The effect of fluorine-based plasma treatment on morphology and chemical surface composition of biocompatible silicone elastomer

X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) have been used to investigate the effect of reactive ion etching (RIE) on poly(methylhydrogensiloxane-co-dimethylsiloxane) surface in fluorine-based plasmas. Polysiloxane layers supported on the standard silicon wafers were etched using SF₆ + O₂ or CF₄ + O₂ plasmas. SEM studies show that the polysiloxane morphology depends on plasma chemical composition strongly. Presence of a columnar layer likely covered with a fluorine rich compound was found on the elastomer surface after the CF₄ + O₂ plasma exposure. After the SF₆ + O₂ or CF₄ + O₂ plasma treatment the polysiloxane surface enriches with fluorine or with fluorine and aluminum, respectively. Different morphologies and surface chemical compositions of the silicone elastomer etched in both plasmas indicate different etching mechanisms.     

At the other side of a saddle-node

We describe phenomena occurring just before a saddle-node bifurcation for one-parameter families of interval maps. In particular, as a parameter approaches the bifurcation value, attracting periodic orbits of periodsk, k+1,k+2,k+3,... can appear. We make a detailed study of a family of cusp-shaped maps, where this phenomenon occurs in a pure form.     

Plane contact problems for a periodic two-layered elastic composite

Summary This paper deals with the two-dimensional static punch problems in the presence of friction for a periodically layered half-space. Within the framework of the homogenized model of linear elasticity with microlocal parameters [8–11] the exact solutions of the considered problems are obtained. The case of the indentation of the composite body by a rigid rectangular punch has been discussed in detail.

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Ebene Kontaktprobleme für ein periodisches elastisches Zweischichten-Komposit

Übersicht In dieser Arbeit wird das zweidimensionale statische Stempelproblem mit Reibung für einen periodisch geschichteten Halbraum betrachtet. Im Rahmen eines Homogenisierungsmodells der linearen Elastizitätstheorie mit mikropolaren Parametern werden die exakten Lösungen der betrachteten Probleme gewonnen. Im Detail wird das Eindringen eines rechteckigen starren Stempels behandelt.

     

Intra- versus intermolecular hydrogen bonds in salicylamide derivatives

The crystal structures, solid-state infrared patterns, and thermal properties of two polymorphs of 4-nitrosalicylanilide are presented. In both polymorphs, intramolecular hydrogen bonds are found between the phenol oxygen and the amide proton, and intermolecular hydrogen bonds are found between the amide carbonyl oxygen and the phenol proton. These hydrogen bond patterns are compared to those found in other known salicylamide derivatives and an analysis is given of the factors contributing to preferences for intra- or intermolecular hydrogen bonds in these structures. Crystal data: polymorph, orthorhombic,Pbca,a=11.003(4),b=27.959(7),c=7.622(5) Å,Z=4,V=2345(3) ų, andR=0.038 (1351 reflections); polymorph, monoclinic,P2₁/a,a=28.36(1),b=11.64(1),c=7.293(8) Å,=90.68(6)°,Z=8,V=2408 ų, andR=0.043 (2425 reflections).     

Some aspects of deformation in Al-Zn alloys

Creep resistance investigations of the Al-40 wt % Zn alloy at room temperature have been performed and revealed some creep compliance. Additions of Cu and Si decrease considerably the preliminary creep compliance in the alloy which then turn to be dimensionally stable and resistant to creep. Tensile test investigations performed at different deformation rates have not revealed the existance of the superplastic deformation mechanism.Presented at the 4^th International Symposium on Plasticity of Metals and Alloys, September 711, 1987, Srni, Czechoslovakia.     

The group of local biholomorphisms of ℂ1 and conformal field theory in the operator formalism

Motivated by the operator formulation of conformal field theory on Riemann surfaces, we study the properties of the infinite dimensional group of local biholomorphic transformations (conformal reparametrizations) of ¹ and develop elements of its representation theory.     

New photocatalysts: Dispersed semiconductor materials with microheterojunctions

We have obtained new semiconductor materials with microheterojunctions by substitution of surface cadmium ions in CdS by Cu(I), Cu(II), and Bi(III) ions. We have shown that the photocatalytic activity of their dispersions in the reaction of evolution of H₂ from alcohol-water mixtures is considerably higher than in the original cadmium sulfide.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 29, No. 3, pp. 270–274, May–June, 1993.We would like to acknowledge Academician V. D. Pokhodenko of the Academy of Sciences of Ukraine for drawing our attention to the prospects for investigation of complex photocatalytic systems based on semiconductors with different types of conductivity.     

Molybdenum-catalyzed episulfidation of (E)-cycloalkenes with elemental sulfur

Episulfidation of (E)-cyclooctene and (E)-cyclononene was achieved with elemental sulfur by using a catalytic amount of a molybdenum oxo complex.