl)diazenyl]isophthalic acid film modified glassy carbon electrode(AuNPs/poly(NDI)/GCE) has shown excellent electrocatalytic activity toward the oxidation of adrenaline(ADR),paracetamol(PAC),and tryptophan(Trp).The bare glassy carbon electrode(GCE) fails to separate the oxidation peak potentials of these molecules,while the poly(NDI) film modified electrode can resolve them.Electrochemical impedance spectroscopy(EIS)indicates that the charge transfer resistance of the bare electrode decreases as 5-[(2-hydroxynaphthalen-l-yl)diazenyl]isophthalic acid is electropolymerized on the bare electrode.Furthermore,EIS exhibits enhancement of electron transfer kinetics between analytes and the electrode after electrodeposition of Au nanoparticles.Differential pulse voltammetry results show that the electrocatalytic current increases linearly in the ranges of 0.01-680.0 μmol L~1 for ADR,0.05-498.0 μmol L~1 for PAC,and 3.0-632.0 μmol L~1 for Trp;with detection limits(S/N = 3) of 0.009 μmol L~1,0.005 μmol L~1,and 0.09 μmol L~1 for ADR,PAC,and Trp,respectively.The proposed method has been successfully applied for simultaneous determination of ADR,PAC,and Trp in biological samples. 相似文献
98.
Chahra Bouchameni Chahrazed Beghidja Adel Beghidja Pierre Rabu Richard Welter 《Polyhedron》2011,30(11):1774-1778
Two new complexes [MnIII(HL)2(acac)] and [MnII(HL)2]n have been obtained by reacting manganese(III) acetylacetonate monohydrate or manganese(II) chloride monohydrate with 2-salicylichydrazono-1,3-dithiolane ligand (H2L). Both compounds have been fully characterized by spectroscopic methods and single crystal X-ray diffraction. In the solid state, the molecular packing are described and discussed in term of weak H-bonds and short contacts. The unprecedented bridging coordination mode of this ligand lead to the first 2-salicylichydrazono-1,3-dithiolane-bridged coordination polymer [MnII(HL)2]n. The EPR spectrum of this compound was obtained with g ≈ 2.07, corresponding to a manganese ion (+II) in octahedral high-spin coordination sphere. The MnII complex exhibit paramagnetic behavior corresponding to quasi-isolated metal centers. 相似文献
99.
S. Kimiagar M. Sadegh Movahed S. Khorram M. Reza Rahimi Tabar 《Journal of statistical physics》2011,143(1):148-167
Using the Markovian method, we study the stochastic nature of electrical discharge current fluctuations in the Helium plasma.
Sinusoidal trends are extracted from the data set by the Fourier-Detrended Fluctuation analysis and consequently cleaned data
is retrieved. We determine the Markov time scale of the detrended data set by using likelihood analysis. We also estimate
the Kramers-Moyal’s coefficients of the discharge current fluctuations and derive the corresponding Fokker-Planck equation.
In addition, the obtained Langevin equation enables us to reconstruct discharge time series with similar statistical properties
compared with the observed in the experiment. We also provide an exact decomposition of temporal correlation function by using
Kramers-Moyal’s coefficients. We show that for the stationary time series, the two point temporal correlation function has
an exponential decaying behavior with a characteristic correlation time scale. Our results confirm that, there is no definite
relation between correlation and Markov time scales. However both of them behave as monotonic increasing function of discharge
current intensity. Finally to complete our analysis, the multifractal behavior of reconstructed time series using its Keramers-Moyal’s
coefficients and original data set are investigated. Extended self similarity analysis demonstrates that fluctuations in our
experimental setup deviates from Kolmogorov (K41) theory for fully developed turbulence regime. 相似文献
100.
Three different experimental measurements, namely, rheology, particle sizing, and x-ray diffraction (XRD), were used to study the effect of anionic additives on the properties of bentonite suspensions. The three additives were sodium carboxymethylcellulose, xanthan gum, and sodium dodecyl sulfate. Flow curves were obtained from shear stress–shear rate measurements, and the viscoelastic properties were determined from oscillatory and transient measurements. Mineralogical data were evaluated by XRD and the particle size analysis performed by light scattering technique. The presence of the surfactant modifies the face-to-face interactions and yields changes of the mixtures rheological behavior at low deformation rates. Polymers act by coating each clay particle and prevent their agglomeration. Therefore, the additives are responsible for the mechanisms of destructuration and structure reorganization as well as the mixtures viscous and viscoelastic behavior. 相似文献