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11.
P. Abreu W. Adam T. Adye E. Agasi I. Ajinenko R. Aleksan G. D. Alekseev P. P. Allport S. Almehed S. J. Alvsvaag et al. 《Zeitschrift fur Physik C Particles and Fields》1995,68(3):353-362
The decayB
*B
has been observed with the DELPHI detector at LEP, where theB
* meson is produced inZ boson decays. The combination of inclusively reconstructedB mesons with well-measured converted photons yields a measurement of the flavour-averagedB
*-B mass difference of 45.5±0.3 (stat.) ±0.8 (syst.) MeV/c2. 95% confidence level upper limits at 6 MeV/c2 are placed on both the isospin (i.e.B
+-B
0) and theB
s
-B
ud
splitting of the mass difference. The production ratio ofB
* toB mesons inZ decays is measured to be 0.72±0.03 (stat.) ±0.06 (syst.). Limits on the production cross-section of other hypothetical excitedB hadron states decaying radiatively are established. The differentialB
* cross section has been measured to be in good agreement with the averageb fragmentation, yielding an average fractionalB
* energy of x
E
=0.695±0.009 (stat.) ±0.013 (syst.). From the decay angular distribution the relative contribution of longitudinalB
* polarisation states is measured to be L/(L + T) = 0.32 ± 0.04 (stat.) ±0.03 (syst.).CICYT_AEN93-0832 相似文献
12.
P. Abreu W. Adam T. Adye E. Agasi R. Aleksan G. D. Alekseev P. Allport S. Almehed F. M. L. Almeida Junior S. J. Alvsvaag et al. 《Zeitschrift fur Physik C Particles and Fields》1994,63(1):3-15
The average lifetime ofB hadrons was measured using data collected with the DELPHI detector at the LEP collider during 1991 and 1992. The measurement was performed using two different anayses. The first method was an improvement on a previous technique, which used charged particle impact parameter distributions. This analysis measured an average lifetime forB hadrons of
相似文献
13.
P. Abreu W. Adam T. Adye E. Agasi R. Aleksan G. D. Alekseev A. Algeri S. Almehed S. J. Alvsvaag U. Amaldi et al. 《Zeitschrift fur Physik C Particles and Fields》1994,61(3):407-419
The study of the properties of inclusive production ofD
s
mesons and of events in which a and a muon are present in the same jet provides two independent measurements of the probability,f
s
w
, for a heavy quark to hadronize into a strangeB orD meson. The data sample analysed corresponds to 243,000 hadronicZ
0 decays. The combined value of these measurements isf
s
w
=0.19±0.06±0.08. From the flight distance distributions ofD
s and of (-lepton) secondary vertices, with the lepton emitted at high transverse momentum relative to the jet axis, two values are obtained for theB
s
0
meson lifetime. Combining these measurements with a previous result based on the study ofD
s- events, theB
s
0
meson lifetime is measured to be: 0.96±0.37 ps. 相似文献
14.
The main problem on caps, posed originally by Segre in the fifties, is to determine the values of k for which there exists a complete k-cap. Very few results on this problem are known. The cardinality of the largest cap(s) and the smallest complete cap(s) are crucial. In this paper it is shown that there exist complete k-caps in PG(3, q), q an odd prime 5 or q = 9, such that k = (q2 + q + 6)/3 or k = (q2 + 2q + 6)/3. These complete caps are smaller than those currently known for q odd.In memoriam Giuseppe Tallini 相似文献
15.
Queiroz MJ Abreu AS Ferreira PM Oliveira MM Dubest R Aubard J Samat A 《Organic letters》2005,7(22):4811-4814
[structure: see text] A new photochromic thieno-2H-chromene alpha-amino acid derivative was prepared by C-N palladium-catalyzed cross-coupling of a bromothieno-2H-chromene with the aminated aromatic side chain of the methyl ester of a N,N-diprotected amino acid. Its good photochromic properties demonstrated by flash photolysis and continuous irradiation indicate a possible application in ophthalmic lenses. It may also be inserted into peptides to give photoinduced reversible structural changes. 相似文献
16.
María Fernanda Martínez-Esperón 《Tetrahedron》2006,62(16):3843-3855
N,N′-aryl- and N,N′-alkyl-buta-1,3-diyne-1,4-ditosylamides have been synthesized for the first time, in good to excellent yields, by copper-catalyzed dimerization of the corresponding N-aryl or N-alkyl tosylynamides. Negishi coupling of N-ethynylzinc tosylamides derivatives with (hetero)aryl iodides in the presence of Pd2dba3 and triphenylphosphine affords N-aryl and N-alkyl arylynamides in yields of up to 90%. Intramolecular [4+2] cycloaddition reactions of N-ethynylphenyl ynamides and arylynamides allow the synthesis of carbazoles and benzannulated and heteroannulated carbazoles in moderate-to-good yields. 相似文献
17.
