首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   322篇
  免费   17篇
化学   202篇
晶体学   3篇
力学   3篇
综合类   1篇
数学   70篇
物理学   60篇
  2024年   2篇
  2023年   4篇
  2022年   19篇
  2021年   15篇
  2020年   7篇
  2019年   13篇
  2018年   6篇
  2017年   22篇
  2016年   20篇
  2015年   13篇
  2014年   12篇
  2013年   27篇
  2012年   22篇
  2011年   18篇
  2010年   14篇
  2009年   13篇
  2008年   15篇
  2007年   14篇
  2006年   20篇
  2005年   2篇
  2004年   4篇
  2003年   5篇
  2002年   4篇
  2001年   5篇
  2000年   5篇
  1999年   1篇
  1998年   2篇
  1997年   1篇
  1996年   2篇
  1995年   2篇
  1994年   5篇
  1993年   2篇
  1992年   1篇
  1991年   1篇
  1989年   2篇
  1987年   1篇
  1986年   1篇
  1985年   2篇
  1984年   3篇
  1983年   2篇
  1982年   4篇
  1981年   5篇
  1980年   1篇
排序方式: 共有339条查询结果,搜索用时 375 毫秒
101.
维吾尔语句子边界识别算法的设计与实现   总被引:2,自引:0,他引:2  
本文分析维吾尔语的句子结束形式,研究维吾尔语句子边界规则,给出了句子划分思路,并实现了维吾尔语句子边界识别算法及程序.在对大量手工划分句子语料进行统计测试结果表明,该句子边界识别程序准确率超过98.7%.维吾尔语句子边界识别的研究对实现维吾尔语词性标注系统、维吾尔语句法分析器、机器翻译等众多领域有着很高的实际意义.  相似文献   
102.
103.
Forced hydrolysis of Fe(III) ions in acidic media was performed under controlled synthetic conditions to produce α- and β-FeOOH iron oxides. The forced hydrolysis synthesis was carried out, separately, in an aqueous medium and the lamellar lyotropic liquid crystalline phase of a commercial non-ionic surfactant/water system. The FT-IR analyses confirmed formation of α- and β-FeOOH iron oxides in the aqueous and the surfactant media with slight formation of ferrihydrite and haematite. TEM micrographs have shown that particles formed in the lamellar lyotropic phase are smaller than those produced in the aqueous medium with their smallest size dimension being constrained in the nanometre scale with a size ranging between 5 and 100 nm. Particles produced in the nanoscale size appeared to have different optical properties compared to their counterparts produced in the microscale size.  相似文献   
104.
105.
In this paper, we study the dynamics of a stochastic Susceptible-Infective-Removed-Infective (SIRI) epidemic model with relapse. By constructing a suitable stochastic Lyapunov function, we establish sufficient conditions for the existence of an ergodic stationary distribution to the model. Moreover, sufficient conditions for extinction of the disease are also obtained.  相似文献   
106.
Polybenzidine (PBz) particles were formed by the chemical polymerization in micelles of block copolymer by using Poly (ethylene oxide)-b-Polystyrene [PEO113-b-PSx (x = 50, 58 and 100)] as templates. The samples were characterized by IR, UV-vis absorption spectroscopy, transmission electron microscopy, cyclic voltammetry, constant current charge-discharge and electrochemical impedance to determine their morphologies and electrochemical properties. The results show that the prepared PBz is submicron to nanometer rod-like conducting particles with uniform sizes. Removing the templates did not affect the morphology but slightly reduced the size of the PBz particles. The size and morphology of PBz particles can be tuned by adjusting the amount of monomer. The PBz submicrorods showed 412 F·g?1 specific capacitance in 0.3 mol·L?1HClO4 at the current density of 1 A·g?1, indicating its better electrochemical activity. The specific capacitance of the PBz particles reduced less than 10% after 500 charge-discharge cycles at the current density of 3 A·g?1, indicating its good cycling stability.  相似文献   
107.
Abstract

A class of non-mesogenic molecules, which as mixtures exhibit monotropic nematic phases, is described.  相似文献   
108.

A new homologous series of thermotropic liquid crystalline poly (azomethine‐ether)s based on dibenzylidene derivatives were synthesized by solution polycondensation of various diformyl‐α,ω-diphenoxyalkanes, I–VIII with 2,6‐bis(m‐aminobenzylidene)‐4‐phenylcyclohexanone X, and characterized by 1H‐NMR, IR and elemental analyses. The inherent viscosities of the polymers were in the range 0.29–0.58 dI/g. All the poly (azomethine‐ether)s were insoluble in common organic solvents but dissolved completely in concentrated H2SO4 and methanesulphonic acid. The mesomorphic properties were studied as a function of the diphenoxyalkane space length. Analysis by DSC and optical polarized microscopy demonstrated that the poly (azomethine‐ether)s from nematic mesophases over wide temperature ranges.  相似文献   
109.
Dealloying is widely utilized but is a dangerous corrosion process as well. Here we report an atomistic picture of the initial stages of electrochemical dealloying of the model system Cu(3)Au (111). We illuminate the structural and chemical changes during the early stages of dissolution up to the critical potential, using a unique combination of advanced surface-analytical tools. Scanning tunneling microscopy images indicate an interlayer exchange of topmost surface atoms during initial dealloying, while scanning Auger-electron microscopy data clearly reveal that the surface is fully covered by a continuous Au-rich layer at an early stage. Initiating below this first layer a transformation from stacking-reversed toward substrate-oriented Au surface structures is observed close to the critical potential. We further use the observed structural transitions as a reference process to evaluate the mechanistic changes induced by a thiol-based model-inhibition layer applied to suppress surface diffusion. The initial ultrathin Au layer is stabilized with the intermediate island morphology completely suppressed, along an anodic shift of the breakdown potential. Thiol-modification induces a peculiar surface microstructure in the form of microcracks exhibiting a nanoporous core. On the basis of the presented atomic-scale observations, an interlayer exchange mechanism next to pure surface diffusion becomes obvious which may be controlling the layer thickness and its later change in orientation.  相似文献   
110.
Local and blowing‐up solutions for the Cauchy problem for a system of space and time fractional evolution equations with time‐nonlocal nonlinearities of exponential growth are considered. The existence and uniqueness of the local mild solution is assured by the Banach fixed point principle. Then, we establish a blow‐up result by Pokhozhaev capacity method. Finally, under some suitable conditions, an estimate of the life span of blowing‐up solutions is established.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号