Transmembrane anion transport mediated by halogen bonding and hydrogen bonding triazole anionophores
Laura E. Bickerton Alistair J. Sterling Paul D. Beer Fernanda Duarte Matthew J. Langton 《Chemical science》2020,11(18):4722
Transmembrane ion transport by synthetic anionophores is typically achieved using polar hydrogen bonding anion receptors. Here we show that readily accessible halogen and hydrogen bonding 1,2,3-triazole derivatives can efficiently mediate anion transport across lipid bilayer membranes with unusual anti-Hofmeister selectivity. Importantly, the results demonstrate that the iodo-triazole systems exhibit the highest reported activity to date for halogen bonding anionophores, and enhanced transport efficiency relative to the hydrogen bonding analogues. In contrast, the analogous fluoro-triazole systems, which are unable to form intermolecular interactions with anions, are inactive. The halogen bonding anionophores also exhibit a remarkable intrinsic chloride over hydroxide selectivity, which is usually observed only in more complex anionophore designs, in contrast to the readily accessible acyclic systems reported here. This highlights the potential of iodo-triazoles as synthetically accessible and versatile motifs for developing more efficient anion transport systems. Computational studies provide further insight into the nature of the anion-triazole intermolecular interactions, examining the origins of the observed transport activity and selectivity of the systems, and revealing the role of enhanced charge delocalisation in the halogen bonding anion complexes.Halogen and hydrogen bonding 1,2,3-triazole derivatives efficiently mediate anion transport across lipid bilayer membranes with unusual anion selectivity profiles. 相似文献
18.
Abstract— The spectroscopic properties of hematoporphyrin, hematoporphyrin-dimethyl ester, uroporphyrin and uroporphyrinoctamethyl ester, incorporated into unilamellar liposomes of dipalmitoylphos-phatidylcholine, have been studied with the aim to assess the distribution of porphyrins within the various liposomal compartments.
The results obtained indicate that the highly hydrosoluble uroporphyrin is partitioned in the endoliposomal aqueous pool while its octamethylester is homogeneously distributed in the inner lipid monolayer. Hematoporphyrin and its dimethylester show an heterogeneous distribution within the phospholipid bilayer. At T = 25°C these porphyrins are preferentially located in the outer phospholipid monolayer. Detailed studies on hematoporphyrin indicate that the distribution between the inner and outer phospholipid monolayer is a function of temperature and liposome dimensions. In particular, the increase of temperature above the critical temperature for the liquid-gel phase transition of the liposomes causes a partial shift of the porphyrin molecules toward the inner phospholipid monolayer. Moreover, the increase of liposome dimensions leads to a greater accessibility of porphyrin to the external medium. 相似文献 19.
Luisa Fernanda Rojas Paola Zapata Laura Ruiz-Tirado 《Current Opinion in Green and Sustainable Chemistry》2022
According to the Food and Agriculture Organization of the United Nations, approximately 1.3 billion tons of food is wasted each year, equivalent to approximately one-third of world production. Agri-food wastes are the source of proteins, carbohydrates, lipids, and other essential minerals that have been exploited for value-added products by the development of biorefineries and sustainable business as important elements of circular economies. The innovation and materialization of these types of processes, including the use of disruptive technologies on microbial bioconversion and enzyme technology, such as nanotechnology, metabolic engineering, and multi-omics platforms, increase the perspectives on the waste valorization process. Lignocellulolytic enzymes, pectinases, and proteases are mainly used as catalyzers on agri-food waste treatment, and their production in house might be the trend in near future for agro-industrial countries. Another way to transform the agri-food wastes is via aerobic or anaerobic microbial process from fungal or bacterial cultures; these processes are the key to produce waste enzymes. 相似文献
20.
Alistair J. Sterling Alexander B. Dürr Russell C. Smith Edward A. Anderson Fernanda Duarte 《Chemical science》2020,11(19):4895
[1.1.1]Propellane is the ubiquitous precursor to bicyclo[1.1.1]pentanes (BCPs), motifs of high value in pharmaceutical and materials research. The classical Lewis representation of this molecule places an inter-bridgehead C–C bond along its central axis; ‘strain relief’-driven cleavage of this bond is commonly thought to enable reactions with nucleophiles, radicals and electrophiles. We propose that this broad reactivity profile instead derives from σ–π-delocalization of electron density in [1.1.1]propellane. Using ab initio and DFT calculations, we show that its reactions with anions and radicals are facilitated by increased delocalization of electron density over the propellane cage during addition, while reactions with cations involve charge transfer that relieves repulsion inside the cage. These results provide a unified framework to rationalize experimental observations of propellane reactivity, opening up opportunities for the exploration of new chemistry of [1.1.1]propellane and related strained systems that are useful building blocks in organic synthesis.A unified framework that explains the reactivity of [1.1.1]propellane through electron delocalization. 相似文献
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